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公开(公告)号:CA3050038C
公开(公告)日:2020-06-09
申请号:CA3050038
申请日:2018-01-22
Applicant: BASF SE
Inventor: MISSKE ANDREA , FLECKENSTEIN CHRISTOPH , FLEISCHHAKER FRIEDERIKE
Abstract: The invention relates to a method for producing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as a catalyst, characterised in that e) boron trifluoride is added to (meth)acrylic acid, f) the mixture is heated to a temperature of 75 to 110°C, g) norbornene is added, and h) the norbornyl-(meth)acrylate obtained is isolated from the reaction mixture. The invention further relates to a method for producing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as a catalyst, characterised in that e) boron trifluoride is added to an organic solvent, f) the mixture is heated to a temperature of 75 to 110°C, g) a mixture containing norbornene and (meth)acrylic acid is added, and h) the norbornyl-(meth)acrylate obtained is isolated from the reaction mixture.
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公开(公告)号:ES2758756T3
公开(公告)日:2020-05-06
申请号:ES08848374
申请日:2008-11-07
Applicant: BASF SE
Inventor: MISSKE ANDREA , EBERT SOPHIA , FRENZEL STEFAN , BOECKH DIETER , HUELSKOETTER FRANK , DANZIGER JAMES
Abstract: Una mezcla de polialquileniminas alcoxiladas anfifílicas solubles en agua que comprenden unidades de repetición en forma condensada de las fórmulas (I), (II), (III) y (IV)**Fórmula** en las que en cada caso indica un enlace entre un átomo de nitrógeno y la posición de unión libre de un grupo A1 de dos unidades de repetición adyacentes de las fórmulas (I), (II), (III) o (IV); y en la que las variables en cada caso se definen de la siguiente manera: A1 se selecciona de modo independiente de alquileno C2-C6 lineal o ramificado; E se selecciona de modo independiente de unidades de alquilenoxi de la fórmula (V)**Fórmula** en la que *en cada caso indica el enlace al átomo de nitrógeno de la unidad de repetición de la fórmula (I), (II) o (IV); A2 en cada caso se selecciona de modo independiente de 1,2-propileno, 1,2-butileno y 1,2-isobutileno; A3 es 1,2-propileno; R en cada caso se selecciona de modo independiente de hidrógeno y alquilo C1-C4; m tiene un valor promedio en el intervalo de 0 a 2; n tiene un valor promedio en el intervalo de 24 a 50; y p tiene un valor promedio en el intervalo de 10 a 50; las polialquileniminas alcoxiladas individuales consisten en 1 unidad de repetición de la fórmula (I), x unidades de repetición de la fórmula (II), y unidades de repetición de la fórmula (III) e y+1 unidades de repetición de la fórmula (IV), en las que x e y en cada caso tienen un valor en el intervalo de 0 a 150; y el peso molecular promedio en número de la estructura de polialquilenimina en cada caso tiene un valor en el intervalo de 60 a 10000 g/mol; y mezclas de sus productos de cuaternización.
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公开(公告)号:SG11201906757PA
公开(公告)日:2019-08-27
申请号:SG11201906757P
申请日:2018-02-09
Applicant: BASF SE
Inventor: FLECKENSTEIN CHRISTOPH , BARO JUERGEN , BECK ERICH , KALLER MARTIN , MISSKE ANDREA , FLEISCHHAKER FRIEDERIKE
IPC: B41M7/00 , C09D11/101 , C09D4/00 , C09D11/30
Abstract: INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 16 August 2018 (16.08.2018) WIP0 I PCT omit IIl °nolo iflo oimIE (10) International Publication Number WO 2018/146259 Al (51) International Patent Classification: C09D 11/101 (2014.01) C09D 4/00 (2006.01) B41M 7/00 (2006.01) CO9D 11/30 (2014.01) (21) International Application Number: PCT/EP2018/053304 (22) International Filing Date: 09 February 2018 (09.02.2018) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 17155623.6 10 February 2017 (10.02.2017) EP (71) Applicant: BASF SE [DE/DE]; Carl-Bosch-Str. 38, 67056 Ludwigshafen am Rhein (DE). (72) Inventors: FLECKENSTEIN, Christoph; Carl-Bosch- Str. 38, 67056 Ludwigshafen (DE). BARO, Juergen; Carl- Bosch-Str. 38, 67056 Ludwigshafen (DE). BECK, Erich; Carl-Bosch-Str. 38, 67056 Ludwigshafen (DE). KALLER, Martin; Carl-Bosch-Str. 38, 67056 Ludwigshafen (DE). MISSKE, Andrea; Carl-Bosch-Str. 38, 67056 Lud- wigshafen (DE). FLEISCHHAKER, Friederike; Carl- Bosch-Str. 38, 67056 Ludwigshafen (DE). = (74) Agent: RIPPEL, Hans Christoph; Isenbruck Bosl Horschler LLP Patentanwalte, EASTSITE ONE, Secken- heimer LandstraBe 4, 68163 Mannheim (DE). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Declarations under Rule 4.17: as to applicant's entitlement to apply for and be granted a patent (Rule 4.17(ii)) of inventorship (Rule 4.17(iv)) Published: with international search report (Art. 21(3)) W O 20 18/ 146 25 9 Al (54) Title: ACRYLATE-BASED MONOMERS FOR USE AS REACTIVE DILUENTS IN PRINTING FORMULATIONS (57) : The invention relates to compositions, comprising. a)1.00 to 65.00% by weight of at least one compound of formula (I), wherein R 1 , R 2 , 0 R 3 , R 4 are each independently H, C1-C6-alkyl, C1-C6-alkoxy, or C1-C6-alkoxy- (I) Ci-C6-alkyl; R is H or Ci-C6-alkyl; Xis CR6R7, 0, or NR 8 ; R 6 R are each in- 7 dependently H, C1-C6-alkyl, Ci-C6-alkoxy, or C1-C6-alkoxy-Ci-C6-alkyl; R8 0 R 5 is H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; k is 1, 2, 3, 4 or 5, as com- ponent A; b) 1.00 to 60.00% by weight of at least one monomer having two (meth)acrylate groups and having a molecular weight of no more than 500 Dal- ton, as component B; c) 0 to 25% by weight of at least one monomer having at least three (meth)acrylate groups and having a molecular weight of no more than 600 Dalton, as component C; and d) 1.00 to 30.00% by weight of at least one polymer having at least two (meth)acrylate groups and having a molecular weight of at least 700 Dalton, as component D; with the proviso that the amount of components A + B is at least 50% by weight, as well as the use of these compositions as printing inks, in particular inkjet printing inks. R1 R2 R:R4 X N
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公开(公告)号:AU2018213816A1
公开(公告)日:2019-08-22
申请号:AU2018213816
申请日:2018-01-22
Applicant: BASF SE
Inventor: MISSKE ANDREA , FLECKENSTEIN CHRISTOPH , FLEISCHHAKER FRIEDERIKE
Abstract: The invention relates to a method for producing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as a catalyst, characterised in that e) boron trifluoride is added to (meth)acrylic acid, f) the mixture is heated to a temperature of 75 to 110°C, g) norbornene is added, and h) the norbornyl-(meth)acrylate obtained is isolated from the reaction mixture. The invention further relates to a method for producing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as a catalyst, characterised in that e) boron trifluoride is added to an organic solvent, f) the mixture is heated to a temperature of 75 to 110°C, g) a mixture containing norbornene and (meth)acrylic acid is added, and h) the norbornyl-(meth)acrylate obtained is isolated from the reaction mixture.
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公开(公告)号:CA2977710A1
公开(公告)日:2016-09-01
申请号:CA2977710
申请日:2016-02-24
Applicant: BASF SE
Inventor: MISSKE ANDREA , FLEISCHHAKER FRIEDERIKE , FLECKENSTEIN CHRISTOPH , KALLER MARTIN , STENGEL ULRIK , BLANCHOT MATHIEU , STOER CLAUDIA , NAIR RITESH
IPC: C07D493/04 , C09J4/02
Abstract: The invention relates to a method for producing isosorbide ethoxylate dimethacrylate by the transesterification of alkyl(meth)acrylate with isosorbide ethoxylate, comprising the following steps: (i) ethoxylating isosorbide to isosorbide ethoxylate; (ii) permitting alkyl(meth)acrylate to react with isosorbide ethoxylate in the presence of potassium phosphate as a catalyst and of a stabilizer and in the presence of an entrainer, forming an azeotrope with the alcohol bonded in the alkyl(meth)alcylate; (iii) continuously distilling off the azeotrope that consists of entrainer and alcohol, steps (ii) and (iii) being carried out simultaneously until isosorbide ethoxylate is substantially completely converted; (iv) separating the catalyst from the isosorbide ethoxylate dimethacrylate-containing product mixture; and (v) distilling off non-converted alkyl(meth)acrylate and entrainer from the product mixture.
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公开(公告)号:ES2551739T3
公开(公告)日:2015-11-23
申请号:ES09789830
申请日:2009-06-16
Applicant: BASF SE
Inventor: JUNG ALFRED , VOELKEL LUDWIG , CREMA STEFANO , MISSKE ANDREA
Abstract: Una composición que comprende (i) una amida alcoxilada que tiene una estructura: R1-C(>=O)-N-[CH2-CH2-O-CHR2-CHR3OH][CH2CH2OH], y (ii) un éster alcoxilado que tiene una estructura: R1-C(>=O)-O-CH2-CH2-N-[CH2-CH2O-(CHR2CHR3-O)q-H][(CHR2-CHR3-O)p-H], donde R1-C(>=O) procede de aceite de coco; CHR2-CHR3O, independientemente, es**Fórmula** p + q es de 0 a 3, y donde el éster alcoxilado está presente en la composición en una cantidad de hasta un 30 partes en peso por cada 100 partes en peso de la amida alcoxilada total y éster alcoxilado.
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公开(公告)号:BRPI1006352A2
公开(公告)日:2015-08-25
申请号:BRPI1006352
申请日:2010-03-10
Applicant: BASF SE
Inventor: MISSKE ANDREA , KABAT ANDRE , BITTNER CHRISTIAN , TERRY DAVID M , ANSPAUGH DOUGLAS D , HOFFMANN MARKUS , ISHAQUE MICHAEL , RIGGS RICHARD , SENS RÜDIGER , HAREMZA SYLKE
IPC: A01N25/22 , A01N53/00 , C07D249/20
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78.
公开(公告)号:DE102014202963A1
公开(公告)日:2015-08-20
申请号:DE102014202963
申请日:2014-02-18
Applicant: BASF SE
Inventor: MISSKE ANDREA , MEISENBURG UWE , PETZOLDT JOCHEN DR , BETTE VIRGINIE , URTEL BOLETTE , BALLIN JEAN-MARC
IPC: C08G65/332
Abstract: Verfahren zur Herstellung von (Meth)acrylsäureestern (E) von Polyalkoxygruppen enthaltenden Alkoholen (A), in dem man Polyalkoxygruppen enthaltende Alkohole (P) der Formel (I) RO-[(CH2)mO]n-H(I)worin m eine ganze Zahl von 1 bis 10, n eine ganze Zahl von 1 bis 100 und R ein geradkettiger, gesättigter oder ungesättigter Alkohol mit 1 bis 30 C-Atomen bedeuten, in Gegenwart mindestens eines basischen Katalysators (K) mit einem pKB-Wert von nicht mehr als 7,0 und mindestens eines sterisch gehinderten Polymerisationsinhibtors mit einem (Meth)acrylsäureanhydrid (A) umsetzt, dadurch gekennzeichnet, dass nach Beendigung der Reaktion die Reaktionsmischung mit einem C1-C6-Alkanol gequencht wird.
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公开(公告)号:BRPI0819203A2
公开(公告)日:2015-05-05
申请号:BRPI0819203
申请日:2008-11-07
Applicant: BASF SE
Inventor: MISSKE ANDREA , EBERT SOPHIA , FRENZEL STEFAN , BOECKH DIETER , HUELSKOETTER FRANK , DANZIGER JAMES
IPC: C08G73/02
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公开(公告)号:BRPI0818460A2
公开(公告)日:2015-04-14
申请号:BRPI0818460
申请日:2008-10-17
Applicant: BASF SE
Inventor: JUNG ALFRED KARL , KUMMETER MARKUS , NORDMANN GERO , VÖLKEL LUDWIG , POSSELT DIETMAR , MISSKE ANDREA
IPC: C10L1/22 , C07C231/14 , C10L1/14 , C10L1/224
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