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    65.
    发明专利
    未知

    公开(公告)号：BRPI0711546A2

    公开(公告)日：2011-11-08

    申请号：BRPI0711546

    申请日：2007-04-11

    Applicant: BASF SE

    Inventor： GRAMMENOS WASSILIOS ,  GROTE THOMAS ,  DIETZ JOCHEN ,  LOHMANN JAN KLAAS ,  RENNER JENS ,  MUELLER BERND ,  ULMSCHNEIDER SARAH

    IPC: C07D401/04 ,  A01N43/707 ,  C07D401/14 ,  C07D405/14 ,  C07D409/14

    Abstract: The invention relates to 3-(pyridin-2-yl)-[1,2,4]-triazines of formula (I) and their use in the control of parasitic fungi and to herbicides that contain said compounds as an effective ingredient thereof. In formula (I), R1, R2 independently represent OH, halogen, NO2, NH2, C1-C8 alkyl, C1-C8 alkoxy, C1-C8 halogenalkyl, C1-C8 halogenalkoxy, C1-C8 alkylamino or di(C1-C8 alkyl)amino, or they form, together with the C atoms to which they are bound, a saturated five-, six- or seven-membered carbocycle or heterocycle, which, in addition to the carbon ring members, has one or two heteroatoms selected from oxygen or sulfur as the ring members, the carbocycle and the heterocycle being unsubstituted or having 1, 2, 3 or 4 C1-C4 alkyl groups as the substituents; R3 represents hydrogen, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 halogenalkyl, C1-C4 halogenalkoxy, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, or halogen; R4 represents hydrogen, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 halogenalkyl, C1-C4 halogenalkoxy or halogen; R5 represents C1-C8 alkyl, C1-C8 halogenalkyl, C1-C8 alkoxy, C1-C8 halogenalkoxy, C3-C8 cycloalkyl, C3-C8 cycloalkyloxy, five- or six-membered heteroaryl, phenyl, phenoxy, benzyl, benzyloxy, five- or six-membered heteroarylmethyl or five- or six-membered heteroaryloxy, said cyclic groups being unsubstituted or having 1, 2, 3, 4 or 5 groups Ra.

    METHOD FOR PRODUCING DIFLUOROMETHYL-SUBSTITUTED PYRAZOLE COMPOUNDS
    66.
    发明专利
    METHOD FOR PRODUCING DIFLUOROMETHYL-SUBSTITUTED PYRAZOLE COMPOUNDS 未知

    公开(公告)号：ZA201000204B

    公开(公告)日：2011-10-26

    申请号：ZA201000204

    申请日：2010-01-12

    Applicant: BASF SE

    Inventor： NETT MARKUS ,  GROTE THOMAS ,  LOHMANN JAN KLAAS ,  DIETZ JOCHEN ,  SMIDT SEBASTIAN PEER ,  RACK MICHAEL ,  ZIERKE THOMAS

    IPC: C07D20060101

    Abstract: The present invention relates to a process for preparing 3-difluoromethyl-Substituted pyrazole compounds of the formula (I) in which R1 is H, halogen, nitro, C1-C8-alkyl, C1-C8-haloalkyl, C3-C8-cycloalkyl, phenyl, naphthyl, hetaryl, cyano, —C(═O)—OR1a, —C(═O)—NR1bR1c, —C(═O)—SR1d or —C(═S)—SR1e; R2 is H, C1-C4-alkyl, benzyl or phenyl; R3 is H, halogen, C1-C8-alkoxy, C1-C8-haloalkoxy, C3-C8-cycloalkoxy, C2-C8-alkenyloxy, C1-C8-alkylthio, C1-C8-haloalkylthio, C3-C8-cyclo-alkylthio or C2-C8-alkenylthio; compounds of the formula (II.a) or (II.b), in which R1 and R3 each have one of the definitions given above; R4 is halogen, —OR4a, —SR4a, —O—SO2—R4a or an —NR4bR4c group; R5 and R6 are each C1-C8-alkyl, C1-C8-haloalkyl, C3-C8-cycloalkyl, benzyl or phenyl, or, together with the nitrogen atom to which they are bonded, are a 3- to 8-membered heterocycle; Lewis acid adducts of compounds of the formula (II.b); the use of compounds of the formula (II.a) or (II.b) and of the Lewis acid adducts for preparing compounds of the formula (I) or (VI); and to a process for converting such compounds to the corresponding 3-difluoro-pyrazol-4-ylcarboxylic acids.

    3-(PIRIDIN-2-IL)-[1,2,4]-TRIAZINAS COMO FUNGICIDAS.
    67.
    发明专利
    3-(PIRIDIN-2-IL)-[1,2,4]-TRIAZINAS COMO FUNGICIDAS. 未知

    公开(公告)号：ES2358615T3

    公开(公告)日：2011-05-12

    申请号：ES07727983

    申请日：2007-04-11

    Applicant: BASF SE

    Inventor： GRAMMENOS WASSILIOS ,  GROTE THOMAS ,  DIETZ JOCHEN ,  LOHMANN JAN KLAAS ,  RENNER JENS ,  MUELLER BERND ,  ULMSCHNEIDER SARAH

    IPC: C07D401/04 ,  A01N43/707 ,  C07D401/14 ,  C07D405/14 ,  C07D409/14

    Abstract: Compuestos de 3-(piridin-2-il)-[1,2,4]-triazina de la fórmula general I en la que: R 1 , R 2 representan independientemente uno de otro OH, halógeno, NO2, NH2, alquilo de C1-C8, alcoxi de C1-C8, haloalquilo de C1-C8, haloalcoxi de C1-C8, alquilamino de C1-C8 o di(alquil de C1-C8)amina, o conjuntamente con los átomos de C, al que están enlazados, pueden formar un carbociclo o heterociclo saturado de 5, 6 ó 7 miembros el cual tiene, además de los miembros de carbono del anillo uno o dos heteroátomos seleccionados entre oxígeno y azufre como miembros de anillo, en cuyo caso el carbociclo y el heterociclo están sin sustituir o tienen 1, 2, 3 ó 4 grupos alquilo de C1-C4 como sustituyentes; R 3 representa hidrógeno, alquilo de C1-C4, alcoxi de C1-C4, haloalquilo de C1-C4, haloalcoxi de C1-C4, cicloalquilo de C3-C6, cicloalquilmetilo de C3-C6 o halógeno; R 4 representa hidrógeno, alquilo de C1-C4, alcoxi de C1-C4, haloalquilo de C1-C4, haloalcoxi de C1-C4 o halógeno; R 5 representa alquilo de C1-C8, haloalquilo de C1-C8, alcoxi de C1-C8, haloalcoxi de C1-C8, cicloalquilo de C3-C8, cicloalquil(de C3-C8)oxi, heteroarilo de de 5 ó 6 miembros, fenilo, fenoxi, bencilo, benciloxi, heteroarilmetilo de 5 ó 6 miembros o heteroariloxi de 5 ó 6 miembros, en cuyo caso Los residuos cíclicos nombrados previamente están sin sustituir o pueden tener 1, 2, 3, 4 ó 5 residuos R a , en cuyo caso R a se selecciona entre OH, SH, halógeno, NO2, NH2, CN, COOH, alquilo de C1-C8, alcoxi de C1-C8, haloalquilo de C1-C8, haloalcoxi de C1-C8, alquilamino de C1-C8, di(alquil de C1-C8)amina, alquil(de C1-C8)tio, haloalquil(de C1­ C8)tio, alquil(de C1-C8)sulfinilo, haloalquil(de C1-C8)sulfinilo, alquil(de C1-C8)sulfonilo, haloalquil(de C1-C8)sulfonilo, cicloalquilo de C3-C8, fenilo, fenoxi y residuos de la fórmula C(=Z)R aa , donde Z representa O, S, N(alquilo de C1-C8), N(alcoxi de C1-C8), N(alqueniloxi de C3-C8) o N(alquiniloxi de C3-C8) y R aa significa hidrógeno, alquilo de C1-C8, alcoxi de C1-C8 NH2, alquilamino de C1-C8 o di(alquil de C1-C8)amino, o dos residuos R a enlazados con átomos de C adyacentes también pueden formar conjuntamente con los átomos de C, con los que están enlazados, un carbociclo saturado de 5, 6 ó 7 miembros, un anillo de benceno o un heterociclo de 5, 6 ó 7 miembros, el cual tiene como miembros de anillo, además de los carbonos miembros de anillo, uno o dos heteroátomos seleccionados entre oxígeno y azufre, en cuyo caso el carbociclo y el heterociclo están sin sustituir o tienen 1, 2, 3 ó 4 grupos alquilo de C1-C4 como sustituyentes; y las sales útiles en la agricultura de los compuestos de la fórmula I, a excepción de: 2,6-Bis-(5,6-dimetil-1,2,4-triazin-3-il)piridina; 2,6-Bis-(5,6-dietil-1,2,4-triazin-3-il)piridina; 2,6-Bis-(5,6-dipropil-1,2,4-triazin-3-il)piridina; 2,6-Bis-(5,6-diisopropil-1,2,4-triazin-3-il)piridina; 35 2,6-Bis-(5,6-dibutil-1,2,4-triazin-3-il)piridina; 2,6-Bis-(5,6-diisobutil-1,2,4-triazin-3-il)piridina; 2,6-Bis-(5,6-dipentil-1,2,4-triazin-3-il)piridina; 2,6-Bis-(5,6-dihexil-1,2,4-triazin-3-il)piridina; 2,6-Bis-(5,6-diheptil-1,2,4-triazin-3-il)piridina; 3-[6-(2,2'-bipiridil)]-5,6-dimetil-1,2,4-triazina; 3-[6-(2,2'-bipiridil)]-5,6-dietil-1,2,4-triazina; 3-[6-(2,2'-bipiridil)]-5,6-dipropil-1,2,4-triazina; 3-[6-(2,2'-bipiridil)]-5,6-dibutil-1,2,4-triazina; 5,6-Dietil-3-[6-(2-piridil)-4-metoxipiridin-2-il]-1,2,4-triazina; 3-(6-Metilpiridin-2-il)-5,6-dimetil-1,2,4-triazina; 3-(6-Metilpiridin-2-il)-5,6-dietil-1,2,4-triazina; 2,6-Bis-(5,6-dimetoxi-1,2,4-triazin-3-il)piridina; y 2,6-Bis-(5,6-dietoxi-1,2,4-triazin-3-il)piridina.

    3-(PYRIDIN-2-YL)-[1,2,4]-TRIAZINES FOR USE AS FUNGICIDES
    68.
    发明专利
    3-(PYRIDIN-2-YL)-[1,2,4]-TRIAZINES FOR USE AS FUNGICIDES 未知

    公开(公告)号：HRP20110092T1

    公开(公告)日：2011-04-30

    申请号：HRP20110092

    申请日：2011-02-04

    Applicant: BASF SE

    Inventor： GRAMMENOS WASSILIOS ,  GROTE THOMAS ,  DIETZ JOCHEN ,  LOHMANN JAN KLAAS ,  RENNER JENS ,  MUELLER BERND ,  ULMSCHNEIDER SARAH

    IPC: C07D401/04 ,  A01N43/707 ,  C07D401/14 ,  C07D405/14 ,  C07D409/14

    Abstract: The invention relates to 3-(pyridin-2-yl)-[1,2,4]-triazines of formula (I) and their use in the control of parasitic fungi and to herbicides that contain said compounds as an effective ingredient thereof. In formula (I), R1, R2 independently represent OH, halogen, NO2, NH2, C1-C8 alkyl, C1-C8 alkoxy, C1-C8 halogenalkyl, C1-C8 halogenalkoxy, C1-C8 alkylamino or di(C1-C8 alkyl)amino, or they form, together with the C atoms to which they are bound, a saturated five-, six- or seven-membered carbocycle or heterocycle, which, in addition to the carbon ring members, has one or two heteroatoms selected from oxygen or sulfur as the ring members, the carbocycle and the heterocycle being unsubstituted or having 1, 2, 3 or 4 C1-C4 alkyl groups as the substituents; R3 represents hydrogen, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 halogenalkyl, C1-C4 halogenalkoxy, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, or halogen; R4 represents hydrogen, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 halogenalkyl, C1-C4 halogenalkoxy or halogen; R5 represents C1-C8 alkyl, C1-C8 halogenalkyl, C1-C8 alkoxy, C1-C8 halogenalkoxy, C3-C8 cycloalkyl, C3-C8 cycloalkyloxy, five- or six-membered heteroaryl, phenyl, phenoxy, benzyl, benzyloxy, five- or six-membered heteroarylmethyl or five- or six-membered heteroaryloxy, said cyclic groups being unsubstituted or having 1, 2, 3, 4 or 5 groups Ra.

    69.
    发明专利
    未知

    公开(公告)号：BRPI0707107A2

    公开(公告)日：2011-04-19

    申请号：BRPI0707107

    申请日：2007-05-31

    Applicant: BASF SE

    Inventor： SMIDT SEBASTIAN PEER ,  DIETZ JOCHEN ,  KEIL MICHAEL ,  GROTE THOMAS

    IPC: C07C201/12 ,  C07C205/12 ,  C07C209/68 ,  C07C211/52

    Abstract: A process for preparing substituted biphenyls of the formula I in which the substituents are defined as follows: X is fluorine or chlorine; R1 is nitro, amino or NHR3; R2 is cyano, nitro, halogen, C1-C6-alkyl, C1-C-6-alkenyl, C1-C6-alkynyl, C1-C6-alkoxy, C1-C6-haloalkyl, C1-C6-alkylcarbonyl or phenyl; R3 is C1-C4-alkyl, C1-C4-alkenyl or C1-C4-alkynyl; n is 1, 2 or 3, where in case that n is 2 or 3, the R.sup.2 radicals may also be different, which comprises reacting the compound of the formula II in which Hal is halogen and X and R1 are as defined above, in the presence of a base and of a palladium catalyst selected from the group of:3 a) palladium-triarylphosphine or -trialkylphosphine complex with palladium in the zero oxidation state, b) salt of palladium in the presence of triarylphospine or trialkylphosphine as a complex ligand or c) metallic palladium, optionally applied to support, in the presence of triarylphosphine or trialkylphosphine, in a solvent, with a diphenylborinic acid (III) in which R2 and n are as defined above, where the triarylphosphines or trialkylphosphines used may be substituted.

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