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公开(公告)号：KR101284759B1
公开(公告)日：2013-07-17
申请号：KR1020100117701
申请日：2010-11-24
Applicant: 한국화학연구원 , 금호피앤비화학 주식회사
Abstract: 본 발명은 저용융점 및 고내열성의 구조로 자기소화성을 부여할 수 있는 에폭시 수지에 관한 것으로서, 보다 구체적으로는 4,4“-디히드록시-5'-페닐-메타-터페닐(4,4"-dihydroxy-5'-phenyl-m-terphenyl) 화합물을 에피할로히드린으로 에폭시화한 하기 화학식 1로 표시되는 에폭시 수지 및 이의 조성물에 관한 것으로서, 본 발명에 따른 에폭시 수지는 높은 내열성을 가지며, 성형성이 우수한 특성을 나타낸다.
[화학식 1]
상기 화학식 1에서, R
1 , R
2 는 서로 독립적으로 수소, C
1 -C
12 의 알킬, 알콕시 또는 페닐이며; n은 0-5의 정수이다.-
公开(公告)号：KR1020130039568A
公开(公告)日：2013-04-22
申请号：KR1020110104220
申请日：2011-10-12
Applicant: 한국화학연구원
IPC: C07F9/6581 , C09K21/12 , C08K5/5399 , C08L23/06
CPC classification number: C07F9/65848 , C08K5/5399 , C08L2201/02 , C08L2666/84 , C09K21/12
Abstract: PURPOSE: A cyclic organic nitrogen-phosphorus compound is provided to ensure high flame retardancy and to be used as an additive of a flame retardant or a stabilizing agent without strength reduction of a polymer material when mixing in the polymer material. CONSTITUTION: A cyclic organic nitrogen-phosphorus compound is denoted by chemical formula 1, 2, 3, or 4. A method for preparing the cyclic organic nitrogen-phosphorus compound of chemical formula 1 comprises a step of reacting phosphorous pentachloride and 1,8-diamino naphthalene under the presence of a catalyst. A method for preparing the cyclic organic nitrogen-phosphorus compound of chemical formula 2 comprises a step of reacting o-phenylene diamine with phosphorous pentachloride under the presence of a catalyst. A method for preparing the cyclic organic nitrogen-phosphorus compound of chemical formula 3 comprises a step of reacting 2-aminobenzonitrile with phosphorous pentachloride under the presence of a catalyst. A method for preparing the cyclic organic nitrogen-phosphorus compound of chemical formula 4 comprises a step of reacting o-phenylene diamine with alkyl phosphorous bichloride under the presence of a catalyst. The flame retardant resin contains the cyclic organic nitrogen-phosphorus compound and organic polymer resin.
Abstract translation: 目的：提供环状有机氮 - 磷化合物以确保高阻燃性，并且当在聚合物材料中混合时不用聚合物材料强度降低而用作阻燃剂或稳定剂的添加剂。 构成：化学式1,2,3或4表示环状有机氮磷化合物。化学式1的环状有机氮磷化合物的制备方法包括使五氯化磷与1,8- 二氨基萘在催化剂存在下进行。 制备化学式2的环状有机氮磷化合物的方法包括在催化剂存在下使邻苯二胺与五氯化磷反应的步骤。 制备化学式3的环状有机氮磷化合物的方法包括在催化剂存在下使2-氨基苄腈与五氯化磷反应的步骤。 制备化学式4的环状有机氮磷化合物的方法包括在催化剂存在下使邻苯二胺与烷基二氯化磷反应的步骤。 阻燃树脂含有环状有机氮 - 磷化合物和有机聚合物树脂。
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公开(公告)号：KR1020120100043A
公开(公告)日：2012-09-12
申请号：KR1020110018661
申请日：2011-03-02
Applicant: 한국화학연구원
Abstract: PURPOSE: A flame retardant composition is provided to be able to be applied to a thermoplastic resin with high processing temperature over 250 °C like a polyamide resin or a polyester resin because of no possibility of ignition during processing a polymer resin. CONSTITUTION: A flame retardant composition comprises melamine-based compound of bis(hydroxymethyl)phosphinate metal salt in chemical formula 1. In chemical formula 1, R is C1-6 alkyl group, C2-6 alkenyl group, or C6-12 aryl group, M is aluminum, magnesium, calcium, titanium, or gallium, n is a natural number of 2-4 which is same with an atomic number of a metal. The bis(hydroxymethyl)phosphinate metal salt is one or more selected from magnesium bis(hydroxymethyl)phosphinate, aluminum bis(hydroxymethyl)phosphinate, and aluminum bis(1-hydroxy-but-2-enyl)phosphinate.
Abstract translation: 目的：提供阻燃剂组合物，以便能够在聚酰胺树脂或聚酯树脂的加工温度超过250℃的高温下应用于热塑性树脂，因为在加工聚合物树脂期间不会发生点火。 构成：阻燃组合物包含化学式1中的双（羟甲基）次膦酸盐金属盐的三聚氰胺类化合物。在化学式1中，R为C 1-6烷基，C 2-6烯基或C 6-12芳基， M是铝，镁，钙，钛或镓，n是与金属的原子序数相同的2-4的自然数。 双（羟甲基）次膦酸盐金属盐是选自双（羟甲基）次膦酸镁，双（羟甲基）次膦酸铝和双（1-羟基丁-2-烯基）次膦酸铝中的一种或多种。
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公开(公告)号：KR1020120060695A
公开(公告)日：2012-06-12
申请号：KR1020100122320
申请日：2010-12-02
Applicant: 충남대학교산학협력단 , 한국화학연구원
IPC: C09J133/04 , C09J7/02 , C09J11/00
CPC classification number: C09J133/04 , C09J7/22 , C09J7/38 , C09J7/385 , C09J11/00 , C09J2201/606 , C09J2203/326 , C09J2205/10 , C09J2205/102
Abstract: PURPOSE: A manufacturing method of an adhesive composition is provided to provide to have simple manufacturing process, to provide adhesive composition having excellent wettability, low releasing force after ultraviolet irradiation, and excellent curing stability, and not remaining residues to an object. CONSTITUTION: A manufacturing method of an adhesive composition comprises: a step of polymerization by mixing a (meth)acrylate based monomer containing a C1-14 alkyl group, a (meth)acrylate based monomer containing a hydroxy group, a carboxy group, or a glycidiyl group, or a mixture thereof, and an initiator; and a step of addition polymerization by putting a photocurable monomer with carbon-carbon double bond having a carbon-carbon double bond, a catalyst, and polymerization inhibitor into the side chain of the polymer.
Abstract translation: 目的：提供粘合剂组合物的制造方法以提供简单的制造方法，以提供具有优异的润湿性，紫外线照射后的低释放力和优异的固化稳定性的粘合剂组合物，并且不残留在物体上。 构成：粘合剂组合物的制造方法包括：通过混合含有C 1-14烷基的（甲基）丙烯酸酯系单体，含有羟基的（甲基）丙烯酸酯系单体，羧基或 缩水甘油基或其混合物和引发剂; 以及通过将具有碳 - 碳双键的碳 - 碳双键的光固化单体，催化剂和聚合抑制剂加入到聚合物的侧链中的加成聚合步骤。
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公开(公告)号：KR1020120056134A
公开(公告)日：2012-06-01
申请号：KR1020100117701
申请日：2010-11-24
Applicant: 한국화학연구원 , 금호피앤비화학 주식회사
Abstract: PURPOSE: An epoxy resin is provided to have high flame retardance and moldability, thereby having excellent flame resistance, thereby providing an epoxy resin composition having excellent self-extinguishability, and a cured material thereof. CONSTITUTION: An epoxy resin is shown in chemical formula 1. A manufacturing method of the epoxy resin comprises: a step of obtaining halohydrin ether by mixing the 4,4"-dihydroxy-5'-phenyl-meta-terphenyl compound in chemical formula 2 and epihalohydrin; a step of conducting a reaction by adding alkali metal hydroxide into the halohydrin ether. In the chemical formulas, R1 and R2 are respectively and independently a C1-12 alkyl, alkoxy, or phenyl, and n is an integer from 0-5.
Abstract translation: 目的：提供环氧树脂以具有高阻燃性和成型性，从而具有优异的阻燃性，从而提供具有优异自熄性的环氧树脂组合物及其固化物。 构成：化学式1表示环氧树脂。环氧树脂的制造方法包括：通过在化学式2中混合4,4“ - 二羟基-5'-苯基 - 间三联苯化合物而获得卤代醇醚的步骤 在该化学式中，R 1和R 2分别独立地为C 1-12烷基，烷氧基或苯基，n为0〜0的整数， 5。
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Patent Agency Ranking
公开(公告)号：KR101109121B1
公开(公告)日：2012-02-15
申请号：KR1020090044710
申请日：2009-05-21
Applicant: 한국화학연구원
Abstract: 본 발명은 난연성이 우수한 비할로겐계 폴리아릴레이트 수지 및 이의 조성물에 관한 것이다. 더욱 자세하게 설명하면, 본 발명의 수지는 비스(4-히드록시메틸 페닐)에틴{Bis(4-hydroxymethyl phenyl)ethyne, BHPE}, 특정 구조의 프탈로일 클로라이드(phthaloyl chloride, PC) 및 특정 구조의 비스히드록시페놀{Bis(hydroxyphenyl), BHP}로 중합된 공중합 수지 및 이들을 포함하는 비할로겐계 폴리아릴레이트 수지 조성물에 관한 것이다. 본 발명의 폴리아릴레이트 수지는 일반 수지 또는 할로겐계 난연성 수지지 보다 낮은 방열율(Heat Release Capacity)을 제공하며, 환경에 유해하지 않고 유독성 물질이 없으며, 기존 할로겐계 난연제 및 난연성 수지에 보다 우수한 난연성을 제공한다. 또한, 이 발명의 고분자 수지는 일반적으로 사용하는 공업적인 용매에 용해성을 증가시켜서 사용할 수 있기 때문에, 가공성 및 상용성 우수할 뿐만 아니라, 충분한 분자량을 갖고 있는 바, 열안정성이 우수하다.
난연성, 비스(4-히드록시메틸 페닐)에틴, 폴리아릴레이트 수지, 방열량-
公开(公告)号：KR1020110081121A
公开(公告)日：2011-07-13
申请号：KR1020110051558
申请日：2011-05-30
Applicant: 한국화학연구원
Abstract: PURPOSE: A flame-retardant halogen-free polyarylate resin composition is provided to ensure excellent environment-friendliness since halogen is not contained, and to obtain a polyarylate resin with high heat resistance, enhanced solubility to a solvent, low radiation amount, and excellent flame retardancy. CONSTITUTION: A flame-retardant halogen-free polyarylate resin composition comprises: a bis(4-hydroxymethyl phenyl)ethyne compound represented by chemical formula 2; a phthaloyl chloride compound represented by chemical formula 3; and a bisphenol-A compound represented by chemical formula 4. In chemical formula 3, R1 is substituted or unsubstituted alkylene, substituted or unsubstituted phenylene, or substituted or unsubstituted arylene. In chemical formula 4, R2 is -C(O)-, -CH2-, -C(CH3)2- or - S (O) 2-.
Abstract translation: 目的：提供一种阻燃无卤多芳基化合物树脂组合物，以确保优异的环境友好性，因为不含卤素，并获得具有高耐热性，增加溶剂的溶解性，低辐射量和优异的火焰的多芳基化合物树脂 性。 构成：阻燃无卤素多芳基化合物树脂组合物包含：由化学式2表示的双（4-羟甲基苯基）乙炔化合物; 由化学式3表示的邻苯二甲酰氯化合物; 和由化学式4表示的双酚A化合物。在化学式3中，R 1是取代或未取代的亚烷基，取代或未取代的亚苯基或取代或未取代的亚芳基。 在化学式4中，R 2是-C（O） - ， - CH 2 - ， - C（CH 3）2 - 或-S（O）2 - 。
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公开(公告)号：KR1020100128047A
公开(公告)日：2010-12-07
申请号：KR1020090046479
申请日：2009-05-27
Applicant: 성균관대학교산학협력단 , 한국화학연구원
IPC: C07F9/6509 , C08K5/5399 , C08L25/04 , C08L55/02
CPC classification number: C07F9/650952 , C08K5/5399 , C08L2201/02 , C08L2666/84 , C09K21/12
Abstract: PURPOSE: A novel phosphorus piperazine and thermoplastic resin composition containing the same are provided to produce flame retardant thermoplastic resin with environmentally-friendly characteristics. CONSTITUTION: A phosphorus piperazine is denoted by chemical formula 1. The phosphorus piperazine compound is prepared by reacting the piperazine with a phosphorus compound of chemical formula 2 and adding tertiary amine. A flame retardant thermoplastic resin composition contains 100 weight parts of alloy of ABS resin, EVA resin, resin copolymer thereof, or a resin thereof and 10-50 weight parts of phosphorus piperazine compound.
Abstract translation: 目的：提供一种新型磷哌嗪和含有它们的热塑性树脂组合物，以制备具有环保特性的阻燃热塑性树脂。 构成：磷哌嗪由化学式1表示。通过使哌嗪与化学式2的磷化合物反应并加入叔胺制备磷哌嗪化合物。 阻燃热塑性树脂组合物含有100重量份的ABS树脂，EVA树脂，其树脂共聚物或其树脂和10-50重量份的磷哌嗪化合物的合金。
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公开(公告)号：KR1020100125822A
公开(公告)日：2010-12-01
申请号：KR1020090044711
申请日：2009-05-21
Applicant: 한국화학연구원
CPC classification number: C08L67/02 , C08G63/547 , C08K5/13 , C08K5/41 , C08L67/03
Abstract: PURPOSE: An environment-friendly fire-retardant polyarylate resin is provided to be environment-friendly as a halogen free material, to ensure high resistance and low heat radiation. CONSTITUTION: An environment-friendly fire-retardant polyarylate resin has a repeating unit of chemical formula 1. In chemical formula 1, R1 is hydrogen atom or C1~C5 alkyl; X is an integer of 1~4; R2 is substituted or unsubstituted alkylene, substituted or unsubstituted phenylene, or substituted or unsubstituted arylene; R3 is -C(O)-, -CH2-, -C(CH3)2- or -S(O)2-; m1 and m2 are an integer satisfying 1
Abstract translation: 目的：环保型阻燃多芳基化合物树脂作为无卤素材料提供环保，以确保高电阻和低热辐射。 构成：环保型阻燃聚芳酯树脂具有化学式1的重复单元。在化学式1中，R 1为氢原子或C 1〜C 5烷基; X为1〜4的整数; R2是取代或未取代的亚烷基，取代或未取代的亚苯基，或取代或未取代的亚芳基; R 3是-C（O） - ， - CH 2 - ， - C（CH 3）2 - 或-S（O）2 - ; m1和m2是满足1 <= m1 <= 100和0 <= m2 <= 100的整数; n是满足1 <= n <= 100的整数。
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公开(公告)号：KR100837376B1
公开(公告)日：2008-06-12
申请号：KR1020060075233
申请日：2006-08-09
Applicant: 한국화학연구원
Abstract: 본 발명은 정전하상 현상용 토너의 제조에 활용되는 구상수지 조성물에 관한 것으로서, 더욱 상세하게는 착색제, 전하제어제, 이형제 등의 배합성분을 함유하는 토너(toner) 중 상기 배합성분을 담지하는 기본 소재인 구상수지 조성물로 중합하여 대전특성을 주는 친유성 단량체에, 중합되는 구상입자 표면에 극성을 부여하기 위하여 소량의 극성 단량체를 단독 혹은 공간 넓힘용 단량체를 선택적으로 포함하고, 점착성과 내구성을 향상시키는 가교제 등을 조합하고, 이들 조성물을 분산안정제가 함유된 수상 매체에서 중합할 경우에, 구상수지의 평균 입경이 작아지고, 입도 분포의 폭이 적어지므로 균일한 크기의 입자를 얻을 수 있고, 구상입자 내ㆍ외부가 친유와 친수로 구분이 확실하게 되어 함수율이 적어, 고습 하에 있어서도 높은 대전량을 유지하고, 구상입자 표면의 극성관능기에 의해 양호한 저온 정착성을 나타내기에, 이렇게 얻어진 구상수지에 토너용 배합성분을 담지하게 되면, 인쇄 시 흐려짐을 낮게 하고, 보다 향상된 화상농도가 얻어질 수 있도록 대전효과를 효율적으로 향상시키도록 개선한 정전하상 현상용 토너에 사용되는 구상수지 조성물 및 그의 제조방법에 관한 것이다.
정전하상, 현상용, 구상수지, 토너, 대전성
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