-
公开(公告)号：JP2001139455A
公开(公告)日：2001-05-22
申请号：JP32078299
申请日：1999-11-11
Applicant: KAO CORP
Inventor： TANAKA NORIHIRO , SATO HIROTAKA , TANAKA SHIGEYOSHI , KATAYAMA ATSUSHI , HIRAYAMA RYOICHI
Abstract: PROBLEM TO BE SOLVED: To provide a bath agent which has excellent smell persistence and gives an effect for improving the property of the skin. SOLUTION: This bath a gent containing a betaine ester represented by the formula (D (R1, R2 and R3 are each H or an alkyl or alkenyl which may have one or more substituents; Y is an alkylene which may have one or more substituents; R is a group obtained by removing one OH group from an alcoholic perfume having one or more OH groups in the molecule; A is an anion).
-
公开(公告)号：JP2000327618A
公开(公告)日：2000-11-28
申请号：JP14571199
申请日：1999-05-26
Applicant: KAO CORP
Inventor： TANAKA SHIGEYOSHI , KOHAMA TAMOTSU , FUJIKURA YOSHIAKI
IPC: B01J27/10 , C07B61/00 , C07C45/67 , C07C49/597
Abstract: PROBLEM TO BE SOLVED: To provide a method for production an 2-alkyl-2-cyclopentenone in high productivity and yield in a few solvent by bringing an alkylidnecyclopentanone into contact with a hydrogen halide under a specific temperature condition by using an alcohol as a solvent. SOLUTION: (A) An 2-alkylidenecyclopentanone of formula I (R is a 2-8C alkyl) is brought into contact with (C) a hydrogen halide at 150-190 deg.C in (B) an alcoholic solvent to provide (D) an 2-alkyl-2-cyclopentenone of formula II. Preferably, the components A and B are charged at first and the component C is added thereto simultaneously or within 30 min to provide the component D. For example, 2-penthylidenecyclo-pentanone and hydrogen chloride are dissolved in 1-butanol and the solution is heated at 160 deg.C and stirred at the same temperature for 2 hr under heating and after finishing the reaction, the solvent is distilled away and the residue is distilled under reduced pressure to 2-pentyl-2- cyclopentenone. Thereby, the objective compound is industrially advantageously obtained in high yield.
-
公开(公告)号：JP2000302713A
公开(公告)日：2000-10-31
申请号：JP11526299
申请日：1999-04-22
Applicant: KAO CORP
Inventor： HASHIZUME NAOMICHI , FUKUDA KAZUYUKI , TANAKA SHIGEYOSHI , ETSUNO JIYUNJI
Abstract: PROBLEM TO BE SOLVED: To obtain a cyclohexanol which is a new compound having voluminous floral perfume and useful as an aromatizing component for toiletry goods such as soap, shampoo, rinse, detergent and cosmetic. SOLUTION: The objective compound is expressed by formula I (R1 to R7 are each H, methyl or ethyl, and the total carbon number of R1 to R7 is
-
公开(公告)号：JP2000302712A
公开(公告)日：2000-10-31
申请号：JP11076099
申请日：1999-04-19
Applicant: KAO CORP
Inventor： HASHIZUME NAOMICHI , FUKUDA KAZUYUKI , TANAKA SHIGEYOSHI , ETSUNO JIYUNJI
Abstract: PROBLEM TO BE SOLVED: To obtain cyclohexylmethanol which is a new compound having voluminous floral perfume and useful as an aromatizing component for toiletry goods such as soap, shampoo, rinse, detergent and cosmetic. SOLUTION: The objective compound is expressed by formula I (R1 is H or methyl; and the bond of formula II is single or double bond and either one of two bonds of formula II is double bond; the wavy line shows a cis isomer or trans isomer), e.g. the compound of formula III. The compound of formula I can be produced e.g. by reacting 4-hydroxymethylcyclohexane carbaldehyde with acetone or methyl ethyl ketone in the presence of a basic catalyst preferably at 0-50 deg.C to obtain an α,β-unsaturated ketone of formula IV, reducing exclusively the carbonyl group of the ketone in the presence of a cerium salt at 0-60 deg.C preferably using a reducing agent and dehydrating the obtained compound of formula V preferably in the presence of an inorganic acid or organic acid in a solvent such as toluene at 50-150 deg.C.
-
公开(公告)号：JPH11209362A
公开(公告)日：1999-08-03
申请号：JP839498
申请日：1998-01-20
Applicant: KAO CORP
Inventor： TANAKA SHIGEYOSHI , ONO SATORU , TOI SUNAO
IPC: C07D307/33
Abstract: PROBLEM TO BE SOLVED: To provide a method for purifying a γ-alkyl-γ-lactone, capable of obtaining the lactone having a high quality, not having a foreign smell and an acidic taste, and satisfiable as a perfume, especially a food additive, by treating the γ-alkyl-γ-lactone with a metal alkoxide. SOLUTION: This method for purifying (A) a γ-alkyl-γ-lactone comprises mixing the component A with (B) a metal alkoxide (preferably sodium methoxide or sodium ethoxide) with stirring, and subsequently distilling the mixture. The component A is preferably obtained by thermally reacting acrylic acid with a primary alcohol, a secondary alcohol or their mixture in the presence of di-t-butyl peroxide.
-
Patent Agency Ranking
公开(公告)号：JPH10338687A
公开(公告)日：1998-12-22
申请号：JP14755997
申请日：1997-06-05
Applicant: KAO CORP
Inventor： NISHIOKA TORU , TANAKA SHIGEYOSHI , ETSUNO JIYUNJI , YAMASHITA OSAMU , OZAWA TADAHIRO
IPC: C07D309/18 , B01J27/10 , C07B61/00 , C07D309/22
Abstract: PROBLEM TO BE SOLVED: To economically obtain a dihydropyran derivative in high productivity and yield by reacting aldehydes with a diene compound in the presence of a Lewis acid catalyst and a specific cocatalyst. SOLUTION: An aldehyde of the formula, R -CHO (R is H, 1-12C alkyl, 6-12C aryl or the like which may be substituted with an alkyl) is reacted with a diene compound of formula I (R and R are each H, a 1-6C alkyl or alkenyl) in the presence of a Lewis acid catalyst and a cocatalyst without any solvent or in a solvent at -30 to 100 deg.C to provide the objective 5,6-dihydro-2H-pyran derivative of formula II. A compound (excluding a nitro compound) having weaker coordination force to Lewis acid than the aldehyde and having action dissolving the Lewis acid into a solvent by coordinating to Lewis acid is used as the cocatalyst and, e.g. one or two or more kinds of compounds selected from aliphatic or aromatic esters, chloroacetic esters, ethers, ketones and carbonates are used in an amount of 0.1-10 mol based on 1 mol Lewis acid.
-
公开(公告)号：JPH04247050A
公开(公告)日：1992-09-03
申请号：JP1197591
申请日：1991-02-01
Applicant: KAO CORP
Inventor： TANAKA SHIGEYOSHI , FUJIKURA YOSHIAKI
Abstract: PURPOSE:To obtain 2-methyl-1-undecanal useful as perfume from an inexpensively obtainable raw material economically and extremely advantageously. CONSTITUTION:A mixture of (A) 1-undecanol and (B) 2-methyl-1-undecanal is dehydrogenated and the unreacted raw material A is separated from the reaction mixture to give a mixture of (C) 1-undecanal, (D) 2-methyl-1-decanal and the unreacted raw material B. The unreacted raw material A is preferably used as the above-mentioned raw material. Then the mixture of the components B to D is allowed to react with formaldehyde or a formaldehyde-forming substance in the presence of an amine to give a mixture of (E) 2-methylene- undecanal, an intermediate D and the unreacted raw material B. The mixture is hydrogenated to give a mixture of (F) 2-methyl-1-undecanal, the intermediate D and the unreacted raw material B. Further, the unreacted raw material B in the mixture is converted into a boric ester to separate the objective compound F.
-
公开(公告)号：JP2008127333A
公开(公告)日：2008-06-05
申请号：JP2006314135
申请日：2006-11-21
Inventor： YANO KENJI , ASADA TAKAHIRO , TANAKA SHIGEYOSHI
IPC: C07C29/143 , C07B61/00 , C07C35/21 , C07C45/74 , C07C49/613 , C11B9/00
Abstract: PROBLEM TO BE SOLVED: To provide a manufacturing method of a camphorenylcyclohexenol compound applicable to industrial manufacturing, and a camphorenylcyclohexenol compound and a camphorenylcyclohexenone compound, and a perfume composition containing them. SOLUTION: This is a manufacturing method of a camphorenylcyclohexenol compound represented by formula (4) (wherein R 1 and R 2 each independently represents hydrogen, a normal or a branched chain alkyl group, an alkenyl group, or an alkynyl group) which is obtained first by the reaction of β-keto-ester and α,β-unsaturated aldehyde in the presence of a basic compound to obtain a camphorenylcyclohexenone compound, then by the reaction of the camphorenylcyclohexenone in the presence of a reducing agent. COPYRIGHT: (C)2008,JPO&INPIT
Abstract translation: 待解决的问题：提供适用于工业制造的辛酰基环己烯醇化合物的制备方法，以及樟脑基环己烯醇化合物和樟脑基环己烯酮化合物以及含有它们的香料组合物。 解决方案：这是由式（4）表示的辛酰基环己烯醇化合物的制备方法（其中R SP 1和R SP 2各自独立地表示氢，正常或 支链烷基，链烯基或炔基），首先通过β-酮酯与α，β-不饱和醛在碱性化合物的存在下反应得到辛酰基环己烯酮化合物，然后通过 在还原剂存在下的辛酰基环己烯酮的反应。 版权所有（C）2008，JPO＆INPIT
-
公开(公告)号：JP2005170822A
公开(公告)日：2005-06-30
申请号：JP2003411569
申请日：2003-12-10
Inventor： AOKI TAKASHI , TANAKA SHIGEYOSHI
IPC: C07C45/62 , C07B61/00 , C07C49/24 , C07C49/385 , C07C49/587 , C07C49/703
Abstract: PROBLEM TO BE SOLVED: To provide a profitable method for producing muscone, by which the muscone can be produced from inexpensive raw materials by simple methods.
SOLUTION: This method for producing the muscone comprises subjecting 8-nonen-2-one to an aldol dimerization reaction to obtain 8-hydroxy-8-methyl-1,16-heptadecadien-10-one, subjecting the compound to an intramolecular ring-closing metathesis reaction to obtain 3-hydroxy-3-methyl-9-cyclopentadecen-1-one, subjecting the compound to a dehydration reaction to obtain 3-methyl-2,9-cyclopentadecadien-1-one, or subjecting 8-nonen-2-one to an aldol dimerization reaction and a dehydration reaction to obtain 8-methyl-1,8,16-heptadecatrien-10-one, subjecting the compound to an intramolecular ring-closing metathesis reaction to obtain 3-methyl-2,9-cyclopentadecadien-1-one, and then hydrogenating the compound to obtain the muscone.
COPYRIGHT: (C)2005,JPO&NCIPIAbstract translation: 要解决的问题：提供用于生产肌肉的有利的方法，通过这种方法，可以通过简单的方法从廉价的原料生产肌肉。 解决方案：该制造肌肉的方法包括将8-壬烯-2-酮进行醛醇二聚反应，得到8-羟基-8-甲基-1,16-十七碳二烯-10-酮，使化合物 分子内闭合复分解反应，得到3-羟基-3-甲基-9-环十五烯-1-酮，使化合物进行脱水反应，得到3-甲基-2,9-环十五碳二烯-1-酮，或者使8 - 壬烯-2-酮与醛醇二聚反应和脱水反应，得到8-甲基-1,8,16-十七碳三烯-10-酮，使化合物进行分子内闭合复分解反应，得到3-甲基 - 2,9-环戊烯二酮-1-酮，然后氢化化合物以获得肌肉酮。 版权所有（C）2005，JPO＆NCIPI
-
公开(公告)号：JP2002128610A
公开(公告)日：2002-05-09
申请号：JP2000316079
申请日：2000-10-17
Applicant: KAO CORP
Inventor： NAGATSUKA MICHIKO , ISHIDA HIROHIKO , TANAKA SHIGEYOSHI
Abstract: PROBLEM TO BE SOLVED: To obtain an antibacterial and antifungal agent capable of exhibiting excellent antibacterial and antifungal activities not only at the directly applied site but also at the vicinity thereof, and, when the released antibacterial and antifungal component is a fragrant component, capable of imparting not only the antibacterial and antifungal activities but also good fragrance to the environment. SOLUTION: This antibacterial and antifungal agent contains an acetal derivative, an adduct to an inorganic salt, or a Schiff base derivative of an antibacterial and antifungal aldehyde compound or an antibacterial and antifungal ketone compound.
-
-
-
-
-
-
-
-
-
Search Results
100
records
(took 0.024 seconds)
