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    THERMOSENSITIVE REVERSIBLE DISCOLORING RESIN WHEEL FOR BICYCLE
    54.
    发明专利
    THERMOSENSITIVE REVERSIBLE DISCOLORING RESIN WHEEL FOR BICYCLE 失效

    公开(公告)号：JPH07205605A

    公开(公告)日：1995-08-08

    申请号：JP367394

    申请日：1994-01-18

    Applicant: TORAY INDUSTRIES

    Inventor： OKAMOTO MASARU ,  YASUDA ATSUSHI ,  AOYAMA TOSHIKAZU

    IPC: B60B5/02 ,  B29C45/00 ,  B29L31/32 ,  B32B27/18 ,  C08J7/04 ,  C09D5/26

    Abstract: PURPOSE:To get changes of two or more colors due to thermal change and increase the fashion sense, by providing a thermosensitive reversible discoloring substance on the surface of a resin wheel on which one or more kinds of thermoplastic resin selected from polyamide resin, polyester resin, etc., are formed by the injection molding. CONSTITUTION:A resin wheel for a bicycle is formed by the injection molding of one or more kinds of thermoplastic resin selected from polyamide resin, polyester resin, polystyrene resin, polycarbonate resin, and polyolefin resin. And a thermosensitive reversible discoloring substance is provided on the surface of the wheel. If necessary, an improving agent against shocks and/or fiber reinforcing agent are added in the thermoplastic resin. Electron donor, electron acceptor, and controller, as generally known are used. The thermosensitive reversible discoloring substance may be used independenly but it is preferably used with an ultraviolet ray absorbent, an oxidation inhibitor, etc.

    FLUORESCENT RESIN WHEEL FOR BICYCLE
    55.
    发明专利
    FLUORESCENT RESIN WHEEL FOR BICYCLE 失效

    公开(公告)号：JPH06286402A

    公开(公告)日：1994-10-11

    申请号：JP7441193

    申请日：1993-03-31

    Applicant: TORAY INDUSTRIES

    Inventor： OKAMOTO MASARU ,  YASUDA ATSUSHI ,  AOYAMA TOSHIKAZU

    IPC: B29C45/00 ,  B29L31/08 ,  B60B5/02

    Abstract: PURPOSE:To provide a resin wheel which emits fluorescence regardless of the radiating direction of light by a headlamp or the like of an automobile and is excellent in visibility by dyeing the resin wheel by a fluorescent brightener after the resin wheel is formed by carrying out injection molding on polyamide resin or the other thermoplastic resin. CONSTITUTION:After a resin wheel is formed by carrying out injection molding on one or more kinds of thermoplactic resins (A) selected from polyamide resin, polyester resin, polystyrene resin, polycarbonate resin and polyolefine resin, this is dyed by a fluorescent brightner, and a fluorescent resin wheel for a bicycle is constituted. A resin composition may be constituted by containing an impact improver (B) in the thermoplastic resin (A). The resin composition may be constituted by containing a fiber reinforcing agent (C) in the thermoplastic resin (A) or a resin composition formed by containing the impact improver (B) in this. Thereby, a safe resin wheel which emits fluorescence reliably regardless of the light radiating direction when light is radiated, can be obtained.

    PRODUCTION OF LIQUID-CRYSTAL POLYMER MOLDED ARTICLE WITH SURFACE METALLIZED
    56.
    发明专利
    PRODUCTION OF LIQUID-CRYSTAL POLYMER MOLDED ARTICLE WITH SURFACE METALLIZED 失效

    公开(公告)号：JPH04293787A

    公开(公告)日：1992-10-19

    申请号：JP5733091

    申请日：1991-03-20

    Applicant: TORAY INDUSTRIES

    Inventor： OKAMOTO MASARU ,  YAMANAKA TORU ,  INOUE SHUNEI

    IPC: C08J7/14 ,  C08J7/12 ,  C23C18/22 ,  C25D5/56

    Abstract: PURPOSE:To produce the molded article excellent in plating film adhesive strength and surface appearance by roughening the surface of a molded article consisting of a liq.-crystal polyester shown by the specified formula and rock wool fibers with an acidic soln. and an alkaline soln. and metallizing the surface by plating. CONSTITUTION:One hundred pts.wt. of a liq.-crystal polyester shown by the formula (k/1/m/n=80/7.5/12.5/20) is mixed with 2-200 pts.wt. of the rock wool fibers (produced from basalt and having about 2-20mum average fiber diameter, about 20-650mu average fiber length and about 2-200 aspect ratio) to form the molded article of a liq.-crystal polymer. This molded article is cleaned with an acidic soln. (sulfuric acid, etc.) for about 7-90min, cleaned with an alkaline soln. (potassium hydroxide, etc.) for 2-120min to roughen its surface and then chemically plated. Consequently, a liq. polymer molded article with the surface metallized excellent in mechanical characteristic and plating thermal cycle is obtained.

    FLAME-RETARDING POLYESTER COMPOSITION
    57.
    发明专利
    FLAME-RETARDING POLYESTER COMPOSITION 失效

    公开(公告)号：JPH04249571A

    公开(公告)日：1992-09-04

    申请号：JP14762891

    申请日：1991-06-19

    Applicant: TORAY INDUSTRIES

    Inventor： INOUE SHUNEI ,  OKAMOTO MASARU ,  ICHIKAWA YASUNORI

    IPC: C08K7/14 ,  C08L67/00 ,  C08L67/02

    Abstract: PURPOSE:To obtain a flame-retarding polyester composition improved in flame retardancy, mechanical properties and residence stability during molding by mixing a melt-anisotropic polyester with a specified polybromostyrene and a filler. CONSTITUTION:A bromostyrene monomer comprising 60wt.% or above dibromostyrene and optionally monobromostyrene and tribromostyrene is polymerized to obtain a polybromostyrene (A) mainly consisting of structural units of the formula and having a number-average molecular weight of 1X10 -30X10 , a weight-average molecular weight of 2X10 -120X10 , an apparent density of 1.0g/cm or above, a compression density of 1.1g/cm or above, and an average pore diameter of 2.5mum or below. 100 pts.wt. melt-anisotropic polyester comprising units selected from among aromatic hydroxycarboxylate units, aromatic dioxy units, aromatic dicarbonyl units, ethylenedioxy units, etc., is mixed with 0.5-60 pts.wt. polymer A and 0-200 pts.wt. filler desirably glass fiber.

    HEAT-RESISTANT RESIN COMPOSITION AND HEAT-RESISTANT TABLEWARE FOR OVEN PRODUCED BY MOLDING THE RESIN
    58.
    发明专利
    HEAT-RESISTANT RESIN COMPOSITION AND HEAT-RESISTANT TABLEWARE FOR OVEN PRODUCED BY MOLDING THE RESIN 失效

    公开(公告)号：JPH04202557A

    公开(公告)日：1992-07-23

    申请号：JP33972990

    申请日：1990-11-30

    Applicant: TORAY INDUSTRIES

    Inventor： YAMANAKA TORU ,  OKAMOTO MASARU ,  INOUE SHUNEI

    IPC: A47J36/04 ,  B29D22/00 ,  B29K67/00 ,  B29L22/00 ,  C08K3/00 ,  C08K3/34 ,  C08L67/00 ,  C08L67/02

    Abstract: PURPOSE:To obtain a heat-resistant resin composition having excellent heat- resistance and impact resistance and suitable as a heat-resistant plastic tableware for oven by compounding a specific amount of a specific talc to a copolymerized polyester having a specific structure and exhibiting liquid-crystal nature in molten state. CONSTITUTION:The objective composition is produced by compounding (A) 100 pts.wt. of a copolymerized polyester composed of the structural units of formula I to formula IV (R1 is group of formula V, etc.; R2 is group of formula VI, etc.; X is H or Cl) wherein the molar ratios of (I+II)/(I+II+III) is 80-95mol%, III/(I+II+III) is 20-5mol%, I/II is 78/ 22 to 93/7 and (II+III)/IV is 1/1, having a logarithmic viscosity of 1-3dl/g and a melting point (Tm) satisfying the formula VII [x is ratio of III/(I+II+III)] and exhibiting crystalline nature in molten state with (B) 5-200 pts.wt. of talc having an average particle diameter of 2.5-3.5mum and containing

    THERMOTROPIC LIQUID CRYSTALLINE POLYESTER RESIN COMPOSITION
    59.
    发明专利
    THERMOTROPIC LIQUID CRYSTALLINE POLYESTER RESIN COMPOSITION 失效

    公开(公告)号：JPH04189863A

    公开(公告)日：1992-07-08

    申请号：JP31877390

    申请日：1990-11-22

    Applicant: TORAY INDUSTRIES

    Inventor： OKAMOTO MASARU ,  KITAJIMA NORIO ,  INOUE SHUNEI

    IPC: C08K5/5465 ,  C08K5/54 ,  C08K5/541 ,  C08K7/14 ,  C08L67/00

    Abstract: PURPOSE:To obtain the title composition suitable for electrical and electronic parts, etc., having slight mechanical anisotropy and high weld strength by blending a thermotropic liquid crystal polyester with specific amounts of a filler and a specific isocyanate-based silane-containing compound. CONSTITUTION:(A) 100 pts.wt. thermotropic liquid crystal polyester shown by formula I to formula III or formula I to formula IV (Y is group shown by formula V, etc.; Z is group shown by formula VI, etc.) is blended with (B) 0-200 pts.wt., preferably 10-150 pts. wt. filler (e.g. glass fibers) and (C) 0.01-20 pts. wt., preferably 0.1-10 pts.wt. isocyanate-based silane-containing compound shown by formula VII (R is CH3 and/or C2H5; R is CH3; x is 2 and/ or 3).

    LIQUID CRYSTAL POLYESTER RESIN COMPOSITION
    60.
    发明专利
    LIQUID CRYSTAL POLYESTER RESIN COMPOSITION 失效

    公开(公告)号：JPH04103656A

    公开(公告)日：1992-04-06

    申请号：JP22182890

    申请日：1990-08-22

    Applicant: TORAY INDUSTRIES

    Inventor： KITAJIMA NORIO ,  OKAMOTO MASARU ,  ICHIKAWA YASUNORI

    IPC: C08K7/14 ,  C08J5/00 ,  C08L67/00

    Abstract: PURPOSE:To obtain a composition having excellent heat resistance, moldability, fluidity, high mechanical strength, especially weld strength and excellent mechanical anisotropic by blending a liquid crystal polyester comprising specific structural units with a specific amount of glass fibers of different diameter structure. CONSTITUTION:(A) 99-20wt.%, preferably 95-30wt.% anisotropic melt phase- forming liquid crystal polyester comprising structural units shown by formula I, formula II and formula IV or formula I, formula II, formula III and formula IV (R1 is group shown by formula V, etc.; R2 is group shown by formula VI, etc.; X is chlorine or H; group shown by formula IV is in an equimolar amount with groups shown by formula II and formula III, having

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