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公开(公告)号:CA2586076A1
公开(公告)日:2006-06-01
申请号:CA2586076
申请日:2005-11-21
Applicant: BASF AG
Inventor: STURM BERTHOLD , ESSER ANTON , NIESSNER MANFRED , NEUTZNER JOSEF , DUPUIS JACQUES , SCHALL NORBERT , RUEBENACKER MARTIN , HAEHNLE HANS-JOACHIM
IPC: D21H21/18
Abstract: The invention relates to a process for producing paper, board and cardboard of high dry strength by separately adding a polymer comprising vinylamine units and a polymeric anionic compound to a paper pulp, dewatering the pulp and drying the paper products, which comprises using as polymeric anionic compound at least one copolymer obtainable by copolymerizing (a) at least one N-vinylcarboxamide of the formula in which R1 and R2 are H or C1- to C6 alkyl, (b) at least one monoethylenically unsaturated monomer comprising acid groups, and/or the alkali metal, alkaline earth metal or ammonium salts thereof, and if appropriate (c) other monoethylenically unsaturated monomers, and if appropriate (d) compounds having at least two ethylenically unsaturated double bonds in their molecule.
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公开(公告)号:DE10340253A1
公开(公告)日:2005-03-24
申请号:DE10340253
申请日:2003-08-29
Applicant: BASF AG
Inventor: SCHMID MARKUS , SEIDL VOLKER , DISTLER DIETER , HAEHNLE HANS-JOACHIM , LOESCH DENNIS , MORITZ HANS-ULRICH , KRUEGER MARCO
Abstract: Monomer solutions with a water content of at least 55 wt% are used in a method for the spray polymerisation of monomer solutions containing radically-polymerisable monomers in an inert atmosphere. An independent claim is also included for water-swellable polymers obtained by this method.
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公开(公告)号:DE10334133A1
公开(公告)日:2005-02-24
申请号:DE10334133
申请日:2003-07-25
Applicant: BASF AG
Inventor: HAEHNLE HANS-JOACHIM , ESSER ANTON , BRAIG VOLKER , BLUM RAINER , BAUMANN PETER , DUPUIS JACQUES , NEUTZNER JOSEF
IPC: C08F8/12 , C08F8/44 , C08F226/02 , C08J5/10 , C08L33/14 , C08L33/26 , C08L39/02 , C08L43/02 , D21H17/34 , D21H17/45 , C08J5/04
Abstract: The present invention relates to an aqueous composition comprising at least one finely divided filler and at least one water-soluble amphoteric copolymer, a process for the preparation of such a composition and its use as an additive in the production of paper, cardboard and board.
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公开(公告)号:PL351567A1
公开(公告)日:2003-05-05
申请号:PL35156700
申请日:2000-04-11
Applicant: BASF AG
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公开(公告)号:DE50000971D1
公开(公告)日:2003-01-30
申请号:DE50000971
申请日:2000-02-21
Applicant: BASF AG
Inventor: HAEHNLE HANS-JOACHIM , SCHROEDER ULRICH , HEIDER WOLFGANG , SCHORNICK GUNNAR , ANSTOCK THOMAS
Abstract: Water-absorbing, expanded, crosslinked polymers obtainable by(I) foaming a polymerizable aqueous mixture which comprises(a) monoethylenically unsaturated monomers which contain acidic groups and are optionally neutralized,(b) optionally other monoethylenically unsaturated monomers,(c) crosslinkers,(d) initiators,(e) 0.1-20% by weight of at least one surfactant,(f) optionally at least one solubilizer and(g) optionally thickeners, foam stabilizers, polymerization regulators, fillers and/or cell nucleating agents,where the foaming takes place by dissolving a gas which is inert to free radicals under a pressure of 2-400 bar in the polymerizable aqueous mixture, and then decompressing the latter to atmospheric pressure, and(II) polymerizing the foamed mixture to form an expanded hydrogel and, where appropriate, adjusting the water content of the expanded polymer to 1-60% by weight, process for preparing the water-absorbing, expanded, crosslinked polymers and use of these polymers in sanitary articles employed for absorbing body fluids, in dressing material for covering wounds, as sealing material, as soil improver, as soil substitute and as packaging material.
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公开(公告)号:DE10047717A1
公开(公告)日:2002-04-18
申请号:DE10047717
申请日:2000-09-27
Applicant: BASF AG
Inventor: HAEHNLE HANS-JOACHIM , BAUMGARTL HORST , BECK MARTIN , HERFERT NORBERT , MOHR BERNHARD , HUFF JUERGEN
IPC: A61F13/53 , A61F13/00 , A61F13/02 , A61F13/15 , A61F13/49 , A61L15/26 , A61L15/42 , C08G12/32 , C08J9/14 , C08J9/36 , C08J9/22 , C08L61/32
Abstract: Hydrophilic open-celled resilient foams containing melamine-formaldehyde resins, characterized by a droplet absorption rate of less than 5 seconds and an EU standard EN ISO 14184-1 formaldehyde emission of less than 100 mg of formaldehyde/kg of foam, and obtainable by(a) heating an aqueous solution or dispersion each containing at least a melamine-formaldehyde precondensate, an emulsifier, a blowing agent and a curing agent to form a foam and crosslink the precondensate,(b) then conditioning the foam at from 120 to 300° C. for from 1 to 180 minutes to remove volatiles, and(c) treating the foam during the conditioning or thereafter with at least one hydrophilicizer and/or with ozone, a corona discharge or a plasma,are useful in hygiene articles to acquire, distribute and immobilize body fluids.
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公开(公告)号:DE59705081D1
公开(公告)日:2001-11-29
申请号:DE59705081
申请日:1997-02-27
Applicant: BASF AG
Inventor: HAEHNLE HANS-JOACHIM , WALTER MANFRED , TROPSCH JUERGEN , KREMESKOETTER JENS , SCHORNICK GUNNAR , ANSTOCK THOMAS
IPC: A61F13/00 , A61F13/53 , A61L15/00 , A61L15/16 , A61L15/42 , A61L15/60 , C05G3/80 , C08F2/44 , C08F2/48 , C08F220/06 , C08J9/30 , C08L33/02
Abstract: Water-absorbing foamlike crosslinked polymers which are obtainable by(I) foaming a polymerizable aqueous mixture which consists of(a) monoethylenically unsaturated monomers containing acid groups, which are at least 50 mol % neutralized,(b) with or without other monoethylenically unsaturated monomers,(c) crosslinker,(d) initiators,(e) from 0.1 to 20% by weight of at least one surfactant,(f) with or without one or more solubilizers and(g) with or without thickeners, foam stabilizers, polymerization regulators, fillers and/or cell nucleating agents,the foaming being performed by dispersing fine bubbles of a gas inert to free radicals, and(II) polymerizing the foamed mixture with formation of a foamed hydrogel, with or without adjusting the water content of the foamed polymer to from 1 to 60% by weight, processes for their preparation and their use in sanitary articles which are used for absorbing body fluids and in dressing materials for covering wounds are described.
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公开(公告)号:DE19917919A1
公开(公告)日:2001-02-01
申请号:DE19917919
申请日:1999-04-20
Applicant: BASF AG
Inventor: HAEHNLE HANS-JOACHIM , DYLLICK-BRENZINGER RAINER , SCHROEDER ULRICH , HERFERT NORBERT , RIEGEL ULRICH
IPC: C08J3/24 , C08L101/14 , C08F226/00 , C08L33/02 , C08L39/02 , C08L79/02
Abstract: A hydrogel forming polymer mixture (I) contains: (A) a hydrogel forming polymer having acidic groups; and (B) a hydrogel forming polymer having amine and /or imine groups such that the ratio of acid groups in (A) to the sum of amine and/or imine groups in (B) is 1:9-9:1.
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公开(公告)号:DE19909214A1
公开(公告)日:2000-09-07
申请号:DE19909214
申请日:1999-03-03
Applicant: BASF AG
Inventor: HAEHNLE HANS-JOACHIM , SCHROEDER ULRICH , HEIDER WOLFGANG , SCHORNICK GUNNAR , ANSTOCK THOMAS
IPC: A61L15/24 , A61L15/42 , A61L15/60 , B01J20/26 , C08J9/12 , C08J9/30 , C09K3/10 , C09K17/20 , C08J9/20 , C09K3/12 , C09K17/18 , A61F13/15
Abstract: The invention relates to water-absorbing, cellular, cross-linked polymers which are obtained by the following steps: (I) expanding a polymerizable aqueous mixture which contains (a) monoethylenically unsaturated monomers that contain acidic groups and that are optionally neutralized, (b) optionally other monoethylenically unsaturated monomers, (c) cross-linking agents, (d) initiators, (e) 0.1 to 20 wt.-%. of at least one surfactant, (f) optionally at least one solubilizer and (g) optionally thickeners, foam stabilizers, polymerization controllers, fillers and/or nucleating agents. A gas that is inert vis-à-vis radicals is dissolved in the polymerizable aqueous mixture at a pressure of 2 to 400 bar to expand the mixture and the mixture is then relaxed to atmospheric pressure; (II) polymerizing the expanded mixture while forming a cellular hydrogel and optionally adjusting the water content of the cellular polymer to 1 to 60 wt.-%. The invention further relates to methods for producing water-absorbing, cellular, cross-linked polymers and to the use of said polymers in hygiene articles that are used for absorbing body fluids, in dressings for covering wounds, as sealing material, as soil conditioner, soil substitute and as packaging material.
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公开(公告)号:AU1924397A
公开(公告)日:1997-09-16
申请号:AU1924397
申请日:1997-02-27
Applicant: BASF AG
Inventor: HAEHNLE HANS-JOACHIM , WALTER MANFRED , TROPSCH JUERGEN , KREMESKOETTER JENS , SCHORNICK GUNNAR , ANSTOCK THOMAS
IPC: A61F13/00 , A61F13/53 , A61L15/00 , A61L15/16 , A61L15/42 , A61L15/60 , C05G3/80 , C08F2/44 , C08F2/48 , C08F220/06 , C08J9/30 , C08L33/02
Abstract: Water-absorbing foamlike crosslinked polymers which are obtainable by(I) foaming a polymerizable aqueous mixture which consists of(a) monoethylenically unsaturated monomers containing acid groups, which are at least 50 mol % neutralized,(b) with or without other monoethylenically unsaturated monomers,(c) crosslinker,(d) initiators,(e) from 0.1 to 20% by weight of at least one surfactant,(f) with or without one or more solubilizers and(g) with or without thickeners, foam stabilizers, polymerization regulators, fillers and/or cell nucleating agents,the foaming being performed by dispersing fine bubbles of a gas inert to free radicals, and(II) polymerizing the foamed mixture with formation of a foamed hydrogel, with or without adjusting the water content of the foamed polymer to from 1 to 60% by weight, processes for their preparation and their use in sanitary articles which are used for absorbing body fluids and in dressing materials for covering wounds are described.
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