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    METHOD FOR PRODUCING OXO-VINYL-IONOL AND O-PROTECTED DERIVATIVES THEREOF
    2.
    发明申请
    METHOD FOR PRODUCING OXO-VINYL-IONOL AND O-PROTECTED DERIVATIVES THEREOF 审中-公开
    用于生产OXOVINYLJONOL及其O型保护的衍生物

    公开(公告)号：WO2013068465A3

    公开(公告)日：2013-07-18

    申请号：PCT/EP2012072144

    申请日：2012-11-08

    Applicant: BASF SE

    Inventor： ERNST HANSGEORG ,  PUHL MICHAEL ,  BENSON STEFAN ,  SIEGEL WOLFGANG

    IPC: C07F9/54 ,  C07C403/06 ,  C07C403/08

    CPC classification number: C07C403/06 ,  C07C403/08 ,  C07F7/1856 ,  C07F9/5442 ,  Y02P20/55

    Abstract: The invention relates to the production of oxo-vinyl-ionol and O-protected derivatives thereof of formula (I), wherein R stands for hydrogen or an OH protecting group, for example a group Si(Ra)3, by reacting a compound of general formula (II), wherein R has the meanings previously specified for formula (I), i.e. beta-vinyl-ionol (formula (II), R = hydrogen) or an O-protected derivative thereof (formula (II), R = OH protecting group), with an oxidant in the presence of at least one transition metal, wherein the oxidant comprises at least one compound containing oxygen, which compound is selected from among hydrogen peroxide and organic hydroperoxides.

    Abstract translation: 本发明涉及Oxovinyljonol和式及其O-保护的衍生物（I）其中R是氢或OH-保护基团，例如基团的Si（Ra）为3，的制备由通式的化合物反应（II），其中 R具有式I，即上面给出的含义 SS-Vinyljonol（式（II）中，R =氢）或O-保护的衍生物（式（II），R = OH保护基团）与至少一种过渡金属，其中所述氧化剂包括至少一种含氧化合物的存在下的氧化剂， 从过氧化氢和有机氢过氧化物选择。

    SULFONAMIDE COMPOUNDS
    3.
    发明申请
    SULFONAMIDE COMPOUNDS 审中-公开
    磺酰胺化合物

    公开(公告)号：WO2009153285A2

    公开(公告)日：2009-12-23

    申请号：PCT/EP2009057531

    申请日：2009-06-17

    Applicant: BASF SE ,  DEYN WOLFGANG VON ,  PUHL MICHAEL ,  POHLMAN MATTHIAS ,  RACK MICHAEL ,  PARRA RAPADO LILIANA ,  LANGEWALD JUERGEN ,  ANSPAUGH DOUGLAS D ,  OLOUMI-SADEGHI HASSAN ,  CULBERTSON DEBORAH L ,  RANKL NANCY B ,  KAMP HENNICKE ,  VAN RAVENZWAAY BENNARD

    Inventor： VON DEYN WOLFGANG ,  PUHL MICHAEL ,  POHLMAN MATTHIAS ,  RACK MICHAEL ,  PARRA RAPADO LILIANA ,  LANGEWALD JUERGEN ,  ANSPAUGH DOUGLAS D ,  OLOUMI-SADEGHI HASSAN ,  CULBERTSON DEBORAH L ,  RANKL NANCY B ,  KAMP HENNICKE ,  VAN RAVENZWAAY BENNARD

    IPC: C07D417/06 ,  A01N43/80 ,  C07D417/14

    CPC classification number: C07D417/06 ,  A01N43/80 ,  C02F1/001 ,  C02F2209/03 ,  C02F2303/16 ,  C07D417/14

    Abstract: The present invention relates to sulfonamide compounds of formula (I) wherein R1 is H, halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl or C1-C6-haloalkoxy; R2 and R3 are H, halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl or C1-C6-haloalkoxy; or R2 together with R3 form a fused 5 or 6-membered carbocycle or heterocycle; R4 is halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl, C1-C6-haloalkoxy, C1-C6-haloalkylthio, C1-C6-haloalkylsulfinyl or C1-C6-haloalksulfonyl; n is 0, 1, 2 or 3; R5 is phenyl or a 5- or 6-membered heterocycle; X is O or NRx, wherein Rx is H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylcarbonyl or C1-C6-alkylcarbonyloxy; Y is N or C(Ry), wherein Ry is H, halogen, CN, C1-C6-alkyl,C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-7-cycloalkyl- C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl and C1-C6-haloalkoxy; and Z is a chemical bond, O or N(Rz), wherein Rz is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C1-C6-alkylcarbonyl or C1-C6-alkylcarbonyloxy; as well as to the N-oxides and salts thereof. These compounds are useful for combating animal pests. The invention also relates to a process for the preparation of these compounds and to intermediate compounds used in said process. The invention further relates to a method for controlling animal pests by using the compounds of formula (I), the N-oxides or the salts thereof, to plant propagation material and to an agricultural and veterinary composition comprising said compounds, the N-oxides or the salts thereof.

    Abstract translation: 本发明涉及式（I）的磺酰胺化合物，其中R1是H，卤素，CN，C1-C6-烷基，C2-C6-烯基，C2-C6-炔基，C3-C7-环烷基，C3-C7-环烷基 C 1 -C 4 - 烷基，C 1 -C 6 - 烷氧基，C 2 -C 6 - 烯氧基，C 2 -C 6 - 炔氧基，C 1 -C 6 - 烷硫基，C 2 -C 6 - 烯硫基，C 2 -C 6 - 炔硫基，C 1 -C 6 - 卤代烷基或C 1 1 -C 6 - 卤代烷氧基; R2和R3是H，卤素，CN，C1-C6-烷基，C2-C6-烯基，C2-C6-炔基，C3-C7-环烷基，C3-C7-环烷基-C1-C4-烷基，C1-C6- 烷氧基，C 2 -C 6 - 烯氧基，C 2 -C 6 - 炔氧基，C 1 -C 6 - 烷硫基，C 2 -C 6 - 烯硫基，C 2 -C 6炔硫基，C 1 -C 6卤代烷基或C 1 -C 6卤代烷氧基; 或R 2与R 3一起形成稠合的5或6元碳环或杂环; R4是卤素，CN，C1-C6-烷基，C2-C6-烯基，C2-C6-炔基，C1-C6-烷氧基，C1-C6-烷硫基，C1-C6-烷基亚磺酰基，C1-C6-烷基磺酰基，C1- C 1 -C 6卤代烷基，C 1 -C 6卤代烷硫基，C 1 -C 6卤代烷基亚磺酰基或C 1 -C 6卤代磺酰基; n为0,1,2或3; R5是苯基或5-或6-元杂环; X是O或NR x，其中Rx是H，C 1 -C 6烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基，C 3 -C 7 - 环烷基，C 1 -C 6 - 烷氧基，C 2 -C 6 - 烯氧基，C 2 -C 6 - 炔基氧基，C 1 -C 6 - 烷基羰基或C 1 -C 6烷基羰基氧基; Y是N或C（Ry），其中R y是H，卤素，CN，C 1 -C 6烷基，C 2 -C 6 - 烯基，C 2 -C 6炔基，C 3 -C 7 - 环烷基，C 3-7 - C 1 -C 6烷基，C 1 -C 6 - 烷氧基，C 2 -C 6 - 烯氧基，C 2 -C 6 - 炔氧基，C 1 -C 6 - 烷硫基，C 2 -C 6 - 烯硫基，C 2 -C 6 - 炔硫基， 卤代烷氧基; Z为化学键，O或N（Rz），其中Rz为C1-C6-烷基，C2-C6-烯基，C2-C6-炔基，C3-C7-环烷基，C1-C6-烷氧基，C2-C6 - 烯氧基，C1-C6-烷基羰基或C1-C6-烷基羰基氧基; 以及N-氧化物及其盐。 这些化合物可用于对抗动物害虫。 本发明还涉及制备这些化合物的方法和用于所述方法的中间体化合物。 本发明还涉及通过使用式（I）化合物，其N-氧化物或其盐来植物繁殖材料以及包含所述化合物，N-氧化物或其盐的农业和兽医组合物来控制动物害虫的方法 其盐。

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