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    Thermoplastic moulding composition based on polysulphone resins, polycarbonates, styrene- and acrylonitrile-containing copolymers and a graft copolymer
    61.
    发明专利
    Thermoplastic moulding composition based on polysulphone resins, polycarbonates, styrene- and acrylonitrile-containing copolymers and a graft copolymer 未知

    公开(公告)号：DE3601418A1

    公开(公告)日：1987-07-23

    申请号：DE3601418

    申请日：1986-01-20

    Applicant: BASF AG

    Inventor： MITULLA KONRAD DR ,  BRANDSTETTER FRANZ DR ,  HEINZ GERHARD DR ,  SEILER ERHARD DR ,  HAMBRECHT JUERGEN DR ,  BLINNE GERD DR

    IPC: C08L81/06 ,  C08L25/12 ,  C08L51/04 ,  C08L69/00

    Abstract: The invention relates to a thermoplastic moulding composition containing A from 20 to 80% by weight of a thermoplastic polysulphone resin (polyarylene-polyether-polysulphone), B from 10 to 60% by weight of a polycarbonate, C from 5 to 50% by weight of at least one copolymer based on c1) at least one vinylaromatic monomer from the group consisting of styrene, alpha -methylstyrene and p-methylstyrene, or mixtures thereof, and c2) acrylonitrile, and D from 5 to 50% by weight of at least one graft copolymer comprising, in each case based on C, d1) from 50 to 90% by weight of at least one elastomer (rubber) and d2) from 10 to 50% by weight of at least one shell grafted onto the elastomer, is characterised in that the copolymer C used contains, based on C, from 88 to 73% by weight of the vinylaromatic monomer c1) and from 12 to 27% by weight of acrylonitrile c2) in copolymerised form, and the viscosity indices are in the range from 50 to 100, and that furthermore, a graft copolymer D having a mean particle size in the range from 80 to 500 nm is used whose elastomer d1) contains, in copolymerised form, d11 at least 80% by weight of butadiene and d12 from 0 to 20% by weight of styrene and/or acrylonitrile, and whose shell c2 contains, based thereon, d21 from 90 to 10% by weight of styrene and d22 from 10 to 90% by weight of methyl methacrylate. The moulding composition is used for the production of mouldings.

    62.
    发明专利
    未知

    公开(公告)号：DE3500705A1

    公开(公告)日：1986-07-24

    申请号：DE3500705

    申请日：1985-01-11

    Applicant: BASF AG

    Inventor： FISCHER JUERGEN DR ,  ZEINER HARTMUT DR ,  NISSEN DIETMAR DR ,  HEINZ GERHARD DR

    IPC: B29B15/12 ,  B29K71/00 ,  C08G65/40 ,  C08G75/23 ,  C08J5/24 ,  C08L71/00 ,  B29C67/14

    Abstract: Fiber-reinforced materials are produced by a process in which a heat-stable thermoplastic aromatic polyether A containing reactive groups, preferably nitrile groups and/or sulfur bridges and/or arylthio or alkylthio groups, if required together with a heat-stable thermoplastic polymer B which does not contain any reactive groups, is applied onto reinforcing fibers, the resulting semi-finished product is shaped, and the plastic matrix in the molding obtained is crosslinked so that there is virturally no increase in its glass transition temperature although the amount of soluble material is decreased to less than 60%, determined by extraction in boiling dichloromethane for one hour.

    63.
    发明专利
    未知

    公开(公告)号：DE3441547A1

    公开(公告)日：1986-05-15

    申请号：DE3441547

    申请日：1984-11-14

    Applicant: BASF AG

    Inventor： SCHUETTE WILHELM DR ,  MC KEE EDMUND DR ,  HILT ALBRECHT DR ,  GOERRISSEN HEINER DR ,  HEINZ GERHARD DR

    IPC: C08L51/00 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L51/02 ,  C08L51/04 ,  C08L59/00 ,  C08L59/02 ,  C08L9/00 ,  C08J3/20

    Abstract: Impact-resistant polyoxymethylene molding materials containing (A) from 30 to 95% by weight of one or more polyoxymethylenes and (B) from 5 to 70% by weight of one or more elastomeric graft polymers which are prepared by emulsion polymerization, are dispersed in component A, have a mean particle diameter of from 0.08 to 2 mu m and are composed of 1. from 60 to 90% by weight of a grafting base of crosslinked polybutadiene in which not more than 30% by weight of the butadiene may be replaced with isoprene, 2,3-dimethylbutadiene, styrene, p-methylstyrene, alpha -methylstyrene and/or (meth)acrylonitrile, and 2. from 10 to 40% by weight of one or more grafted shells consisting of polymers of styrene and/or methyl methacrylate, in which not more than 15% by weight of the said monomers 2 may be replaced with acrylonitrile or a C1-C8-alkyl acrylate, the percentages A and B and the percentages 1 and 2 summing to 100, with or without (C) effective amounts of assistants, and a process for their preparation.

    66.
    发明专利
    未知

    公开(公告)号：ES2079011T3

    公开(公告)日：1996-01-01

    申请号：ES91115907

    申请日：1991-09-19

    Applicant: BASF AG

    Inventor： WOLF PETER DR ,  HEINZ GERHARD DR

    IPC: C07D277/66 ,  C08G65/40 ,  C08G75/23

    Abstract: Soluble and/or meltable benzothiazole-containing polyaryl ethers with a glass transition temperature of above 150 DEG C. and a melting point of up to 450 DEG C. are composed essentially of repeat units of the formula I (I) whose rings may be substituted by C1-C6-alkyl, C1-C6-alkoxy, aryl or halogen and where R is

    67.
    发明专利
    未知

    公开(公告)号：DE59106708D1

    公开(公告)日：1995-11-23

    申请号：DE59106708

    申请日：1991-07-03

    Applicant: BASF AG

    Inventor： KOCH JUERGEN DR ,  SCHUERMANN GREGOR DR ,  HEINZ GERHARD DR

    IPC: C08K5/49 ,  C08K5/521 ,  C08K5/524 ,  C08K7/02 ,  C08L71/08 ,  C08L71/12 ,  C08L101/00

    Abstract: Stabilised polyaryl ether ketone moulding composition containing, as essential constituents,… A: from 50 to 99.99 % by weight of a polyaryl ether ketone A prepared by electrophilic polycondensation and comprising at least 50 mol% of units of the formula I … … or ring-substituted C1- to C8-alkyl, C6- to C20-aryl or halogen derivatives thereof, where s and t may each adopt the value 0, 1, 2 or 3, and T and T' are -O- or -CO-,… B: from 0.01 to 4 % by weight of a phosphorus compound B containing units of the formula IIa … … or of the formula IIb … … in which the substituents and indices are as defined below:… V is oxygen or sulphur,… Q is a C1- to C25-alkyl group or a C6- to C25-aryl group, it being possible for the aromatic rings to be monosubstituted to trisubstituted by C1- to C4-alkyl groups,… Q and Q , independently of one another, are C1- to C20-alkyl groups, C1- to C20-alkoxy groups, C6- to C20-aryl or -aryloxy groups, it being possible for the abovementioned hydrocarbon radicals to be interrupted by 1 to 3 hetero atoms, such as nitrogen, oxygen or sulphur,… Ar is meta-phenylene, para-phenylene or 2 to 6 aromatic rings linked to one another in the meta- or para-position by a chemical bond or by oxygen, sulphur, a (-CO-) group, a (-SO2-) group or a (-C(CH3)2-) group, it being possible for each aromatic ring to be monosubstituted to trisubstituted by C1- to C4-alkyl groups,… Ar is meta- or para-phenylene, which may be monosubstituted to trisubstituted by C1- to C10-alkyl, C1- to C10-alkoxy, C6- to C20-aryl or C6- to C20-aryloxy groups or by halogen atoms,… X is -O-, -CO-, -S-, a (-SO2-) group, a (-C(CH3)2-) group or a chemical bond,… u,v,w are 0 or 1, and x is 0, 1 or 2,… C: up to 50 % by weight of a further thermoplastic which is different from A), and… D: up to 45 % by weight of fibrous or particulate fillers or mixtures thereof.

    68.
    发明专利
    未知

    公开(公告)号：ES2075012T3

    公开(公告)日：1995-10-01

    申请号：ES89110212

    申请日：1989-06-06

    Applicant: BASF AG

    Inventor： PIPPER GUNTER ,  SIMON GEORG NIKOLAUS DR ,  HEINZ GERHARD DR ,  ITTEMANN PETER DR ,  SCHLEIER GISBERT DR

    IPC: C08G63/66 ,  C08G63/78 ,  C08G63/80

    Abstract: Process for the continuous preparation of linear thermoplastic polyesters, in which a) a transesterification or esterification product of aliphatic and/or aromatic dicarboxylic acids having a molecular weight /l, and in step c), the precondensate is further condensed at a temperature of from 240 to 290 DEG C under a pressure of from 0.5 to 20 mm Hg and a residence time of from 10 to 40 minutes, giving polyesters which are suitable for granulation.

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