公开(公告)号：DE59603658D1

公开(公告)日：1999-12-23

申请号：DE59603658

申请日：1996-07-12

Applicant: BASF AG

Inventor： BROECKER FRANZ JOSEF ,  STROEZEL MANFRED ,  RHEUDE UDO

IPC: B01J23/44 ,  B01J35/06 ,  B01J37/02 ,  C07B61/00 ,  C07C5/08 ,  C07C5/09 ,  C07C11/02 ,  C07C29/17 ,  C07C33/02

Abstract: Prepn. of alkenes by partial hydrogenation of alkynes in the liq. phase at 20-250 degrees C and 0.3-200 bar partial hydrogen pressure using a palladium catalyst-comprises:(a) the use of a solid bed carrier-supported catalyst obtd. by tempering the carrier material in air, cooling, coating with metallic palladium under vacuum, shaping and processing into monolithic catalyst element; and (b) the addn. of 10-18 ppm carbon monoxide to the hydrogen.

公开(公告)号：DE19810671A1

公开(公告)日：1999-09-16

申请号：DE19810671

申请日：1998-03-12

Applicant: BASF AG

Inventor： RUFF DETLEF ,  BURST WOLFRAM ,  KAISER WULF ,  STROEZEL MANFRED

IPC: C07C45/72 ,  C07C45/74 ,  C07C49/603 ,  C07C49/543 ,  C07C45/68 ,  C07C45/45

Abstract: 2,5,6-trimethyl-cyclohex-2-en-1-one (I) is prepared by continuously pumping diethylketone (II), crotonaldehyde (III) and an aqueous strong base through a pressure vessel in such a fashion that the reaction temperature is 150-350 degrees C and the average residence time in the pressure vessel is only 0.1 seconds to 20 minutes. Preparation of 2,5,6-trimethyl-cyclohex-2-en-1-one (I) comprises reaction of (i) diethylketone (II) with (ii) crotonaldehyde (III) (or a compound which is converted to (III) under the selected reaction conditions), in the presence of basic agents, at elevated temperatures. Component (ii) (1 mol), component (i) (5-30 mol) and an aqueous solution or suspension of a strong base are pumped continuously, via separate supply points or in the form of a mixture, into an optionally heated pressure vessel which can guarantee intensive mixing. The components are pumped to the vessel in such a fashion that the reaction temperature is 150-350 degrees C and the average residence time in the pressure vessel is only 0.1 seconds to 20 minutes.

公开(公告)号：ES2119936T3

公开(公告)日：1998-10-16

申请号：ES94112560

申请日：1994-08-11

Applicant: BASF AG

Inventor： KAIBEL GERD ,  STROEZEL MANFRED ,  PFEFFINGER JOACHIM

IPC: B01D3/14 ,  B01D3/32

公开(公告)号：DE19611976A1

公开(公告)日：1997-10-02

申请号：DE19611976

申请日：1996-03-26

Applicant: BASF AG

Inventor： KAIBEL GERD DR ,  BROECKER FRANZ JOSEF DR ,  STROEZEL MANFRED

IPC: B01F5/06 ,  B01J8/00 ,  B01J8/06 ,  B01J8/18 ,  B01J8/20 ,  B01J8/22 ,  B01J8/34 ,  B01J19/24 ,  C07C45/62

Abstract: In carrying out reactions in a reactor containing a liquid phase in which a catalyst is suspended, and where a gaseous phase may be present, the liquid and gas phases pass, at least partly, through a device having openings or passages whose hydraulic diameter is 0.5-20 (1-3) mm. Also claimed is the reactor including a device having openings or passages in it built so that liquid or gas flow through it during the reaction.

公开(公告)号：DE19601558A1

公开(公告)日：1997-07-24

申请号：DE19601558

申请日：1996-01-17

Applicant: BASF AG

Inventor： KAIBEL GERD DR ,  STROEZEL MANFRED ,  RHEUDE UDO DR ,  GRAAUW JAN DE PROF DR ,  OLUJIC ZARKO DR ,  FREY GUENTHER ,  JANSEN HELMUT

IPC: B01D3/28 ,  B01J19/32 ,  B01D3/14

公开(公告)号：DE4328424A1

公开(公告)日：1995-03-02

申请号：DE4328424

申请日：1993-08-24

Applicant: BASF AG

Inventor： KAIBEL GERD ,  STROEZEL MANFRED ,  PFEFFINGER JOACHIM

IPC: B01D3/14 ,  B01D3/32

公开(公告)号：DE4220239A1

公开(公告)日：1993-12-23

申请号：DE4220239

申请日：1992-06-20

Applicant: BASF AG

Inventor： STROEZEL MANFRED ,  ARNOLD LOTHAR DR ,  HOERCHER ULRICH DR ,  ILLGEN WOLFGANG

IPC: B01F5/00 ,  B01F7/00 ,  B01F5/12

Abstract: An assembly to make a liquid made of ingredients including gas which may react with each other. The mixing chamber (1) is formed of a symmetrical outer mantle and two end walls (3, 5). Mixer paddles rotate within the chamber, driven by a motor. The novelty is that the mantle has a separate inlet (8, 9) for each ingredient and an outlet (10) for the mixing product; further that there is a flowpath between the two ends walls (3, 5) formed by a circular passage (17). USE/ADVANTAGE - The unit mixes ingredients including gas which may react together. The mixer is of simple construction and makes a very homogenous and stable produce with steady output.

公开(公告)号：CA1065797A

公开(公告)日：1979-11-06

申请号：CA243230

申请日：1976-01-05

Applicant: BASF AG

Inventor： BECK FRITZ ,  FRANCKE DIETHARD ,  NOHE HEINZ ,  HANNEBAUM HEINZ ,  STROEZEL MANFRED

IPC: C25B3/29 ,  C25B9/17 ,  C25B9/00

Abstract: An electrochemical cell with a nonpartitioned electrolyte chamber and plane electrodes, which form a stack, the chamber filled by the electrolyte forming narrow gaps between the electrodes, and the electrode stack being assembled on a fixed baseplate so that its axis is essentially vertical.

公开(公告)号：DE50012565D1

公开(公告)日：2006-05-24

申请号：DE50012565

申请日：2000-12-08

Applicant: BASF AG

Inventor： REIMER KLAUS ,  KAIBEL GERD DR ,  KAMMEL ULRICH DR ,  BROECKER FRANZ-JOSEF DR ,  ANSMANN ANDREAS DR ,  ETZRODT HEINZ DR ,  STROEZEL MANFRED ,  HAAKE MATHIAS DR ,  LAUPICHLER LOTHAR DR ,  BOCKSTIEGEL BERNHARD DR

IPC: C07C5/09 ,  B01J23/44 ,  B01J23/50 ,  B01J35/04 ,  B01J35/06 ,  B01J37/02 ,  B01J37/08 ,  C07B61/00 ,  C07C29/17 ,  C07C33/02 ,  C07C33/03

Abstract: Production of alkenes by liquid-phase hydrogenation of alkynes containing 10-30 carbon (C) atoms comprises using a monolithic supported palladium catalyst and hydrogen containing 10-2000 ppm carbon monoxide (CO). Production of alkenes by liquid-phase hydrogenation of alkynes containing 10-30 C atoms at 20-250 degrees C and a hydrogen partial pressure of 0.3-200 bar comprises: (a) using a fixed bed of a catalyst prepared by calcining a support material in air, cooling it, impregnating it with a solution containing a palladium salt and optionally other metal ions, drying the product and shaping it into a monolithic catalyst element; and (b) either adding 10-2000 ppm CO to the hydrogen or generating an equivalent amount of CO by adding a CO-releasing compound to the liquid phase.

公开(公告)号：ES2251916T3

公开(公告)日：2006-05-16

申请号：ES00116165

申请日：2000-08-01

Applicant: BASF AG

Inventor： BROCKER FRANZ JOSEF DR ,  HAAKE MATHIAS DR ,  KAIBEL GERD DR ,  ROHRBACHER GERD ,  SCHWAB EKKEHARD DR ,  STROEZEL MANFRED

IPC: B01J23/42 ,  B01J8/00 ,  B01J10/00 ,  B01J19/24 ,  B01J19/26 ,  B01J32/00 ,  B01J35/04 ,  B01J35/06 ,  C07B61/00 ,  C07C5/10 ,  C07C13/18 ,  F28D9/04

Abstract: Dispositivo para la realización de una hidrogenación de benceno para dar ciclohexano con participación de una fase gaseosa, que contiene hidrógeno, de una fase líquida, que contiene benceno y de una fase sólida, que contiene catalizador, que presenta - un órgano de dispersión (6), que está configurado para la generación de un fluido de reacción mediante la dispersión de una fase gaseosa en una fase líquida, - al menos un reactor (1), configurado en forma de intercambiador de calor, con entrada (31, 41) y salida (43), estando limitada la cavidad del reactor por medio de paredes disipadoras del calor, que presentan una distancia, sensiblemente constante, a lo largo del eje principal de flujo de fluido de la reacción, y estando cargado el reactor con una rejilla metálica (20, 32) recubierta de catalizador y - un conducto de alimentación (7), que conduce el fluido de la reacción desde el órgano formador de la dispersión (6) hasta la entrada del reactor (31, 41) y que tiene una longitud tan corta, que no se modifica sensiblemente el grado de dispersibilidad del fluido de la reacción en el momento del paso a través del conducto de alimentación.