公开(公告)号：CA2483310C

公开(公告)日：2011-09-13

申请号：CA2483310

申请日：2003-04-25

Applicant: BASF AG

Inventor： RULAND ALFRED ,  SCHOLTISSEK MARTIN ,  OETTER GUENTER ,  TAEGER KLAUS

IPC: C07C43/11 ,  C09K23/42 ,  A01N25/30 ,  A61K8/39 ,  A61K8/86 ,  A61Q19/00 ,  B01D19/04 ,  C02F1/52 ,  C07B61/00 ,  C07C41/03 ,  C07C43/13 ,  C08G65/26 ,  C09D5/02 ,  C09K3/00 ,  C09K23/00 ,  C11D1/72 ,  C11D1/722

Abstract: The invention relates to alkoxylates of general formula (I) C5H11CH(C3H7)CH2O(A)n(CH2CH2O)mH, wherein: A represents propyleneoxy, buteneoxy or penteneoxy; n represents a number ranging from 1 to 8, and; m represents a number ranging from 2 to 20. The inventive compounds are used as emulsifiers, foam regulators and as wetting agents for hard surfaces.

公开(公告)号：DE10243363A1

公开(公告)日：2004-04-01

申请号：DE10243363

申请日：2002-09-18

Applicant: BASF AG

Inventor： RULAND ALFRED ,  SCHOLTISSEK MARTIN ,  TROPSCH JUERGEN ,  BOEHN ROLAND ,  HACKMANN CLAUS ,  WULFF CHRISTIAN

IPC: A01N25/30 ,  A61K8/39 ,  A61K8/86 ,  A61Q19/00 ,  A61Q19/10 ,  C02F1/52 ,  C09D5/02 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825 ,  D06M13/165 ,  D06M13/17 ,  D06P1/613 ,  D06P1/651 ,  C07C43/10 ,  A61K7/00

Abstract: Alkoxylate mixture contains 70-99 wt.% alkoxylate(s) (A1) of 2-propyl-heptan-1-ol(s) and 1-30 wt.% alkoxylate(s) (A2) of 2-propyl-4-methyl-hexan-1-ol(s) and/or 2-propyl-5-methyl-hexan-1-ol(s). Alkoxylate mixture contains alkoxylates of formula (I), comprising 70-99 wt.% alkoxylate(s) (A1) of 2-propyl-heptan-1-ol(s) of formula (I; where C5H11 = n-C5H11) and 1-30 wt.% alkoxylate(s) (A2) of 2-propyl-4-methyl-hexan-1-ol(s) and/or 2-propyl-5-methyl-hexan-1-ol(s), of formula (I; where C5H11 = C2H5CH(CH3)CH2 and/or CH3CH(CH3)CH2CH2), in which the alkylenoxy groups have random or alternating distribution or are in 2 or more blocks in any sequence. A = ethylenoxy; B = 3-10 C alkylenoxy or a mixture of such groups; n = 0-30; m = 0-20; and n+m = 1 or more. Independent claims are also included for the following: (1) production of the alkoxylate mixture by reacting the corresponding alkanols with 2-5 C alkylene oxides under alkoxylation conditions, using a double metal cyanide compound as catalyst, and mixing them before or after alkoxylation or after partial alkoxylation; (2) laundry, cleaning, wetting, coatings, adhesive, leather degreasing, humectant and plant protection formulations containing the alkoxylate mixture.

公开(公告)号：DE10243361A1

公开(公告)日：2004-04-01

申请号：DE10243361

申请日：2002-09-18

Applicant: BASF AG

Inventor： RULAND ALFRED ,  SCHOLTISSEK MARTIN ,  TROPSCH JUERGEN ,  BAUR RICHARD

IPC: C07C41/03 ,  C07C43/11 ,  C08G65/26 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825 ,  C08G65/10

Abstract: Alkoxylate mixture contains 0.1-99.9 wt.% alkoxylate(s) (I) of 8-11 carbon (C) alkanol(s) and 0.1-99.9 wt.% alkoxylate(s) (II) of 12-24 C alkanol(s), in which (I) has 1-20 and (II) has 1-50 ethylenoxy groups, (I) and (II) have 0-10, optionally mixed 3-10 C alkylenoxy groups and the ethylenoxy and other alkylenoxy groups have random or alternating distribution or are in 2 or more blocks in any sequence. Alkoxylate mixture contains 0.1-99.9 wt.% alkoxylate(s) (I) and 0.1-99.9 wt.% alkoxylate(s) (II) of the given formulae, in which the ethylenoxy and other alkylenoxy groups have random or alternating distribution or are in 2 or more blocks in any sequence: R1 = CnH2n+1; R2 = CmH2m+1; A = ethylenoxy; B = 3-10 C alkylenoxy or a mixture of such groups; n = 8-11; m = 12-24; x = 1-20; = 1-50; y, w = 0-10 . An Independent claim is also included for production of the alkoxylate mixture by reacting the corresponding alkanols with 2-5 C alkylene oxides under alkoxylation conditions, using a double metal cyanide compound as catalyst, and mixing them before or after alkoxylation or after partial alkoxylation.

公开(公告)号：DE10218754A1

公开(公告)日：2003-11-13

申请号：DE10218754

申请日：2002-04-26

Applicant: BASF AG

Inventor： RULAND ALFRED ,  SCHOLTISSEK MARTIN ,  OETTER GUENTER ,  TAEGER KLAUS

IPC: A01N25/30 ,  A61K8/39 ,  A61K8/86 ,  A61Q19/00 ,  C02F1/52 ,  C07C41/03 ,  C07C43/11 ,  C08G65/26 ,  C08G65/28 ,  C09D5/02 ,  C09K23/42 ,  C11D1/72 ,  C07C43/13 ,  C11D1/722 ,  B01F17/42 ,  B01D19/04 ,  A61K7/00 ,  A61K9/107 ,  B08B3/08 ,  A01N25/04 ,  C14C9/02 ,  D06M13/17

Abstract: 2-Propyl-heptan-1-ol alkoxylates (IA) with 3-14 ethylenoxy and 1.2-1.8 propylenoxy or pentenoxy or 1-1.8 butenoxy groups in the molecule are new. 2-Propyl-heptan-1-ol alkoxylates (IA) of formula (I), with specified numbers of alkoxylate groups, are new. A = propylenoxy, butenoxy or pentenoxy; n = 1.2-1.8 or, if A is butenoxy, 1-1.8; and m = 3-14. Independent claims are also included for the following: (1) use of a wider range of alkoxylates of formula (I; where n = 1-8; m = 2-20) as emulsifiers, foam regulators and wetting agents for hard surfaces; (2) preparation of alkoxylates (IA) by reacting the alkanol with propylene oxide and then with ethylene oxide under alkoxylation conditions, which can be carried out in the presence of a double metal cyanide compound as catalyst; (3) preparation of the alkanol by alkaline dimerization of valeraldehyde to an alpha,beta-unsaturated aldehyde, followed by hydrogenation; and (4) cleaning, wetting, coating, adhesive, leather degreasing, humectant, textile treatment or cosmetic, pharmaceutical or plant protection formulations containing (I).

公开(公告)号：DE10218753A1

公开(公告)日：2003-11-13

申请号：DE10218753

申请日：2002-04-26

Applicant: BASF AG

Inventor： RULAND ALFRED ,  SCHOLTISSEK MARTIN ,  TROPSCH JUERGEN ,  BOEHN ROLAND ,  HACKMANN CLAUS

IPC: A01N25/30 ,  A61K8/39 ,  A61K8/86 ,  A61Q19/00 ,  A61Q19/10 ,  C02F1/52 ,  C09D5/02 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825 ,  D06M13/165 ,  D06M13/17 ,  D06P1/613 ,  D06P1/651 ,  C11D1/66

Abstract: Alkoxylate mixture contains 70-99 wt.% alkoxylate(s) (A1) of 2-propyl-heptan-1-ol(s) and 1-30 wt.% alkoxylate(s) (A2) of 2-propyl-4-methyl-hexan-1-ol(s) and/or 2-propyl-5-methyl-hexan-1-ol(s). Alkoxylate mixture contains alkoxylates of formula (I), comprising 70-99 wt.% alkoxylate(s) (A1) of 2-propyl-heptan-1-ol(s) of formula (I; where C5H11 = n-C5H11) and 1-30 wt.% alkoxylate(s) (A2) of 2-propyl-4-methyl-hexan-1-ol(s) and/or 2-propyl-5-methyl-hexan-1-ol(s), of formula (I; where C5H11 = C2H5CH(CH3)CH2 and/or CH3CH(CH3)CH2CH2), in which the alkylenoxy groups have random or alternating distribution or are in 2 or more blocks in any sequence. A = ethylenoxy; B = 3-10 C alkylenoxy or a mixture of such groups; n = 0-30; m = 0-20; and n+m = 1 or more. Independent claims are also included for the following: (1) production of the alkoxylate mixture by reacting the corresponding alkanols with 2-5 C alkylene oxides under alkoxylation conditions, using a double metal cyanide compound as catalyst, and mixing them before or after alkoxylation or after partial alkoxylation; (2) laundry, cleaning, wetting, coatings, adhesive, leather degreasing, humectant and plant protection formulations containing the alkoxylate mixture.

公开(公告)号：CA2483470A1

公开(公告)日：2003-11-06

申请号：CA2483470

申请日：2003-04-25

Applicant: BASF AG

Inventor： TROPSCH JURGEN ,  BAUR RICHARD ,  SCHOLTISSEK MARTIN ,  RULAND ALFRED

IPC: C07C41/03 ,  C07C43/11 ,  C08G65/26 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825

Abstract: The alkoxylate mixture contains 0.1 to 99.9 wt. % of at least one alkoxylate of general formula (I) CnH2n+1O(A)x(B)yH, wherein: A represents ethyleneoxy; B represents C3-C10 alkyleneoxy or mixtures thereof, whereby groups A and B ca n exist in a statistically distributed or alternating form or in the form of t wo or more blocks arranged in any order; n represents a whole number ranging fr om 8 to 11; x represents a number ranging from 1 to 20, and; y represents a number ranging from 0 to 10. The alkoxylate mixture also contains 0.1 to 99. 9 wt. % of at least one alkoxylate of general formula (II) CmH2m+1O(A)v(B)wH, wherein: A represents ethyleneoxy; B represents C3-C10 alkyleneoxy or mixtur es thereof, whereby groups A and B can exist in a statistically distributed or alternating form or in the form of two or more blocks arranged in any order; m represents a whole number ranging from 12 to 24; v represents a number rangi ng from 1 to 50, and; w represents a number ranging from 0 to 10.

公开(公告)号：AU748254B2

公开(公告)日：2002-05-30

申请号：AU5859298

申请日：1997-12-19

Applicant: BASF AG

Inventor： KISTENMACHER AXEL ,  KLINGELHOFER PAUL ,  PERNER JOHANNES ,  HARTMANN MARKUS ,  RULAND ALFRED

IPC: C04B22/16 ,  C04B24/26 ,  C04B24/32 ,  C04B103/32 ,  C08F2/00 ,  C08F220/04 ,  C08F220/06 ,  C08F220/28 ,  C08F220/58 ,  C08F290/04

Abstract: The present invention relates to the use of water soluble or water dispersible polymers containing carboxyl groups, optionally in latent form, and side-chains of general formula (I) -X-Y-[-O-(-Alk-O) n -R] k as additives in mineral building materials, wherein X, Y, Alk, R, n and k have the meanings cited in claim 1. Said polymers can be obtained by polymerizing ethylenically unsaturated monomers in the presence of compounds containing phosphorus and, optionally, by additional polymer-analogous transformation. The invention further relates to the production of said polymers and the use thereof. Also described are polymers, which can be obtained by polymerizing aromatic vinyl compounds, olefins, cycloolefins and/or dienes, as D monomers and anhydrides of ethylenically unsaturated dicarboxylic acids as E monomers and which can be used both as parent compounds for the above-mentioned polymers and as additives for mineral building materials.

公开(公告)号：CO5040158A1

公开(公告)日：2001-05-29

申请号：CO97069846

申请日：1997-11-28

Applicant: CLOROX CO ,  BASF AG

Inventor： ULRICH ANNEN ,  DELINE JAMES E ,  LAFAYETTE D FOLAND ,  KLOTTER KEVIN A ,  MULLER JOSEPH ,  MULLER MICHAEL ,  KLAUS MUNDINGER ,  PHILLIPPI MARTIN A ,  RULAND ALFRED ,  SCHAFER WOLFGANG ,  WIDDER RUDI ,  SCHURMANN GREGOR ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07C253/18 ,  C07C255/03 ,  C07D265/12 ,  C07D291/00 ,  C07D295/15 ,  C11D3/39 ,  C11D3/395

Abstract: Un proceso para la preparación de un compuesto que tiene laestructura de la Fórmula I en donde A es una anillo saturado formado por una pluralidad de átomos adicionales al átomo N1, el anillo saturado de átomos incluyendo por lo menos un átomo de carbón y por lo menos un átomo de O, S y N, el substituyente R1 unido al átomo N1 de la estructura de la Fórmula I incluyendo, ya sea, (a) un alquil C1-24 o un alquil alcoxilado en donde el alcoxi es un C2-4 , (b) un cicloalquil C4-24 , (c) un alcaril C7-24 , (d) un alcoxi repetitivo o no repetitivo o un alcohol alcoxilado, en donde la unidad alcoxi es C2-4 , o (e) -CR2 R3 C N en donde R2 y R3 son cada uno H, un alquil C1-24 , un cicloalquil o un alcaril o un alcoxi repetitivo o no repetitivo o un alcohol alcoxilado en donde unidades alcoxi son C2-4 , el valor de Z se encuentra entre el rango de 0 a 10 y en donde Y es un contraión, compuesto por los pasos de la reacción de una amina heterocíclica con un monoaldehido odialdehido R6 -CHO o OHC-R5 -CHO, en donde R5 es un enlace químico o un puente alcalino C1 a C6 o un pueste oxietileno y R6 indica un H o un alquil C1 a C20 y con el cianuro hidrogenado o el cianuro metálico alcalino encontrándose en un medio acuoso (Paso A); y la cauterización de la amina heterocíclica de la reacción con un agente alquilante para introducir el sustituyente R1 en la molécula (Paso B), en donde el Paso A se lleva a cabo bajo un rango de PH entre 8 y 14 y el Paso B se lleva a un pH no menor que 2.

公开(公告)号：ZA9710685B

公开(公告)日：1998-09-03

申请号：ZA9710685

申请日：1997-11-27

Applicant: CLOROX CO ,  BASF AG

Inventor： ANNEN ULRICH ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KLOTTER KEVIN A ,  MULLER JOSEPH ,  MULLER MICHAEL ,  MUNDINGER KLAUS ,  PHILLIPPI MARTIN A ,  RULAND ALFRED ,  SCHAFER WOLFGANG ,  SCHURMANN GREGOR ,  WIDDER RUDI ,  ZIELSKE ALFRED G

IPC: C07D20060101 ,  C11D20060101 ,  C11D ,  C07D

公开(公告)号：ES2060161T3

公开(公告)日：1994-11-16

申请号：ES90906976

申请日：1990-05-10

Applicant: BASF AG

Inventor： DENZINGER WALTER ,  HARTMANN HEINRICH ,  GOUSETIS CHARALAMPOS ,  GOECKEL ULRICH ,  RULAND ALFRED

IPC: C02F1/00 ,  C02F5/00 ,  C02F5/08 ,  C02F5/10 ,  C02F5/12 ,  C02F5/14 ,  C08F20/02 ,  C08F26/06 ,  C08F220/04 ,  C08F220/06 ,  C08F222/02 ,  C08F226/06

Abstract: PCT No. PCT/EP90/00752 Sec. 371 Date Nov. 1, 1991 Sec. 102(e) Date Nov. 1, 1991 PCT Filed May 10, 1990 PCT Pub. No. WO90/14314 PCT Pub. Date Nov. 29, 1990.Water-soluble copolymers which contain, polymerized in, as characteristic monomers (a) 99 to 50% by weight of monoethylenically unsaturated carboxylic acids with 3 to 8 carbon atoms or their salts and (b) 1 to 50% by weight of N-vinylimidazole or substituted N-vinylimidazoles, their salts or products of quaternization and which have K values of from 10 to 50 are used for water treatment to reduce deposits of scale and sludge in water-conveying systems.