公开(公告)号：WO1988003915A1

公开(公告)日：1988-06-02

申请号：PCT/US1987003006

申请日：1987-11-20

Applicant: LITOVITZ, Theodore, Aaron ,  MACEDO, Pedro, B.

Inventor： LITOVITZ, Theodore, Aaron ,  HOJAJI, Hamid ,  BARKATT, Aaron

IPC: C03C11/00

CPC classification number: C03C1/002 ,  B01J39/09 ,  C01F17/0006 ,  C03C3/06 ,  C03C3/061 ,  C03C3/089 ,  C03C3/091 ,  C03C11/005 ,  C03C2201/10 ,  C03C2201/32 ,  C03C2201/40 ,  C03C2201/50 ,  G21F9/12

Abstract: An ion exchange material comprising a porous silicate glass prepared by a process which comprises producing a base glass from a melt which contains 40 to 80 mol percent silica and between 0.2 and 35 mol percent of one or more transition metals of Groups IVa, Va, VIa, VIIa and VIIIa and of the actinides, separating the base glass by heat treatment into at least a soluble phase and an insoluble phase, and leaching out the soluble glass to obtain a porous glass. In another embodiment the invention comprises a process for separating rare earth ions or actinide ions or mixtures thereof using the ion exchange material.

Abstract translation: 一种离子交换材料，其包含通过以下方法制备的多孔硅酸盐玻璃，所述多孔硅酸盐玻璃包括由含有40至80摩尔％二氧化硅和0.2至35摩尔％的IVa，Va，VIa族中的一种或多种过渡金属的熔体制备基础玻璃 ，Ⅶa和Ⅷa以及锕系元素，通过热处理将基础玻璃分离成至少可溶相和不溶相，并将可溶性玻璃浸出以获得多孔玻璃。 在另一个实施方案中，本发明包括使用离子交换材料分离稀土离子或锕系离子或其混合物的方法。

公开(公告)号：US20240150227A1

公开(公告)日：2024-05-09

申请号：US18538487

申请日：2023-12-13

Applicant: FURUKAWA ELECTRIC CO., LTD.

Inventor： Kazunori MUKASA ,  Keiichi AISO

IPC: C03C13/04 ,  G02B6/02 ,  G02B6/028

CPC classification number: C03C13/046 ,  G02B6/02395 ,  G02B6/0283 ,  C03C2201/11 ,  C03C2201/50

Abstract: An optical fiber includes a core portion made of silica-based glass; and a cladding portion made of silica-based glass having lower maximum refractive index than the core portion, the cladding portion surrounding an outer periphery of the core portion. The core portion is doped with an alkali metal element and chlorine. An average concentration of chlorine is higher than 800 atomic ppm on a cross-section perpendicular to a longitudinal direction of the core portion. A region doped with the alkali metal element is larger than a region doped with chlorine at 800 atomic ppm or higher.

公开(公告)号：US11878940B2

公开(公告)日：2024-01-23

申请号：US16992534

申请日：2020-08-13

Applicant: Corning Incorporated

Inventor： Qiang Fu ,  Qing Zhou

IPC: C03C3/097 ,  C03C13/00 ,  C03C4/00 ,  C03C17/32 ,  C03C3/087

CPC classification number: C03C3/097 ,  C03C4/0007 ,  C03C13/00 ,  C03C17/324 ,  C03C3/087 ,  C03C2201/50 ,  C03C2201/54

Abstract: A silicate-based glass composition includes: 50-70 wt. % SiO2, 0.01-10 wt. % P2O5, 10-30 wt. % Na2O, 0.01-10 wt. % CaO, 0.01-10 wt. % MO, and 15-30 wt. % R2O, such that MO is the sum of MgO, CaO, SrO, BeO, and BaO, and R2O is the sum of Na2O, K2O, Li2O, Rb2O, and Cs2O.

公开(公告)号：US20230183127A1

公开(公告)日：2023-06-15

申请号：US18064744

申请日：2022-12-12

Applicant: SCHOTT AG ,  SCHOTT Technical Glass Solutions GmbH

Inventor： Lars Mueller ,  Ruediger Dietrich ,  Thomas Pfeiffer ,  Julian Koch ,  Bernd Ruedinger ,  Meike Schneider ,  Jochen Alkemper

IPC: C03C10/00 ,  C03C3/083 ,  C03C3/085 ,  C03C3/087 ,  C03B32/02 ,  C03C21/00

CPC classification number: C03C10/0027 ,  C03C3/083 ,  C03C3/085 ,  C03C3/087 ,  C03B32/02 ,  C03C21/002 ,  C03C2203/20 ,  C03C2203/50 ,  C03C2201/50

Abstract: A cover glass made of a glass ceramic that is silica based and has a main crystal phase of high quartz solid solution or keatite solid solution is provided. The cover glass has a stress profile with at least one inflection point at a depth of the cover glass of more than 10 μm, a thickness from 0.1 mm to 2 mm, and a chemical tempering structure with a surface compressive stress of at least 250 MPa and at most 1500 MPa. A process for producing the cover glass is provided that includes producing a silica based green glass, hot shaping the silica based green glass, thermally treating the silica based green glass with a nucleation step and a ceramization step, and performing an ion exchange at an exchange bath temperature for a duration of time in an exchange bath.

公开(公告)号：US20170305781A1

公开(公告)日：2017-10-26

申请号：US15645303

申请日：2017-07-10

Applicant: SUMITOMO ELECTRIC INDUSTRIES, LTD.

Inventor： Tetsuya HARUNA ,  Yoshiaki TAMURA ,  Yoshihiro TUKUDA

IPC: C03C3/06 ,  C03C25/68 ,  C03B37/014 ,  C03B37/018 ,  G02B6/036

CPC classification number: G02B6/03694 ,  C03B37/01446 ,  C03B37/01466 ,  C03B37/01473 ,  C03B37/018 ,  C03B2203/22 ,  C03C3/06 ,  C03C13/045 ,  C03C17/02 ,  C03C25/68 ,  C03C2201/50

Abstract: One of embodiments relates to an optical fiber in which an alkali metal element is efficiently doped to its core to suppress transmission loss from increasing. A mean concentration or a concentration distribution of the alkali metal element is adjusted such that 0.48 or less is obtained as an weighted value obtained by weighting a distribution of field intensity of guided light at a wavelength of 1550 nm, with respect to a radial direction distribution of a ratio ID2/Iω3 of an intensity ID2 of Raman scattering light by a silica three-membered ring structure and an intensity Iω3 of Raman scattering light by a Si—O stretching vibration, in a cross-sectional region having a diameter of 20 μm.

公开(公告)号：US09782949B2

公开(公告)日：2017-10-10

申请号：US12427397

申请日：2009-04-21

Applicant: David Francis Dawson-Elli ,  Steven Edward DeMartino ,  Laura L Hluck

Inventor： David Francis Dawson-Elli ,  Steven Edward DeMartino ,  Laura L Hluck

IPC: B32B17/00 ,  B32B7/02 ,  E06B3/66 ,  C03C17/36 ,  G02F1/15 ,  B32B17/10 ,  B32B37/14 ,  B32B38/00 ,  G02F1/153

CPC classification number: B32B7/02 ,  B32B17/10036 ,  B32B17/10091 ,  B32B17/101 ,  B32B17/10761 ,  B32B37/14 ,  B32B38/0004 ,  C03C17/3668 ,  C03C17/3681 ,  C03C2201/50 ,  E06B3/66 ,  G02F1/1523 ,  G02F1/153 ,  G02F1/1533 ,  G02F2001/1536 ,  G02F2202/09 ,  Y10T428/2495 ,  Y10T428/24967 ,  Y10T428/26

Abstract: Laminated articles and layered articles, for example, low alkali glass laminated articles and layered articles useful for, for example, electrochromic devices are described.

公开(公告)号：US20170057867A1

公开(公告)日：2017-03-02

申请号：US15351782

申请日：2016-11-15

Applicant: SUMITOMO ELECTRIC INDUSTRIES, LTD.

Inventor： Tetsuya HARUNA ,  Masaaki HIRANO ,  Yoshiaki TAMURA ,  Tetsuya NAKANISHI

IPC: C03C13/04 ,  C03B37/027

CPC classification number: C03C13/046 ,  C03B37/02727 ,  C03B2201/50 ,  C03B2205/55 ,  C03B2205/56 ,  C03C3/06 ,  C03C13/045 ,  C03C2201/21 ,  C03C2201/23 ,  C03C2201/50 ,  C03C2203/54 ,  G02B6/02395 ,  Y02P40/57

Abstract: There is provided a method for producing a low-loss alkali metal-doped silica core optical fiber having excellent hydrogen resistance. The method for producing the optical fiber according to the present invention includes a drawing step of drawing an optical fiber preform in a drawing furnace to produce a silica glass-based optical fiber including a core region containing an alkali metal with an average concentration of 0.5 atomic ppm or more and a cladding region that surrounds the core region and a heating step of heating the optical fiber in a heating furnace through which the optical fiber drawn from the drawing furnace passes.

Abstract translation: 提供了具有优异的耐氢性的低损耗碱金属掺杂的硅芯光纤的制造方法。 根据本发明的光纤的制造方法包括在拉拔炉中拉制光纤预制件的拉拔工序，制造出含有平均浓度为0.5原子的碱金属的核心区域的石英玻璃基光纤 ppm以上的包层区域和包围芯区域的包层区域以及在从拉拔炉抽出的光纤通过的加热炉中加热光纤的加热工序。

公开(公告)号：US20160137545A1

公开(公告)日：2016-05-19

申请号：US14921487

申请日：2015-10-23

Applicant: Corning Incorporated

Inventor： Sezhian Annamalai ,  Carlos Alberto Duran ,  Kenneth Edward Hrdina

IPC: C03C3/06

CPC classification number: C03C3/06 ,  C03B19/06 ,  C03B19/12 ,  C03B19/1453 ,  C03B32/00 ,  C03B2201/10 ,  C03B2201/23 ,  C03B2201/30 ,  C03B2201/32 ,  C03B2201/40 ,  C03B2201/42 ,  C03B2201/50 ,  C03B2201/54 ,  C03C3/076 ,  C03C10/0009 ,  C03C2201/10 ,  C03C2201/23 ,  C03C2201/30 ,  C03C2201/32 ,  C03C2201/40 ,  C03C2201/42 ,  C03C2201/50 ,  C03C2201/54 ,  C03C2201/58 ,  C03C2203/54

Abstract: Ultralow expansion titania-silica glass. The glass has high hydroxyl content and optionally include one or more dopants. Representative optional dopants include boron, alkali elements, alkaline earth elements or metals such as Nb, Ta, Al, Mn, Sn Cu and Sn. The glass is prepared by a process that includes steam consolidation to increase the hydroxyl content. The high hydroxyl content or combination of dopant(s) and high hydroxyl content lowers the fictive temperature of the glass to provide a glass having a very low coefficient of thermal expansion (CTE), low fictive temperature (Tf), and low expansivity slope.

Abstract translation: 超低膨胀二氧化钛 - 二氧化硅玻璃。 玻璃具有高羟基含量，并且任选地包括一种或多种掺杂剂。 代表性的可选掺杂剂包括硼，碱元素，碱土金属元素或诸如Nb，Ta，Al，Mn，Sn Cu和Sn的金属。 玻璃通过包括蒸汽固结以增加羟基含量的方法制备。 高羟基含量或掺杂剂和高羟基含量的组合降低了玻璃的假想温度，以提供具有非常低的热膨胀系数（CTE），低假想温度（Tf）和低膨胀斜率的玻璃。

公开(公告)号：US20130116108A1

公开(公告)日：2013-05-09

申请号：US13540204

申请日：2012-07-02

Applicant: Nathan J. Cassingham ,  Ben Matthew Gauthier ,  Martin Panchula ,  Robert Stephen Pavlik ,  Yan Zhou ,  Konstantin S. Zuyev

Inventor： Nathan J. Cassingham ,  Ben Matthew Gauthier ,  Martin Panchula ,  Robert Stephen Pavlik ,  Yan Zhou ,  Konstantin S. Zuyev

IPC: C03C3/06

CPC classification number: C03C1/02 ,  C03B1/00 ,  C03B2201/075 ,  C03B2201/08 ,  C03B2201/23 ,  C03B2201/24 ,  C03B2201/31 ,  C03B2201/32 ,  C03B2201/34 ,  C03B2201/50 ,  C03B2201/54 ,  C03C3/06 ,  C03C2201/08 ,  C03C2201/23 ,  C03C2201/24 ,  C03C2201/31 ,  C03C2201/32 ,  C03C2201/34 ,  C03C2201/40 ,  C03C2201/50

Abstract: The invention relates to a silica glass compound having improved physical and chemical properties. In one embodiment, the present invention relates to a silica glass having a desirable brittleness in combination with a desirable density while still yielding a glass composition having a desired hardness and desired strength relative to other glasses. In another embodiment, the present invention relates to a silica glass composition that contains at least about 85 mole percent silicon dioxide and up to about 15 mole percent of one or more dopants selected from F, B, N, Al, Ge, one or more alkali metals (e.g., Li, Na, K, etc.), one or more alkaline earth metals (e.g., Mg, Ca, Sr, Ba, etc.), one or more transition metals (e.g., Ti, Zn, Y, Zr, Hf, etc.), one or more lanthanides (e.g., Ce, etc.), or combinations of any two or more thereof.

Abstract translation: 本发明涉及具有改善的物理和化学性质的二氧化硅玻璃化合物。 在一个实施方案中，本发明涉及具有期望的脆性以及所需密度的二氧化硅玻璃，同时仍然产生相对于其它玻璃具有所需硬度和所需强度的玻璃组合物。 在另一个实施方案中，本发明涉及二氧化硅玻璃组合物，其含有至少约85摩尔％的二氧化硅和至多约15摩尔％的选自F，B，N，Al，Ge的一种或多种掺杂剂，一种或多种 碱金属（如Li，Na，K等），一种或多种碱土金属（如Mg，Ca，Sr，Ba等），一种或多种过渡金属（如Ti，Zn，Y， Zr，Hf等），一种或多种镧系元素（例如Ce等），或其任何两种或多种的组合。

公开(公告)号：US07536076B2

公开(公告)日：2009-05-19

申请号：US11801472

申请日：2007-05-10

Applicant: Rostislav Radievich Khrapko ,  Hazel B Matthews, III

Inventor： Rostislav Radievich Khrapko ,  Hazel B Matthews, III

IPC: G02B6/00

CPC classification number: G02B6/02 ,  C03B37/01446 ,  C03B37/01453 ,  C03B37/01807 ,  C03B2201/12 ,  C03B2201/20 ,  C03B2201/50 ,  C03B2203/26 ,  C03B2203/29 ,  C03C3/06 ,  C03C2201/11 ,  C03C2201/12 ,  C03C2201/50 ,  G02B6/02014 ,  G02B6/02266

Abstract: Disclosed is an optical fiber having a silica-based core comprising an alkali metal oxide selected from the group consisting of K2O, Na2O, LiO2, Rb2O, Cs2O and mixtures thereof in an average concentration in said core between about 50 and 500 ppm by weight, said core further comprising chlorine and fluorine, wherein the average concentration of fluorine in said core is greater than the average concentration of alkali metal oxide in said core and the average concentration of chlorine in said core is greater than the average concentration of alkali metal oxide in said core; and a silica-based cladding surrounding and directly adjacent the core. By appropriately selecting the concentration of alkali metal oxide dopant in the core and the cladding, a low loss optical fiber may be obtained.

Abstract translation: 公开了一种光纤，其具有二氧化硅基核，其包含选自K2O，Na2O，LiO2，Rb2O，Cs2O及其混合物的碱金属氧化物，其中所述芯中的平均浓度为约50至500重量ppm， 所述芯还包含氯和氟，其中所述芯中的氟的平均浓度大于所述芯中的碱金属氧化物的平均浓度，并且所述芯中的平均氯浓度大于碱金属氧化物的平均浓度 说核心; 以及围绕并直接邻近芯的二氧化硅基包层。 通过适当地选择芯和包层中的碱金属氧化物掺杂剂的浓度，可以获得低损耗光纤。