公开(公告)号：US3887754A

公开(公告)日：1975-06-03

申请号：US36521773

申请日：1973-05-30

Applicant: BASF AG

Inventor： WALTER MANFRED

IPC: C08J9/22 ,  C08J9/224 ,  C09K3/00

CPC classification number: C08J9/224 ,  C08J2325/04 ,  Y10T428/2998

Abstract: Particulate expandable styrene polymers having a short minimum mold resistance time and characterized by a coating of an amide of phthalic acid, dihydrophthalic acid or tetrahydrophthalic acid.

Abstract translation: 具有短的最短抗霉化时间的颗粒状可膨胀苯乙烯聚合物，其特征在于涂覆邻苯二甲酸，二氢邻苯二甲酸或四氢邻苯二甲酸的酰胺。

公开(公告)号：JP2008024943A

公开(公告)日：2008-02-07

申请号：JP2007215899

申请日：2007-08-22

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフトBASF Aktiengesellschaft

Inventor： HAEHNLE HANS-JOACHIM ,  WALTER MANFRED ,  TROPSCH JUERGEN DR ,  KREMESKOETTER JENS ,  SCHORNICK GUNNAR ,  ANSTOCK THOMAS

IPC: C08J9/12 ,  A61F13/00 ,  A61F13/15 ,  A61F13/49 ,  A61F13/53 ,  A61L15/16 ,  A61L15/42 ,  A61L15/60 ,  B01J20/26 ,  C05G3/04 ,  C08F2/44 ,  C08F2/48 ,  C08J9/30

CPC classification number: C05G3/04 ,  A61L15/425 ,  A61L15/60 ,  C08J9/30

Abstract: PROBLEM TO BE SOLVED: To provide a water-absorbing foamy crosslinked polymer.
SOLUTION: The process for producing the polymer comprises a first step (I) of foaming a polymerizable aqueous mixture of (a) a monoethylene unsaturated monomer having an acid radical in which at least its 50 mol% is neutralized, (b) optionally other monoethylene unsaturated monomer, (c) a crosslinking agent, (d) an initiator, (e) 0.1-20 wt.% of at least one kind of surfactant, (f) optionally at least one kind of solubilizer, and (g) optionally, a thickener, foam stabilizer, polymerization regulator, filler and/or foam nucleus-forming agent, and of dispersing fine foams of inactive gas into the radical to carry out foaming, and a second step (II) of forming a foamy hydrogel and optionally adjusting a water content of the foamy polymer to 1-60 wt.% to polymerize the foamed mixture.
COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供吸水泡沫交联聚合物。 解决方案：制备聚合物的方法包括：（a）具有至少其50mol％中和的酸基的单亚乙烯不饱和单体的可聚合水性混合物的发泡的第一步骤（I），（b） 任选的其它单乙烯不饱和单体，（c）交联剂，（d）引发剂，（e）0.1-20重量％的至少一种表面活性剂，（f）任选至少一种增溶剂，和（g ）任选的增稠剂，泡沫稳定剂，聚合调节剂，填料和/或泡沫成核剂，以及将惰性气体的细泡沫分散到自由基中以进行发泡;以及形成泡沫状水凝胶的第二步骤（II） 并且任选地将泡沫聚合物的水含量调节至1-60重量％以聚合发泡混合物。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：DE59707861D1

公开(公告)日：2002-09-05

申请号：DE59707861

申请日：1997-02-27

Applicant: BASF AG

Inventor： HAEHNLE HANS-JOACHIM ,  WALTER MANFRED ,  TROPSCH JUERGEN ,  KREMESKOETTER JENS ,  SCHORNICK GUNNAR ,  ANSTOCK THOMAS

IPC: A61F13/53 ,  A61F5/44 ,  A61F13/15 ,  A61F13/49 ,  A61L15/42 ,  A61L15/60 ,  B32B5/18 ,  C08F220/06

公开(公告)号：CA1162000A

公开(公告)日：1984-02-07

申请号：CA382576

申请日：1981-07-27

Applicant: BASF AG

Inventor： HAHN KLAUS ,  RATH HANS P ,  KRAPF HEINZ ,  DE GRAVE ISIDOOR ,  WALTER MANFRED

IPC: C08J9/22 ,  C08J9/224 ,  C08J9/232 ,  C08L25/04 ,  C08J9/16

Abstract: Particulate styrene polymers which contain a blowing agent and are surface-coated with from 0.05 to 1% by weight of an ester. The coating agent is an ester of citric acid and alcohols fo 10 to 20 carbon atoms; tristearyl citrate is a preferred ester. The styrene polymers can be used to produce foam moldings, with short mold dwell times and good welding of the foam particles.

公开(公告)号：NO784300L

公开(公告)日：1979-06-22

申请号：NO784300

申请日：1978-12-20

Applicant: BASF AG

Inventor： HAHN KLAUS ,  WALTER MANFRED ,  STANGE KARL ,  WEBER HEINZ

IPC: C08L27/00 ,  C08J9/00 ,  C08J9/22 ,  C08J9/224 ,  C08K5/34 ,  C08L7/00 ,  C08L21/00 ,  C08L25/04 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08J

Abstract: Particulate self-extinguishing thermoplastic molding compositions based on styrene polymers containing volatile blowing agents are surface-coated with an organic bromine compound and, to stabilize the bromine compound against photodegradation, a N-hydroxyphenylbenzotriazole or a hydroxybenzophenone. The molding compositions may be used for the manufacture of foams by expanding the blowing agents at elevated temperatures.

公开(公告)号：NO774215A

公开(公告)日：1978-06-12

申请号：NO774215

申请日：1977-12-08

Applicant: BASF AG

Inventor： WALTER MANFRED

IPC: C08J9/00 ,  C08J9/224 ,  C08L

CPC classification number: C08J9/224 ,  C08J9/0033 ,  C08J2325/04 ,  C08K5/46 ,  C08L25/04

公开(公告)号：CA982750A

公开(公告)日：1976-01-27

申请号：CA148480

申请日：1972-08-01

Applicant: BASF AG

Inventor： WALTER MANFRED ,  WEBER HEINZ

IPC: C08J9/22 ,  C08J9/224

Abstract: 1396949 Coated expandable polymer particles BADISCHE ANILIN-& SODA-FABRIK AG 4 Aug 1972 [7 Aug 1971] 36498/72 Heading B2E [Also in Division C3] Coated particulate expandable styrene polymers are made by coating particles of the expandable polymer with 0.05-2% by wt. of the polymer, of a carboxamide or mixture thereof of m.p. 60-110‹C and of formula: RCONHR' where R is a C 7-21 alkyl or alkenyl group and R' is a C 8-22 alkyl or alkenyl group. In the examples beads or granulates of polystyrene containing pentane are coated with powdered stearic, behenic, myristic or oleic N- stearylamide, stearic N-oleylamide, stearic N-2- ethylhexylamide, or behenic or myristic N-laurylamide. The coated particles may be pre-expanded with steam, stored and then expanded in a mould with steam.

公开(公告)号：AU8824191A

公开(公告)日：1992-06-04

申请号：AU8824191

申请日：1991-11-28

Applicant: BASF AG

Inventor： WALTER MANFRED ,  HUSEMANN WOLFRAM ,  NAEGELE DIETER

IPC: C08J9/14 ,  C08F2/18 ,  C08F2/44 ,  C08F4/34 ,  C08J9/00 ,  C08J9/16 ,  C08K5/00 ,  C08K5/01 ,  C08L25/04 ,  C08J9/20

Abstract: Expandable styrene polymers, containing …… a) a styrene polymer … b) from 1 to 10% by weight, based on a), of a saturated C3- to C6-hydrocarbon as blowing agent, and optionally … c) conventional assistants in effective amounts, … characterised in that the benzene content is less than 1 ppm and the styrene content is less than 2000 ppm.

公开(公告)号：AU7452087A

公开(公告)日：1987-12-24

申请号：AU7452087

申请日：1987-06-19

Applicant: BASF AG

Inventor： VOSS HARRO ,  HAHN KLAUS ,  WALTER MANFRED ,  DEGRAVE ISIDOOR

IPC: C08J9/16 ,  C08F2/44 ,  C08J9/14 ,  C08J9/22 ,  C08K5/01 ,  C08K5/02 ,  C08L25/04 ,  C08J9/12 ,  C08J9/18

Abstract: Particulate styrene polymers containing blowing agents are prepared by a process in which an aliphatic hydrocarbon of 7 to 9 carbon atoms is added in an amount of from 0.01 to 0.5% by weight, based on the styrene polymer, before, during or after the polymerization. The particulate styrene polymers can be processed to foam blocks and moldings having a satisfactory smooth surface.

公开(公告)号：CA1057450A

公开(公告)日：1979-06-26

申请号：CA236889

申请日：1975-10-02

Applicant: BASF AG

Inventor： HINSELMANN KLAUS ,  PENZIEN KLAUS ,  SCHICK RUPERT ,  WALTER MANFRED ,  WEBER HEINZ ,  WIRTH HEINRICH

IPC: C08J9/00 ,  C08J9/16 ,  C08J9/22 ,  C08K5/00 ,  C08L25/06

Abstract: Particulate expandable styrene polymers which contain from 0.0001 to 0.2% by weight, based on the styrene polymer, of an inhomogeneously distributed nucleating agent for expandable polystyrene, the nucleating agent being present only in a peripheral zone of the particles whilst the interior of the particles is free from nucleating agent. Nucleating agents which may be used are organic compounds having at least three bromine atoms, bonded to aliphatic or cycloaliphatic structures, in the molecule, or bromine compounds which are polymerizable, or are copolymerizable with styrene.