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公开(公告)号：JPS6295340A
公开(公告)日：1987-05-01
申请号：JP23510685
申请日：1985-10-23
Applicant: TORAY INDUSTRIES
Inventor： KAYABA KEIJI , MORI SATORU , YAMAMOTO YOSHIYUKI
Abstract: PURPOSE:A molding resin composition having improved molding and processing properties, providing a molded article with improved rubber characteristics, obtained by blending two polyether ester amides having different composition in a molten state. CONSTITUTION:A composition consisting of 1-99wt% polyether ester amide containing (A) Xwt% polyamide derived fro >=6C aminocarboxylic acid (preferably 11-aminoundecanoic acid), lactam or >=6C diamine and a carboxylate as a hard component and (B) 100-Xwt% polyether ester derived from a poly(alkylene oxide)glycol, preferably poly(tetramethylene oxide)glycol having 300-6,000 number-average molecular weight and 4-20C dicarboxylic acid as a soft component and 99-1wt% polyether ester amide containing Ywt% component A and 100-Ywt% component A, wherein X and Y are in a range shown by the formula.
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公开(公告)号：JPS6284141A
公开(公告)日：1987-04-17
申请号：JP22412185
申请日：1985-10-08
Applicant: TORAY INDUSTRIES
Inventor： KAYABA KEIJI , MORI SATORU , YAMAMOTO YOSHIYUKI
Abstract: PURPOSE:To obtain a composition of good appearance with high performance in flexibility, low-temperature characteristics resiliency and bleedout resistance, by incorporating a polyether-esteramide with a vinyl chloride graft copolymer. CONSTITUTION:The objective composition can be obtained by incorporating (A) 1-99wt% of a polyether esteramide derived from (i) a >=6C aminocarboxylic acid or (ii) a >=6C lactam or (iii) a salt from >=6C diamine and dicarboxylic acid and (iv) a poly (alkylene oxide) glycol with a number-average molecular weight 300-6,000 and (v) a 4-20C dicarblxylic acid with (B) 99-1wt% of a vinyl chloride graft copolymer prepared by graft copolymerization of vinyl chloride to ethylene-vinyl acetate copolymer. The EVA of the component B is preferably with such amount of the vinyl acetate copolymerized as to fall between 10 and 90wt%. The component B is preferably with such amounts the EVA and vinyl chloride copolymerized falling between 30 and 70wt% and 70 and 30wt%, respectively.
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公开(公告)号：JPS6280037A
公开(公告)日：1987-04-13
申请号：JP22074385
申请日：1985-10-03
Applicant: TORAY INDUSTRIES
Inventor： KAYABA KEIJI , KONDO MAKOTO , YAMAMOTO YOSHIYUKI
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公开(公告)号：JPS61195154A
公开(公告)日：1986-08-29
申请号：JP3453685
申请日：1985-02-25
Applicant: TORAY INDUSTRIES
Inventor： ISHII HIROMITSU , YAMAMOTO YOSHIYUKI , TANAKA HAJIME
Abstract: PURPOSE:To obtain a composition with outstanding moldability, surface gloss and mechanical properties, by incorporating metallic soap and/or silicone oil in block polyetherester copolymer derived from solid phase polymerization. CONSTITUTION:The objective composition can be obtained by incorporating (A) 100pts.wt. of a copolymer with a relative viscosity 0.8-4.5 prepared, in an inert gas or vacuum, by solid phase polymerization using, e.g. a rotary reactor, at 140-220 deg.C (pref. at a temperature lower than the melting temperature by 10-50 deg.C), of a block polyetherester copolymer derived from melt polycondensation between aromatic dicarboxylic acid (or its ester derivative), low-molecular weight glycol and poly(alkylene oxide) glycol with (B) 0.001-2 (pref. 0.005-1)pts.wt. of metallic soap (pref. stearic acid Ba salt or Al-salt) and/or (C) 0.001-2 (pref. 0.005-1)pts.wt. of silicone oil (pref. dimethyl polysiloxane).
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公开(公告)号：JPS61183352A
公开(公告)日：1986-08-16
申请号：JP2346685
申请日：1985-02-12
Applicant: TORAY INDUSTRIES
Inventor： OKITA SHIGERU , KAYABA KEIJI , YAMAMOTO YOSHIYUKI
Abstract: PURPOSE:To provide the titled compsn. having excellent impact resistance, durability and toughness, by blending a polyether ester amide with a linear arom. polyester. CONSTITUTION:At least one compd. (a) (e.g. 12-amino-dodecanoic acid) selected from among 6C or higher aminocarboxylic acids and lactams and salts of 6C or higher diamines with dicarboxylic acids, a poly(alkylene oxide) glycol (b) having a number-average MW of 300-6,000, such as poly(tetramethylene oxide) glycol, and a 4-20C dicarboxylic acid (c) such as dodecanedioic acid are solution-polymerized and the polymerization is then accelerated under high vacuum to obtain a polyether ester amide (A). 1-50wt% component A is blend ed with 99-50pts.wt. linear arom. polyester (e.g. polybutylene terephethalate) obtd. by condensing an arom. dicarboxylic acid with a diol as main components.
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Patent Agency Ranking
公开(公告)号：JPS61183345A
公开(公告)日：1986-08-16
申请号：JP2346585
申请日：1985-02-12
Applicant: TORAY INDUSTRIES
Inventor： KAYABA KEIJI , KONDO MAKOTO , YAMAMOTO YOSHIYUKI
Abstract: PURPOSE:To provide a resin compsn. having excellent moldability, impact resistance, flexibility and mechanical properties, by mixing a polyether ester amide having a specified composition with a polyacetal. CONSTITUTION:A polyether ester amide is prepd. by reacting a 6C or higher aminocarboxylic acid or lactam, or a salt of a 6C or higher diamine and a dicarboxylic acid (e.g. 11-aminoundecanoic acid) (A), a poly(alkylene oxide) glycol (B) having a number-average MW of 300-6,000 [e.g. poly(tetramethylene oxide) glycol] and a 4-20C dicarboxylic acid (C) (e.g. terephthalic acid). 99-1wt% polyether ester amide is mixed with 1-99wt% polyacetal (e.g. formal dehyde homopolymer or formaldehyde/propylene oxide copolymer) to obtain the desired resin compsn.
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公开(公告)号：JPS60228532A
公开(公告)日：1985-11-13
申请号：JP8368984
申请日：1984-04-27
Applicant: TORAY INDUSTRIES
Inventor： TANAKA CHIAKI , KONDOU MAKOTO , YAMAMOTO YOSHIYUKI
Abstract: PURPOSE:To obtain the titled amide having a high degree of polymerization and a low gel-like foreign matter content within a short time, by polycondensing a specified polyamide-forming component with a polyether-ester-forming compound in the presence of antimony oxide. CONSTITUTION:A polyether-ester-amide of a number-average MW>=15,000 is obtained by charging a reaction vessel with 99-5wt% at least one polyamide- forming compound selected from among a lactam, an aminocarboxylic acid and a salt between substantially equivalent amounts of a diamine and a dicarboxylic acid (e.g., aminododecanoic acid), 1-95wt% polyether-ester-forming component between substantially equivalent amounts of a 4-20C dicarboxylic acid and a poly(alkylene oxide) glcyol of a number-average MW of 300-5,000 and a small amount of a P compound, agitating the contents in the vessel by heating to 180-300 deg.C under a nitrogen stream to form a homogeneous mixture, adding 0.001-0.5wt% antimony oxide (e.g., Sb2O3) to this mixture and polycondensing the monomers in a molten state at 200-300 deg.C for 30min-10hr in a vacuum of 50mm.Hg or below.
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公开(公告)号：JPS57100154A
公开(公告)日：1982-06-22
申请号：JP17648780
申请日：1980-12-16
Applicant: TORAY INDUSTRIES
Inventor： YONETANI KIICHI , YAMAMOTO YOSHIYUKI , YANAGI MASAKATA
Abstract: PURPOSE:A composition that is made by adding a specific vinyl polymer and a glycidyl ester-containing copolymer to a polyalkylene terephthalate, thus being suitably used for parts of precision instrument, because of its keeping of high level of mechanical properties and of adhesion to epoxy resins. CONSTITUTION:(A) 100pts.wt. of polyalkylene terephthalate, preferably polybutylene terephthalate of 1.2-2.0 relative viscosity at 25 deg.C are kneaded under melting together with (B) 3-100pts. of a vinyl polymer with a tensile modulus of over 4,000kg/cm , consisting of a vinyl monomer of formulaI(R1 is H, lower alkyl; R2 is alkyl ester consisting of phenyl, cyano and 1-10C alkyl) and (C) 0.01-30, preferably 0.1-10pts. of a glycidyl ester-containing copolymer consisting of 1-60wt% a vinyl monomer containing glycidyl ester and 99-40wt% another vinyl monomer of formulaIat a temperature higher than the melting point of component A.
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公开(公告)号：JPS56159245A
公开(公告)日：1981-12-08
申请号：JP6243380
申请日：1980-05-12
Applicant: TORAY INDUSTRIES
Inventor： NAKAMURA SEIICHI , YAMAMOTO YOSHIYUKI , YANAGI MASAKATA
Abstract: PURPOSE:A molded polyester article, having improved antistatic properties, and obtained by using a block polyether-ester and a metallic salt of a sulfonic acid. CONSTITUTION:Polybutylene terephthalate having a relative viscosity of 1.3-2.0 is incorporated with (A) 10-45wt% block polyetherester, preferably having a melting point of about 70-220 deg.C and synthesized from terephthalic acid, isophthalic acid, 1,4-butanediol, polyethylene glycol, etc., and if necessary mixed with a heat stabilizer, and (B) 0.01-5wt% metallic salt of a sulfonic acid expressed by the formula ArSO3.1/mMe (Ar is an aromatic residue which may or may not have a substituent; m is an integer 1-3; Me is a metallic atom), preferably a sodium alkylbenzenesulfonate. The resultant mixture is then molded.
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公开(公告)号：JPS5638346A
公开(公告)日：1981-04-13
申请号：JP11450779
申请日：1979-09-06
Applicant: TORAY INDUSTRIES
Inventor： YONETANI KIICHI , YAMAMOTO YOSHIYUKI , YANAGI MASAKATA
Abstract: PURPOSE:A resin composition having improved impact resistance and weather resistance, obtained by adding a specific olefin-unsaturated acid glycidyl ester copolymer and a bisamide compound to polybutylene terephthalate. CONSTITUTION:100pts.wt. polybutylene terephthalate, preferably having a relative viscosity at 25 deg.C in 0.5wt% o-chlorophenol solution 1.2-1.8 is blended with 0.1- 100pts.wt. olefin copolymer(copolymerization amount is preferably 1-50mol%) consisting of an alpha-olefin and an alpha,beta-unsaturated acid glycidyl ester shown by the formula I (R is H or lower alkyl), and 0.001-10pts.wt. at least one bisamide compound (preferably ethylene bisstearic acid amide, etc.) shown by the formulas II-IV (R1 is 1-20C hydrocarbon; R2-R6 are 1-30C hydrocarbon) in molten state.
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