61.
    发明专利
    未知

    公开(公告)号:DE59708777D1

    公开(公告)日:2003-01-02

    申请号:DE59708777

    申请日:1997-08-26

    Applicant: BASF AG

    Abstract: A process for preparing a polyamide by reacting at least one aminonitrile with water comprises:(1) reacting at least one aminonitrile with water at a temperature from 100 to 360° C. and a pressure from 0.1 to 35x106 Pa to obtain a reaction mixture,(2) further reacting the reaction mixture at a temperature from 150 to 400° C. and a pressure which is lower than the pressure in step 1, the temperature and the pressure being selected so as to obtain a first gas phase and a first liquid or a first solid phase or a mixture of first solid and first liquid phase, and the first gas phase is separated from the first liquid or the first solid phase or from the mixture of first liquid and first solid phase, and(3) admixing the first liquid or the first solid phase or the mixture of first liquid and first solid phase with a gaseous or liquid phase comprising water at a temperature from 150 to 360° C. and a pressure from 0.1 to 30x106 Pa to obtain a product mixture.

    62.
    发明专利
    未知

    公开(公告)号:ES2178755T3

    公开(公告)日:2003-01-01

    申请号:ES97906172

    申请日:1997-03-05

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/01113 Sec. 371 Date Sep. 4, 1998 Sec. 102(e) Date Sep. 4, 1998 PCT Filed Mar. 5, 1997 PCT Pub. No. WO97/32866 PCT Pub. Date Sep. 12, 1997A noble metal-free catalyst composition is obtainable by a) preparing an aqueous mixture comprising i) a salt of at least one base metal selected from among the elements having atomic numbers 21-32, 39-42, 48-51, 57-75 and 81-83; ii) phosphate ions; and iii) at least one nitrogen source; and b) evaporating the aqueous mixture obtained and drying the catalyst composition thus formed. The catalyst composition prepared can be used for producing hydrogen peroxide and for the epoxidation of olefins.

    METHOD OF OBTAINING ALIPHATIC ALPHA, OMEGA-AMINOINITRILES

    公开(公告)号:PL181432B1

    公开(公告)日:2001-07-31

    申请号:PL32106495

    申请日:1995-12-16

    Applicant: BASF AG

    Abstract: Aliphatic alpha,omega-aminonitriles are prepared by partial hydrogenation of aliphatic alpha,omega-dinitriles at elevated temperatures and superatmospheric pressure in the presence of a solvent and of a catalyst by a process which comprises using a catalyst which (a) contains a compound based on a metal selected from the group consisting of nickel, cobalt, iron, ruthenium and rhodium and (b) contains from 0.01 to 25% by weight, based on (a), of a promoter based on a metal selected from the group consisting of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminum, tin, phosphorus, arsenic, antimony, bismuth and rare earth metals and (c) from 0 to 5% by weight, based on (a), of a compound based on an alkali metal or on an alkaline earth metal. with the proviso that the component (a) is not based on iron or iron and one of the metals selected from the group consisting of cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group consisting of titanium, manganese, chromium and molybdenum, and with the further proviso that, when a compound based on only ruthenium or rhodium or ruthenium and rhodium or nickel and rhodium is selected as component (a), the promoter (b) may be dispensed with.

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