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公开(公告)号:BR0110658A
公开(公告)日:2003-02-11
申请号:BR0110658
申请日:2001-05-03
Applicant: BASF AG
Inventor: DESBOIS PHILIPPE , SCHADE CHRISTIAN , GAUSEPOHL HERMANN
IPC: C08J5/00 , C08F2/00 , C08F2/38 , C08F279/02 , C08F287/00 , C08L51/04 , C08L53/02 , D01F6/42 , C08L25/06
Abstract: The invention relates to an anionically polymerised, impact-resistant polystyrene with a dispersed plasticiser phase, comprising particles with capsule particle morphology and method for production thereof.
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公开(公告)号:ES2178784T3
公开(公告)日:2003-01-01
申请号:ES97941943
申请日:1997-08-18
Applicant: BASF AG
Inventor: FISCHER WOLFGANG , GAUSEPOHL HERMANN , KNOLL KONRAD , LATSCH STEFAN , LOTH WOLFGANG , SCHADE CHRISTIAN
IPC: C08F2/38 , C08F2/01 , C08F2/02 , C08F4/44 , C08F4/46 , C08F4/50 , C08F12/00 , C08F12/04 , C08F12/08 , C08F36/00 , C08F36/04 , C08F279/02 , C08F297/04
Abstract: A process for the continuous anionic polymerization or copolymerization of styrene or diene monomers using an alkali metal alkyl compound as polymerization initiator is carried out in the presence of an alkyl- or arylmetal compound of an element which occurs in at least divalent form as rate regulator, preferably under non-isothermal conditions and without back-mixing in a tubular or tube-bundle reactor, preferably using an alkyl- or arylmetal compound A of the formula R1M1 and an alkyl- or arylmetal compound B of the formula R2nM2 in a molar ratio between B and A of from 0.1:1 to 500:1, whereM1 is Li, Na or K;R1 is hydrogen, C1-C20-alkyl, C6-C20-aryl, or C7-C20-alkyl-substituted aryl;M2 is an n-valent element from group 2a, 2b or 3a of the Periodic Table; andR2 is hydrogen, halogen, C1-C20-alkyl or C6-C20-aryl; and a special anionic polymerization initiator containing no Lewis base.
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公开(公告)号:CA2408345A1
公开(公告)日:2002-11-06
申请号:CA2408345
申请日:2001-05-03
Applicant: BASF AG
Inventor: GAUSEPOHL HERMANN , DESBOIS PHILIPPE , SCHADE CHRISTIAN
IPC: C08J5/00 , C08F2/00 , C08F2/38 , C08F279/02 , C08F287/00 , C08L51/04 , C08L53/02 , D01F6/42 , C08L25/06
Abstract: The invention relates to an anionically polymerised, impact-resistant polystyrene with a dispersed plasticiser phase, comprising particles with capsule particle morphology and method for production thereof.
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公开(公告)号:ES2170423T3
公开(公告)日:2002-08-01
申请号:ES97950033
申请日:1997-10-28
Applicant: BASF AG
Inventor: BOCKH DIETER , JAGER HANS-ULRICH , LUX JURGEN ALFRED , STEIN STEFAN , DETERING JURGEN , SCHADE CHRISTIAN
IPC: C08F226/06 , C11D3/00 , C11D3/37 , D06P1/52 , D06P5/08
Abstract: PCT No. PCT/EP97/05939 Sec. 371 Date May 5, 1999 Sec. 102(e) Date May 5, 1999 PCT Filed Oct. 28, 1997 PCT Pub. No. WO98/21301 PCT Pub. Date May 22, 1998The use of polymers which comprise at least 5 mol % of quaternized 1-vinylimidazole units of the formula where R is C1-C25-alkyl, C5-C10-cycloalkyl or benzyl R1,R2,R3 are identical or different and are H, CH3 and C2H5, and X(-) is an anion, as color-fixing and color transfer-inhibiting additive to laundry aftertreatment aids and to detergents.
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公开(公告)号:DE10022504A1
公开(公告)日:2001-11-15
申请号:DE10022504
申请日:2000-05-10
Applicant: BASF AG
Inventor: DESBOIS PHILIPPE , SCHADE CHRISTIAN , GAUSEPOHL HERMANN
IPC: C08J5/00 , C08F2/00 , C08F2/38 , C08F279/02 , C08F287/00 , C08L51/04 , C08L53/02 , D01F6/42 , C08F12/08 , C08F279/04 , C08F257/02
Abstract: Anionically polymerized high-impact polystyrene (I) comprises a dispersed soft phase having particles with a capsular particle morphology (not defined). Independent claims are also included for: (a) mixtures of (I) and anionically or radically polymerized transparent or high-impact polystyrene; (b) a process for producing (I), comprising anionic polymerization of styrene in the presence of a styrene-butadiene diblock copolymer (II) and an anionic polymerization initiator, where (II) has a styrene block content of 40-60 wt.%; and (c) fibers, films and molded articles produced from (I).
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公开(公告)号:DE19954818A1
公开(公告)日:2001-05-17
申请号:DE19954818
申请日:1999-11-13
Applicant: BASF AG
Inventor: DEBOIS PHILIPPE , WARZELHAN VOLKER , SCHADE CHRISTIAN , FONTANILLE MICHEL , DEFFIEUX ALAIN , MENORET STEFANE
IPC: C08F2/38 , C08F2/44 , C08F4/44 , C08F4/48 , C08F4/52 , C08F4/54 , C08F12/00 , C08F12/04 , C08F36/00 , C08F36/04 , C08F291/00 , C08F297/04
Abstract: The invention relates to a method for carrying out the anionic polymerization of vinyl aromatic monomers or dienes in the presence of a lithium organyl or lithium alcoholate and a magnesium compound or an aluminum compound, whereby a sterically hindered phenol or amine is added.
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公开(公告)号:DE59702613D1
公开(公告)日:2000-12-14
申请号:DE59702613
申请日:1997-08-18
Applicant: BASF AG
Inventor: LAETSCH STEFAN , FISCHER WOLFGANG , GAUSEPOHL HERMANN , WARZELHAN VOLKER , SCHADE CHRISTIAN
IPC: C08F4/44 , C08F4/50 , C08F12/04 , C08F12/08 , C08F36/04 , C08F212/04 , C08F236/10 , C08F279/02 , C08F297/04
Abstract: The anionic polymerization of dienes or copolymers of dienes and vinylaromatic monomers in a vinylaromatic monomer or monomer mixture to give homopolydienes or copolymers or mixed homopolydienes and copolymers is carried out in the presence of a metal alkyl or aryl of an element having a valence of at least two without addition of Lewis bases.
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公开(公告)号:ES2144799T3
公开(公告)日:2000-06-16
申请号:ES96943078
申请日:1996-12-11
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , WEKEL HANS-ULRICH , SANNER AXEL , SPERLING KARIN
IPC: A61K47/32 , A61K8/72 , A61K8/81 , A61K9/10 , A61K31/74 , A61Q19/00 , C08F220/04 , C08F222/00 , C08F222/02 , C08F222/04 , C08F290/06 , C09K3/00 , C09K23/00 , C09K23/52
Abstract: PCT No. PCT/EP96/05522 Sec. 371 Date Jun. 2, 1998 Sec. 102(e) Date Jun. 2, 1998 PCT Filed Dec. 11, 1996 PCT Pub. No. WO97/21744 PCT Pub. Date Jun. 19, 1997The disclosure relates to a copolymer obtainable by radically initiated polymerization of the following: A) 70-99.9 wt. % an olefinically unsaturated C3-C5 monocarboxylic acid, an olefinically unsaturated C4-C8 dicarboxylic acid or its anhydride, or a mixture of such carboxylic acids; with B) 0.1-30 wt. % one or more multiply olefinically unsaturated carboxylic acid derivatives of formula (I)Z-Y-(CHR3-CH2-X)n-R4(I)in which Z is a vinyl or allyl group or structure (a), R1, R2 are hydrogen or methyl, R3 is hydrogen, methyl or ethyl, R4 is a singly or multiply olefinically unsaturated alkenyl or cycloalkenyl group or a singly or doubly olefinically unsaturated arylalkylene group, X is oxygen or NH, Y is oxygen, NH or N-alkyl, n is a number between 0 and 50; and C) 0-29.9 wt. % other copolymerizable monomers. The proposed copolymer can be used as a thickener or dispergent for aqueous systems.
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公开(公告)号:AU6084399A
公开(公告)日:2000-04-10
申请号:AU6084399
申请日:1999-09-16
Applicant: BASF AG
Inventor: JUNGLING STEPHAN , SCHADE CHRISTIAN , GAUSEPOHL HERMANN , WARZELHAN VOLKER , DESBOIS PHILIPPE , FONTANILLE MICHEL , DEFFIEUX ALAIN
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70.
公开(公告)号:AU2925099A
公开(公告)日:1999-09-06
申请号:AU2925099
申请日:1999-02-05
Applicant: BASF AG
Inventor: SCHADE CHRISTIAN , FISCHER WOLFGANG , GAUSEPOHL HERMANN , JUNGLING STEPHAN , WARZELHAN VOLKER , FONTANILLE MICHEL , DEFFIEUX ALAIN , DESBOIS PHILIPPE
Abstract: Disclosed are a process for the preparation of an initiator composition comprising an alkali metal organyl and an aluminum organyl and a process for the polymerization of anionically polymerizable monomers.
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