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公开(公告)号:JPS62289232A
公开(公告)日:1987-12-16
申请号:JP13127486
申请日:1986-06-06
Applicant: KAO CORP
Inventor: URUSHIBATA HIDEAKI , YASUDA YUTAKA , SHIDA JUN
IPC: B01J13/00 , B01F17/52 , C08F20/34 , C08F20/52 , C08F26/06 , C08F212/00 , C08F212/14 , C08F220/34 , C08F220/60 , C08F226/06 , D21H17/05 , D21H17/17 , D21H17/35 , D21H17/37 , D21H17/44
Abstract: PURPOSE:To enhance the dispersion stability and storage stability of the title dispersion by preparing the aq. dispersion from a water-soluble copolymer consisting of a specified cationic surfactant, a cationic monomer and an aromatic vinyl monomer; and a water-insoluble substance. CONSTITUTION:From 1-15mol% cationic surfactant having a 4-28C hydrocarbonic group and a polymerizable functional group, 50-90mol% copolymerizable cationic monomer, and 1-49mol% copolymerizable aromatic vinyl monomer are allowed to react with each other to obtain a water-soluble copolymer. The water-soluble copolymer and a water-insoluble substance are mixed to prepare an aq. dispersion. An ketene dimer is appropriately used as the water-insoluble substance, and the particle diameter is appropriately controlled to
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公开(公告)号:JPS61134383A
公开(公告)日:1986-06-21
申请号:JP25525884
申请日:1984-12-03
Applicant: Kao Corp
Inventor: YASUDA YUTAKA , KONO YOSHINAO , IMANAKA TAKEHIRO , YOKOTA YUKINAGA
IPC: C07D303/36 , C07D301/27
Abstract: PURPOSE: To obtain the titled substance useful as a cation-forming agent for compounds such as cellulose, polyamine, etc., having high shelf stability, by reacting a tertiary amine with an epihalohydrin in the presence of a 1,3- dihalohydrin.
CONSTITUTION: A tertiary amine is reacted with an epihalohydrin in the presence of a 1,3-dihalohydrin to give the titled substance. 1,3-Dichloroisopropanol is preferable as the 1,3-dihalohydrin, an amount of it used is preferably 2W8mol% based on the raw material quaternary amine, a given amount of the 1,3-dihalohydrin is previously added to the epihalohydrin, or a fixed amount of the 1,3-dihalohydrin is added to the reaction mixture with time, and the reaction is carried out.
COPYRIGHT: (C)1986,JPO&JapioAbstract translation: 目的:通过在1,3-二卤代醇的存在下使叔胺与表卤代醇反应,得到具有高储存稳定性的化合物如纤维素,多胺等的阳离子形成剂的标题物质。 构成:在1,3-二卤代醇存在下,叔胺与表卤代醇反应,得到标题物质。 作为1,3-二卤代醇,优选1,3-二氯异丙醇,相对于原料季胺,其使用量优选为2-8mol%,预先向表卤代醇中加入给定量的1,3-二卤代醇 ,或固定量的1,3-二卤代醇随时间加入到反应混合物中,并进行反应。
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公开(公告)号:JP2584504B2
公开(公告)日:1997-02-26
申请号:JP31801488
申请日:1988-12-16
Applicant: KAO CORP
Inventor: OOYA NAOHIRO , TOKUNAGA HIROSHI , YASUDA YUTAKA
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公开(公告)号:JP2584495B2
公开(公告)日:1997-02-26
申请号:JP18774188
申请日:1988-07-27
Applicant: KAO CORP
Inventor: OOYA NAOHIRO , TOKUNAGA HIROSHI , YASUDA YUTAKA , MATSUI SADA
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公开(公告)号:JPH05306361A
公开(公告)日:1993-11-19
申请号:JP11132992
申请日:1992-04-30
Applicant: KAO CORP
Inventor: HOSOKAWA YASUTOKU , MITA NOBUYUKI , YASUDA YUTAKA
IPC: B65D1/00 , B65D1/02 , B65D65/38 , C08K5/06 , C08K5/36 , C08K5/375 , C08K5/41 , C08L67/00 , C08L67/02 , B65D1/09
Abstract: PURPOSE:To obtain a natural resources saving polyester container useful in case of making it highly strong or in thin wall by draw and blow molding a composition obtained by adding a specific amount of a specific compound to a polyester resin. CONSTITUTION:A resin composition obtained by adding 0.1-10(wt.) parts of a compound of formula I [A1 and A2 are C6-22 alkyl, or aralkyl; X is a single bond, formula II (R1 and R2 are H, C1-4 alkyl), SO2, etc.] (e.g. a compound of formula III) or a compound of formula IV (R3 and R4 are C6-22 alkyl; (m) and (n) are 1 =4 surface draw ratio.
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公开(公告)号:JPH0597982A
公开(公告)日:1993-04-20
申请号:JP25765491
申请日:1991-10-04
Applicant: KAO CORP
Inventor: SUZUKI FUMITO , HOSOKAWA YASUTOKU , YASUDA YUTAKA
IPC: C08G63/187 , C08G63/181
Abstract: PURPOSE:To obtain an aromatic polyester resin containing a specific dicarboxylic acid component, having moldability similar to that of PET and exhibiting excellent barrier properties to ultraviolet ray, oxygen and steam. CONSTITUTION:A polyester obtained by copolymerizing (A) dicarboxylic acid component selected from A1: terephthalic acid or its esterformable derivative and A2: bis(2-hydroxy-2-oxoethoxy)-9, 10anthraquinone of formula I or its ester- formable derivative with (B) a glycol component containing a glycol component selected from a 2-10C straight-chain aliphatic glycol as an essential component and as necessary >=20mol% other copolymerizable component, and composed of 0.1-100%, preferably 0-99.5% recurring units of formula II [(m) is integer of 2--10], 0-99.9%, preferably 0-99.5% recurring units of formula III [(n) is same as (M)], and preferably having >=0.5g/dl intrinsic viscosity (in a solvent in which weight ratio of phenol/tetrachloroethane is 60/40 at 25 deg.C).
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公开(公告)号:JPH04310720A
公开(公告)日:1992-11-02
申请号:JP7758191
申请日:1991-04-10
Applicant: KAO CORP
Inventor: HOSOKAWA YASUTOKU , SUZUKI FUMITO , AMIYA TSUYOSHI , YASUDA YUTAKA
IPC: B29B11/08 , B29C49/00 , B29C49/06 , B29C49/08 , B29C49/22 , B29C49/64 , B29K23/00 , B29K67/00 , B29K105/32 , B29L22/00 , B65D65/40
Abstract: PURPOSE:To use suitably a plastic container particularly as a food packaging container by manufacturing the plastic container having transparency, superior barrier properties against water vapor and against UV rays. CONSTITUTION:A preform composed at least of two layers consisting of a mixed polyester layer (layer A) composed of thermoplastic polyester (a) containing 80mol% or more of ethylene terephthalate and/or ethylene isophthalate unit as repeating unit and thermoplatic polyester (b) containing 20mol% or more of ethylene naphthalate unit as repeating unit and a polyolefin layer (layer B) is injection molded, and further stretch blown at least in a monoaxial direction in a temperature range of 110 deg.C-140 deg.C to manufacture a plastic multi-layer container.
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公开(公告)号:JPH04310719A
公开(公告)日:1992-11-02
申请号:JP7758091
申请日:1991-04-10
Applicant: KAO CORP
Inventor: HOSOKAWA YASUTOKU , SUZUKI FUMITO , AMIYA TSUYOSHI , YASUDA YUTAKA
IPC: B29B11/08 , B29C49/08 , B29C49/22 , B29C49/64 , B29K23/00 , B29K67/00 , B29K105/32 , B29L22/00 , B65D65/40
Abstract: PURPOSE:To use suitably a plastic container particularly as a food packaging container by manufacturing the plastic container having transparency, superior barrier properties against water vapor and against UV rays. CONSTITUTION:A peform composed of at least two layers consisting of a thermoplastic polyester layer (layer A) containing 1mol% or more to less than 80mol% of etylene naphthalate unit as repeating unit and a polyolefin layer (layer B) is injected and molded, and further stretch-blown at least in an monoaxial direction in a temperature range of 110 deg.C-140 deg.C to manufacture a multi-layer plastic container.
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公开(公告)号:JPH0494110A
公开(公告)日:1992-03-26
申请号:JP21192990
申请日:1990-08-09
Applicant: KAO CORP
Inventor: SATO MASAHARU , IMANISHI KUNIHIKO , YASUDA YUTAKA
Abstract: PURPOSE:To improve high frequency characteristics and attainment of capacity by using transition metallic salt solution of a small viscosity as oxidizer solution to be introduced to a surface of a dielectric for formation of solid electrolyte and by forming solid electrolyte by carrying out oxidation polymerization for aromatic compound on a surface of the dielectric. CONSTITUTION:A surface of a metal (Al) foil 1 which becomes an anode is etched and a micro bore is formed to enlarge a surface area thereof. A dielectric thin film 2 of metallic oxide (Al2O3) is formed along a wallside of the bore on the surface. A layer 3 of solid electrolyte which is formed by oxidation polymerization of aromatic compound using low viscosity solution of oxidizer consisting of transition metallic salt of organic acid having viscosity of 100 centipoises or less is formed on a surface of the dielectric thin film 2 to get deep into the bore. An electrode 5 of a metal (Ag paste) which becomes a cathode is attached to the other side of the layer 3 of solid electrolyte. A graphite layer 4 is used between the electrode 5 and the layer 3 of solid electrolyte for keeping good contact, and electrode leads 6 and 7 are attached.
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公开(公告)号:JPH045217A
公开(公告)日:1992-01-09
申请号:JP10823190
申请日:1990-04-24
Applicant: KAO CORP
Inventor: SUGASAWA HIROTAKE , NISHIMURA TETSUO , UEMURA TOMOHIRO , TAKANO SATOSHI , YASUDA YUTAKA
IPC: A61K8/18 , A61K8/19 , A61K8/30 , A61K8/88 , A61Q1/00 , A61Q1/02 , A61Q1/04 , A61Q1/10 , A61Q1/12 , C01F11/46 , C09C1/02 , C09C3/10
Abstract: PURPOSE:To obtain a pigment having the surface coated with an organic polymer having a specific scattering transmittance and total transmittance with brightness suppressing effects and a cosmetic, containing the aforementioned pigment blended therein and having excellent transparency, feeling of bare skin and covering power of color shading such as liver-spot and ephelis. CONSTITUTION:A pigment having the surface coated with an organic polymer with >= 70% scattering transmittance when formed into a thin film of 25 thickness at 20 wt.% powder concentration and >= 85% total transmittance. The aforementioned pigment is obtained by a method for dissolving an organic polymer (e.g. a polyamide, polyolefin or cellulose) in a good solvent such as benzene, stirring and dispersing the powder (e.g. platy barium sulfate) therein and then adding a poor solvent such as methanol, depositing the organic polymer on the powder surface, etc. A cosmetic prepared by blending the resultant pigment therein is capable of simultaneously satisfying good transparency, feeling of bare skin and covering power of liver-spot, ephelis, etc.
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