公开(公告)号：DE59500200D1

公开(公告)日：1997-06-05

申请号：DE59500200

申请日：1995-02-22

Applicant: BASF AG

Inventor： LANGHAUSER FRANZ DR ,  FISCHER DAVID DR ,  KERTH JUERGEN DR ,  SCHWEIER GUENTHER DR ,  BARSTIES ELKE ,  BRINTZINGER HANS-HERBERT PROF ,  SCHAIBLE STEFAN ,  ROELL WERNER DR

IPC: C08F4/622 ,  C08F4/02 ,  C08F4/60 ,  C08F4/602 ,  C08F4/616 ,  C08F4/628 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/656 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00

Abstract: New supported catalyst systems prepd. by the following method: (a) reaction of a fine particled carrier with an alpha -tris-alkoxysilyl- OMEGA -haloalkyl cpd.; (b) addn. of a metallocene complex of formula (I); (c) reaction with a quaternising agent of formula (V); and (d) opt. addn. of an open chain or cyclic alumoxane cpd. of formula (VI) or (VII). M = Ti, Zr, Hf,V, Nb or Ta; X = F, Cl, Br, I, H 1-10C alkyl, 6-15C aryl or -OR ; R = 1-10C alkyl, 6-15C aryl, 1-10C alkyl, 6-20C aryl, 6-20C aryl - 1-10C alkyl, 1-10C fluoroalkyl or 6-20C fluoroaryl; R -R and R -R = H, 1-10C alkyl, opt.1-10C alkyl substd. 5-7 membered cycloalkyl or 6-15C aryl(alkyl),with which two neighbouring gps. may opt. form 4-15C cyclic gps., or Si(R )3; R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; R = : Q = N,P, As, Sb or Bi; R , R = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl- 6-20C aryl, 6-20C aryl -1-10C alkyl, 1-10C fluoroalkyl or 5-20C fluoroaryl, or R and R may form a 2-15C heterocyclic gp. contg. 1-8 heteroatoms from main gps. III-VI of the periodic table; R = H, 1-10C alkyl, opt.1-10C alkyl substd. 5-7 membered cycloalkyl, 6-15C aryl(alkyl) in which two neighbouring gps. may opt. form 4-15C cyclic gps. Si(R )3 or a gp. of formula R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; Q = N, P, As, Sb, or Bi; R , R = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl 6-20C aryl, 6-20C aryl -1-10C alkyl, 1-10C fluoroalkyl, 6-20C fluoroaryl or R14 and R15 may form a 2-15C heterocyclic gp.contg. 1-8 heteroatoms from main gps. III-VI of the periodic table; Y = a gp. of formula Z = Si,Ge, Sn or C; R -R = H, 1-10C alkyl, 3-10C cycloalkyl or 6-15C aryl, with two neighbouring gps. opt. forming a 4-15C cyclic gp.; A = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl-6-20C aryl, 6-20C aryl-1-10C alkyl, 1-10C fluoroalkyl or 6-20C fluoroaryl; X = F, Cl, Br, I, SO3 , SO4 or NO3 ; a = 1-2; R = 1-4C alky; and m = 5-30. Also claimed are (i) the prepn. of the supported catalyst systems, and (ii) use of the catalyst systems for the prepn. of 2-10C alk-1-enes at -50 to 300 degrees C. 0.5-3000 bar.

公开(公告)号：ZA951725B

公开(公告)日：1996-09-02

申请号：ZA951725

申请日：1995-03-02

Applicant: BASF AG

Inventor： LANGHAUSER FRANZ ,  FISCHER DAVID ,  KERTH JUERGEN ,  SCHWEIER GUENTHER ,  BARSTIES ELKE ,  BRINTZINGER HANS-HERBERT ,  SCHAIBLE STEFAN ,  ROELL WERNER

IPC: C08F4/622 ,  C08F4/02 ,  C08F4/60 ,  C08F4/602 ,  C08F4/616 ,  C08F4/628 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/656 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F

Abstract: New supported catalyst systems prepd. by the following method: (a) reaction of a fine particled carrier with an alpha -tris-alkoxysilyl- OMEGA -haloalkyl cpd.; (b) addn. of a metallocene complex of formula (I); (c) reaction with a quaternising agent of formula (V); and (d) opt. addn. of an open chain or cyclic alumoxane cpd. of formula (VI) or (VII). M = Ti, Zr, Hf,V, Nb or Ta; X = F, Cl, Br, I, H 1-10C alkyl, 6-15C aryl or -OR ; R = 1-10C alkyl, 6-15C aryl, 1-10C alkyl, 6-20C aryl, 6-20C aryl - 1-10C alkyl, 1-10C fluoroalkyl or 6-20C fluoroaryl; R -R and R -R = H, 1-10C alkyl, opt.1-10C alkyl substd. 5-7 membered cycloalkyl or 6-15C aryl(alkyl),with which two neighbouring gps. may opt. form 4-15C cyclic gps., or Si(R )3; R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; R = : Q = N,P, As, Sb or Bi; R , R = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl- 6-20C aryl, 6-20C aryl -1-10C alkyl, 1-10C fluoroalkyl or 5-20C fluoroaryl, or R and R may form a 2-15C heterocyclic gp. contg. 1-8 heteroatoms from main gps. III-VI of the periodic table; R = H, 1-10C alkyl, opt.1-10C alkyl substd. 5-7 membered cycloalkyl, 6-15C aryl(alkyl) in which two neighbouring gps. may opt. form 4-15C cyclic gps. Si(R )3 or a gp. of formula R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; Q = N, P, As, Sb, or Bi; R , R = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl 6-20C aryl, 6-20C aryl -1-10C alkyl, 1-10C fluoroalkyl, 6-20C fluoroaryl or R14 and R15 may form a 2-15C heterocyclic gp.contg. 1-8 heteroatoms from main gps. III-VI of the periodic table; Y = a gp. of formula Z = Si,Ge, Sn or C; R -R = H, 1-10C alkyl, 3-10C cycloalkyl or 6-15C aryl, with two neighbouring gps. opt. forming a 4-15C cyclic gp.; A = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl-6-20C aryl, 6-20C aryl-1-10C alkyl, 1-10C fluoroalkyl or 6-20C fluoroaryl; X = F, Cl, Br, I, SO3 , SO4 or NO3 ; a = 1-2; R = 1-4C alky; and m = 5-30. Also claimed are (i) the prepn. of the supported catalyst systems, and (ii) use of the catalyst systems for the prepn. of 2-10C alk-1-enes at -50 to 300 degrees C. 0.5-3000 bar.

公开(公告)号：ZA9501725B

公开(公告)日：1996-09-02

申请号：ZA9501725

申请日：1995-03-02

Applicant: BASF AG

Inventor： LANGHAUSER FRANZ ,  FISCHER DAVID ,  KERTH JUERGEN ,  SCHWEIER GUENTHER ,  BARSTIES ELKE ,  BRINTZINGER HANS-HERBERT ,  SCHAIBLE STEFAN ,  ROELL WERNER

IPC: C08F4/622 ,  C08F4/02 ,  C08F4/60 ,  C08F4/602 ,  C08F4/616 ,  C08F4/628 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/656 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F

CPC classification number: C08F10/00 ,  C08F4/63908 ,  C08F4/63916 ,  C08F4/63927

公开(公告)号：DE4406964A1

公开(公告)日：1995-09-07

申请号：DE4406964

申请日：1994-03-03

Applicant: BASF AG

Inventor： LANGHAUSER FRANZ DR ,  FISCHER DAVID DR ,  KERTH JUERGEN DR ,  SCHWEIER GUENTHER DR ,  BARSTIES ELKE ,  BRINTZINGER HANS-HERBERT PROF ,  SCHAIBLE STEFAN ,  ROELL WERNER DR

IPC: C08F4/622 ,  C08F4/02 ,  C08F4/60 ,  C08F4/602 ,  C08F4/616 ,  C08F4/628 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/642 ,  C08F4/656 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00

Abstract: New supported catalyst systems prepd. by the following method: (a) reaction of a fine particled carrier with an alpha -tris-alkoxysilyl- OMEGA -haloalkyl cpd.; (b) addn. of a metallocene complex of formula (I); (c) reaction with a quaternising agent of formula (V); and (d) opt. addn. of an open chain or cyclic alumoxane cpd. of formula (VI) or (VII). M = Ti, Zr, Hf,V, Nb or Ta; X = F, Cl, Br, I, H 1-10C alkyl, 6-15C aryl or -OR ; R = 1-10C alkyl, 6-15C aryl, 1-10C alkyl, 6-20C aryl, 6-20C aryl - 1-10C alkyl, 1-10C fluoroalkyl or 6-20C fluoroaryl; R -R and R -R = H, 1-10C alkyl, opt.1-10C alkyl substd. 5-7 membered cycloalkyl or 6-15C aryl(alkyl),with which two neighbouring gps. may opt. form 4-15C cyclic gps., or Si(R )3; R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; R = : Q = N,P, As, Sb or Bi; R , R = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl- 6-20C aryl, 6-20C aryl -1-10C alkyl, 1-10C fluoroalkyl or 5-20C fluoroaryl, or R and R may form a 2-15C heterocyclic gp. contg. 1-8 heteroatoms from main gps. III-VI of the periodic table; R = H, 1-10C alkyl, opt.1-10C alkyl substd. 5-7 membered cycloalkyl, 6-15C aryl(alkyl) in which two neighbouring gps. may opt. form 4-15C cyclic gps. Si(R )3 or a gp. of formula R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; Q = N, P, As, Sb, or Bi; R , R = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl 6-20C aryl, 6-20C aryl -1-10C alkyl, 1-10C fluoroalkyl, 6-20C fluoroaryl or R14 and R15 may form a 2-15C heterocyclic gp.contg. 1-8 heteroatoms from main gps. III-VI of the periodic table; Y = a gp. of formula Z = Si,Ge, Sn or C; R -R = H, 1-10C alkyl, 3-10C cycloalkyl or 6-15C aryl, with two neighbouring gps. opt. forming a 4-15C cyclic gp.; A = 1-10C alkyl, 3-15C cycloalkyl, 6-15C aryl, 1-10C alkyl-6-20C aryl, 6-20C aryl-1-10C alkyl, 1-10C fluoroalkyl or 6-20C fluoroaryl; X = F, Cl, Br, I, SO3 , SO4 or NO3 ; a = 1-2; R = 1-4C alky; and m = 5-30. Also claimed are (i) the prepn. of the supported catalyst systems, and (ii) use of the catalyst systems for the prepn. of 2-10C alk-1-enes at -50 to 300 degrees C. 0.5-3000 bar.