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    51.
    发明专利
    未知

    公开(公告)号：DE19813399A1

    公开(公告)日：1999-09-30

    申请号：DE19813399

    申请日：1998-03-26

    Applicant: BASF AG

    Inventor： LANGHAUSER FRANZ ,  APPLEYARD DAVID ,  HORTON MURRAY ,  HINGMANN ROLAND ,  SCHWEIER GUENTHER ,  RAUSCHENBERGER VOLKER ,  HENNIG INGOLF ,  LILGE DIETER ,  SCHOENE WERNER ,  KERSTING MEINOLF

    IPC: C08F2/34 ,  C08F4/02 ,  C08F4/658 ,  C08F210/06 ,  C08F210/16 ,  D01F6/30

    Abstract: A random copolymer (I) of propylene with other 2-10 C 1-alkenes comprises 0.7-1.4 wt.% ethylene comonomer or 0.7-3.0 wt.% 4-10 C 1-alkene. (I) has a solubility in cold xylene of 1.0-2.5 wt.% or 0.75-2.0 wt.% when the comonomer is ethylene or a 4-10C 1-alkene respectively. Independent claims are included for: (i) a process for the preparation of (I) by the gas phase polymerisation of propylene and a 2-10 C 1-alkene at 50-100 degrees C and 15-40 bar in the presence of a Ziegler-Natta catalyst containing: (A) a titanium containing solid component containing at least a halogen containing magnesium compound and an electron donor; (B) an aluminum compound; and (C) at least a further electron donor compound. The ratio of partial pressure of propylene to comonomer is 400:1-15:1 and the molar ratio of (B) to (C) is 20:1-2:1; and (ii) film, fiber or molded articles containing (I).

    Supported metallocene complexes having heterofunctional groups in the cyclopentadienyl system as catalyst system
    57.
    发明专利
    Supported metallocene complexes having heterofunctional groups in the cyclopentadienyl system as catalyst system 未知

    公开(公告)号：ZA951725B

    公开(公告)日：1996-09-02

    申请号：ZA951725

    申请日：1995-03-02

    Applicant: BASF AG

    Inventor： LANGHAUSER FRANZ ,  FISCHER DAVID ,  KERTH JUERGEN ,  SCHWEIER GUENTHER ,  BARSTIES ELKE ,  BRINTZINGER HANS-HERBERT ,  SCHAIBLE STEFAN ,  ROELL WERNER

    IPC: C08F4/622 ,  C08F4/02 ,  C08F4/60 ,  C08F4/602 ,  C08F4/616 ,  C08F4/628 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/656 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F

    Abstract: New supported catalyst systems prepd. by the following method: (a) reaction of a fine particled carrier with an alpha -tris-alkoxysilyl- OMEGA -haloalkyl cpd.; (b) addn. of a metallocene complex of formula (I); (c) reaction with a quaternising agent of formula (V); and (d) opt. addn. of an open chain or cyclic alumoxane cpd. of formula (VI) or (VII). M = Ti, Zr, Hf,V, Nb or Ta; X = F, Cl, Br, I, H 1-10C alkyl, 6-15C aryl or -OR ; R = 1-10C alkyl, 6-15C aryl, 1-10C alkyl, 6-20C aryl, 6-20C aryl - 1-10C alkyl, 1-10C fluoroalkyl or 6-20C fluoroaryl; R -R and R -R = H, 1-10C alkyl, opt.1-10C alkyl substd. 5-7 membered cycloalkyl or 6-15C aryl(alkyl),with which two neighbouring gps. may opt. form 4-15C cyclic gps., or Si(R )3; R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; R = : Q = N,P, As, Sb or Bi; R , R = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl- 6-20C aryl, 6-20C aryl -1-10C alkyl, 1-10C fluoroalkyl or 5-20C fluoroaryl, or R and R may form a 2-15C heterocyclic gp. contg. 1-8 heteroatoms from main gps. III-VI of the periodic table; R = H, 1-10C alkyl, opt.1-10C alkyl substd. 5-7 membered cycloalkyl, 6-15C aryl(alkyl) in which two neighbouring gps. may opt. form 4-15C cyclic gps. Si(R )3 or a gp. of formula R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; Q = N, P, As, Sb, or Bi; R , R = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl 6-20C aryl, 6-20C aryl -1-10C alkyl, 1-10C fluoroalkyl, 6-20C fluoroaryl or R14 and R15 may form a 2-15C heterocyclic gp.contg. 1-8 heteroatoms from main gps. III-VI of the periodic table; Y = a gp. of formula Z = Si,Ge, Sn or C; R -R = H, 1-10C alkyl, 3-10C cycloalkyl or 6-15C aryl, with two neighbouring gps. opt. forming a 4-15C cyclic gp.; A = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl-6-20C aryl, 6-20C aryl-1-10C alkyl, 1-10C fluoroalkyl or 6-20C fluoroaryl; X = F, Cl, Br, I, SO3 , SO4 or NO3 ; a = 1-2; R = 1-4C alky; and m = 5-30. Also claimed are (i) the prepn. of the supported catalyst systems, and (ii) use of the catalyst systems for the prepn. of 2-10C alk-1-enes at -50 to 300 degrees C. 0.5-3000 bar.

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