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公开(公告)号：KR101785342B1
公开(公告)日：2017-11-15
申请号：KR1020160042666
申请日：2016-04-07
Applicant: 한국화학연구원
IPC: C07D327/02 , C07C19/08 , C07C17/38 , C07C17/383
CPC classification number: C07D327/02 , C07C17/38 , C07C17/383 , C07C19/08
Abstract: 본발명은사불화에테인-β-설톤제조용반응시스템및 이를이용한사불화에테인-β-설톤의제조방법에관한것이다. 본발명에따른사불화에테인-β-설톤제조용반응시스템및 이를이용한제조방법을이용하여상온, 상압에서안전하고용이하게고수율및 고순도로사불화에테인-β-설톤을제조할수 있으며, 급격한발열을피할수 있고동시에가압에따른공정의폭발위험성이개선되므로, 상기반응시스템및 제조방법은사불화에테인-β-설톤으로부터유래되는연료전지전해질등 에너지관련소재, 특히불소계이오노머를제조하는데유용하게사용될수 있다.
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82.发明授权폴리비닐리덴 플루오라이드 나노 입자 제조용 계면활성제, 이를 이용한 폴리비닐리덴 플루오라이드 나노 입자의 제조 방법 및 이에 따라 제조되는 폴리비닐리덴 플루오라이드 나노 입자 有权用于制备聚偏二氟乙烯纳米粒子的表面活性剂，使用其制备聚偏二氟乙烯纳米粒子的方法以及用于制备聚偏二氟乙烯纳米粒子的方法
公开(公告)号：KR101748618B1
公开(公告)日：2017-07-04
申请号：KR1020160034452
申请日：2016-03-23
Applicant: 한국화학연구원
CPC classification number: C08K5/36 , C08F2/38 , C08F14/22 , C08F2500/24 , C08J3/12
Abstract: 본발명은짧은불화탄소그룹을포함하는신규설페이트계음이온계면활성제를에멀젼중합에이용하여폴리비닐리덴플루오라이드나노입자를제조하는방법및 이에따라제조되는폴리비닐리덴플루오라이드나노입자에관한것으로, 본발명에따른신규한설페이트계음이온계면활성제는인체축적및 독성도가매우낮은짧은불화탄소그룹을지니고있어, 이를에멀젼중합에사용하여폴리비닐리덴플루오라이드나노입자를제조하는방법은기존의 APFO를사용한공정보다훨씬적은양의불소계면활성제를사용할수 있어 APFO를대체할수 있는유용한효과가있고, 본발명의폴리비닐리덴플루오라이드나노입자의제조방법은반응조건을조절하여폴리비닐리덴플루오라이드나노입자의분자량을조절하여다양한분야에서요구되는물성을충족시킬수 있어전기전자산업, 반도체산업, 디스플레이산업, 자동차산업등의분야에서유용한효과가있다.
Abstract translation: 本发明涉及一种方法，使用一种新型的基于硫酸盐的阴离子表面活性剂，包括在乳液聚合中短的氟化碳基团用于生产产生yiettara发明聚偏氟乙烯的纳米颗粒和聚偏氟乙烯的纳米颗粒 根据新颖基于硫酸盐的阴离子表面活性剂的更公平它具有主体的积累和短氟碳基dokseongdo非常低，通过使用这种乳液聚合的制造方法使用现有的APFO聚偏氟乙烯的纳米颗粒 根据本发明的聚偏二氟乙烯纳米颗粒可以通过控制反应条件以将聚偏二氟乙烯纳米颗粒的分子量调节为 它可以通过控制电气和电子工业，半导体工业，显示器来满足各个领域所需的性能 在诸如工业，汽车工业等领域中有有用的效果。
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公开(公告)号：KR1020160012642A
公开(公告)日：2016-02-03
申请号：KR1020140094489
申请日：2014-07-25
Applicant: 한국화학연구원
IPC: C08F220/22 , C08F2/24 , C08F2/38 , C08F14/00 , B01F17/52
CPC classification number: C08F2/24 , C08F2/38 , C08F14/00 , C08F220/22 , B01F17/00 , B01F17/0078
Abstract: 본발명은불소계유화제를포함하는불소계단량체의중합방법및 이에따라제조되는불소계고분자에관한것이다. 보다구체적으로는불소계단량체를중합하여불소계고분자를제조하는방법에관한것으로, 특히하기화학식 1로표시되는불소계유화제를사용하는수분산유화중합방법에관한것이다. [화학식 1][상기화학식 1에서, R은수소또는메틸이고, R는직쇄또는분쇄의알킬(C-C)이며, 알킬은헤테로시클로알킬또는아미노기로더 치환될수 있고, n은 1 내지 5의정수이며, x는몰분율로 0.05 ≤≤ 0.99이고, y는몰분율로 0.01 ≤≤ 0.60이고, z는몰분율로 0.01 ≤≤0.50이다.]
Abstract translation: 本发明涉及一种聚合氟化单体的方法，所述氟化单体包括通过该方法制备的含氟乳化剂和氟化聚合物。 更具体地说，本发明涉及通过聚合氟化单体，特别是使用由化学式1表示的含氟乳化剂的水性乳液聚合方法制备氟化聚合物的方法。在化学式1中，R 1是氢或甲基; R2是C1-C12直链或支链烷基，烷基可以进一步被杂环烷基或氨基取代; n为1〜5的整数， 和x作为摩尔分数满足0.05 <= x /（x + y + z）<= 0.99，y作为摩尔分数满足0.01 <= y /（x + y + z）<= 0.60，z为摩尔 分数满足0.01 <= z /（x + y + z）<= 0.50。 本发明的目的是提供一种聚合氟化单体的方法，所述氟化单体包括含氟乳化剂和由此制备的含氟聚合物，其具有优异的化学和热稳定性，在聚合反应期间具有高聚合速度和优异的分散稳定性和收率，并且易于控制 氟化聚合物的分子量和粒度。 本发明的另一目的是提供一种聚合氟化单体的方法，其包含毒性低，不积聚在人体内的新型环保型氟化乳化剂，由此制备氟化聚合物。 本发明的另一目的是提供聚合环境友好的氟化单体的方法，其可以通过容易地回收氟化乳化剂来降低废水处理中的成本和努力。
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公开(公告)号：KR101064664B1
公开(公告)日：2011-09-15
申请号：KR1020080118851
申请日：2008-11-27
Applicant: 한국화학연구원
IPC: C07D307/48 , B01J21/06 , B01J23/30
CPC classification number: Y02P20/544
Abstract: 본 발명은 티타니아에 담지된 텅스텐계 촉매를 이용하여 고수율로 퍼퓨랄을 제조하는 방법에 관한 것으로, 구체적으로는 자일로오즈 또는 헤미셀룰로오즈를 원료로 사용하여 퍼퓨랄을 제조하는 방법에 있어서, 초임계 유체를 포함하는 반응 매질 내에서 티타니아 지지체에 이소폴리텅스테이트(isopolytungstate)을 담지시킨 고체산 촉매체를 이용하여 원료를 퍼퓨랄로 전환시키는 단계(단계 1) 및 상기 반응 매질에 초임계 유체를 분사하여 퍼퓨랄을 추출 및 분리 시키는 단계(단계 2)를 포함하는 고수율로 퍼퓨랄을 제조하는 방법을 제공한다.
본 발명에 따른 퍼퓨랄 제조방법은 열적 안정성과 화학적 안정성이 우수한 텅스텐계 고체산 촉매를 이용하여 퍼퓨랄을 제조하여, 수율이 우수하면서도, 촉매손실율이 적어 퍼퓨랄의 제조단가를 감소시켜 퍼퓨랄 제조에 유용하게 사용할 수 있다.
고체산(solid acid), 초임계 유체(supercritical fluid), 퍼퓨랄(furfural), 티타니아(Titania), 이소폴리텅스테이트(isopolytungstate)-
公开(公告)号：KR1020100054571A
公开(公告)日：2010-05-25
申请号：KR1020080113537
申请日：2008-11-14
Applicant: 한국화학연구원
CPC classification number: Y02P20/544
Abstract: PURPOSE: A producing method of furfural is provided to improve the yield of the furfural, to reduce the fabrication cost of the furfural, and to reduce the catalyst loss rate. CONSTITUTION: A producing method of furfural using xylose or hemicellulose as a raw material comprises the following steps: converting the raw material into the furfural using a solid acid catalyst body deposited with isopolytungstate to a gamma-alumina supporting body inside a reaction medium including supercritical fluid; and extracting or separating the furfural by spraying the supercritical fluid to the reaction medium. The supercritical fluid is either supercritical carbon dioxide, or supercritical propane.
Abstract translation: 目的：提供糠醛的生产方法，以提高糠醛的产率，降低糠醛的制造成本，降低催化剂的损失率。 构成：使用木糖或半纤维素作为原料的糠醛的制造方法包括以下步骤：使用沉积有异多钨酸盐的固体酸催化剂体将原料转化为糠醛至包含超临界流体的反应介质内的γ-氧化铝负载体 ; 并通过将超临界流体喷射到反应介质中来提取或分离糠醛。 超临界流体是超临界二氧化碳或超临界丙烷。
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Patent Agency Ranking
公开(公告)号：KR1020090022947A
公开(公告)日：2009-03-04
申请号：KR1020070088667
申请日：2007-08-31
Applicant: 한국화학연구원
Abstract: A method and an apparatus for evaluating performance of heterogeneous catalysts are provided to evaluate the performance of a catalyst acting on the elementary reaction to be evaluated objectively, by separating the reaction product progressing the side reaction easily from its environment by inducing supercritical fluid to a heterogeneous catalytic reaction system. An apparatus for evaluating performance of heterogeneous catalysts comprises a supercritical fluid supply device(100), catalytic reactor(300) and recovery device(400). The supercritical fluid supply device supplies the supercritical fluid. The catalytic reactor causes the reaction by a catalyst in a state that reaction raw materials are injected, and discharges the reaction products through a fluid supply tube of the supercritical fluid supply device. The recovery device separates and recovers the liquefied reaction products from the supercritical fluid by being supplied with the supercritical fluid dissolved with the reaction products.
Abstract translation: 提供了一种用于评估非均相催化剂性能的方法和装置，以评价客观评价作用于元素反应的催化剂的性能，通过将反应产物从其环境容易地分离，从而将超临界流体诱导到异质 催化反应体系。 用于评估非均相催化剂性能的装置包括超临界流体供应装置（100），催化反应器（300）和回收装置（400）。 超临界流体供应装置供应超临界流体。 催化反应器在反应原料注入的状态下通过催化剂进行反应，并通过超临界流体供给装置的流体供给管排出反应产物。 回收装置通过供给与反应产物一起溶解的超临界流体从超临界流体中分离和回收液化的反应产物。
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公开(公告)号：KR100879635B1
公开(公告)日：2009-01-21
申请号：KR1020070085923
申请日：2007-08-27
Applicant: 한국화학연구원
Abstract: A method for separating acetone is provided to reduce waste treatment costs of an organic solvent generated in a manufacturing process of water soluble polyurethane and to save the production costs of a manufacturing process of water soluble polyurethane by recycling the refined organic solvent. A method for separating acetone comprises a step for distilling a waste acetone compound to be a moisture content of 0.1-5 wt.%; a step for producing an amine salt by neutralizing the distilled waste acetone mixture with an organic acid; and a step for separating and collecting the acetone by distilling the reaction mixture containing the amine salt.
Abstract translation: 提供分离丙酮的方法，以减少在水溶性聚氨酯的制造过程中产生的有机溶剂的废物处理成本，并且通过再循环精制有机溶剂来节省水溶性聚氨酯的制造工艺的生产成本。 分离丙酮的方法包括将废丙酮化合物蒸馏成含水量为0.1-5重量％的步骤; 通过用有机酸中和蒸馏的废丙酮混合物来生产胺盐的步骤; 以及通过蒸馏含有胺盐的反应混合物来分离和收集丙酮的步骤。
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公开(公告)号：KR100428749B1
公开(公告)日：2004-04-28
申请号：KR1020020013209
申请日：2002-03-12
Applicant: 한국화학연구원
IPC: C10L10/02
Abstract: PURPOSE: A new combustion supporting catalytic liquid composition is provided to greatly improve complete solution stabilization and combustion dust suppressing functions of the composition by selecting a particular aromatic solvent as a primary base solvent, thereby enabling solubilization and stabilization at the same time. CONSTITUTION: In a combustion supporting catalytic composition for suppressing combustion dust containing ferrocene, the combustion supporting catalytic liquid composition for suppressing combustion dust is characterized in that the composition comprises 60 to 90 wt.% of aromatic solvent as a primary base solvent, and 1.0 to 12.0 wt.% of ferrocene as a combustion supporting catalyst, wherein the primary base solvent is C9 aromatic distillate of petrochemical process or mixed solvent of aromatic hydrocarbons prepared by using the C9 aromatic distillate of petrochemical process as raw material, wherein the primary base solvent is mixed xylene distillate comprising ethyl benzene and meta-xylene, wherein the primary base solvent comprises meta-xylene, wherein the primary base solvent includes benzene, and includes toluene and alkyl benzene at the same time, wherein the primary base solvent comprises 10 to 25 wt.% of alkyl benzene for the weight of benzene and 45 to 85 wt.% of toluene for the weight of benzene at the same time, and wherein the combustion supporting catalytic composition comprises aliphatic solvent as well as aromatic solvent as solvent constituents.
Abstract translation: 目的：提供一种新的助燃催化液体组合物，通过选择特定的芳族溶剂作为主要的基础溶剂，从而大大改善组合物的完全溶液稳定性和燃烧粉尘抑制功能，从而使溶解和稳定化同时成为可能。 一种用于抑制含二茂铁的燃烧粉尘的助燃催化剂组合物，其特征在于该组合物含有60-90％ 以二茂铁12.0重量％为助燃剂，其中一级碱溶剂为石化工艺C9芳烃馏分或以石化工艺C9芳烃馏分为原料制备的芳烃混合溶剂，其中一级碱性溶剂为 包含乙苯和间二甲苯的混合二甲苯馏出物，其中所述主要碱溶剂包含间二甲苯，其中所述主要碱溶剂包含苯，并且同时包含甲苯和烷基苯，其中所述主要碱溶剂包含10-25重量％ 对于苯的重量，烷基苯的百分数和对于t的45-85重量％的甲苯 苯重量，并且其中所述助燃催化组合物包含脂族溶剂以及芳族溶剂作为溶剂组分。
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公开(公告)号：KR100383217B1
公开(公告)日：2003-05-12
申请号：KR1019990020730
申请日：1999-06-04
Applicant: 한국화학연구원
IPC: C07C209/86
Abstract: 본 발명은 톨루엔디아민의 제조 회수방법에 관한 것으로서, 더욱 상세하게는 톨루엔디아민(TDA)을 포스겐화하여 톨루엔디이소시아네이트(TDI)를 제조하는 화학 공정에서의 부반응 생성물로 얻어지는 고비점 타르(tar) 폐기물을, 물의 임계 온도와 임계 압력 전후의 고온 고압의 화학 반응 조건에서 암모니아 수용액을 반응성 매질로 사용하여 분해하여 고가의 원료 톨루엔디아민(TDA)으로 전환하여 제조 회수하는 방법에 관한 것이다.
이로써 본 발명에 따른 방법은 폐기물 처리 비용을 절감하고 매립지 부족 문제를 완화할 수 있으며, 궁극적으로는 톨루엔디이소시아네이트(TDI) 제조 공정의 경제성을 제고할 수 있다.-
公开(公告)号：KR1020030003833A
公开(公告)日：2003-01-14
申请号：KR1020010039665
申请日：2001-07-04
Applicant: 한국화학연구원
CPC classification number: B01D65/06 , B01D61/025 , B01D61/364 , B01D2313/46 , B01D2321/16 , C02F1/44
Abstract: PURPOSE: A maintenance of membranes by prefiltration at high pressure and by cleaning their microstructures with supercritical fluids is provided, in which contamination of main separation membrane is minimized by cleaning the pre-treatment filtration media, with the cleaning being conducted by stabilizing and forcibly adsorbing the hydrophilic or hydrophobic contaminants at high pressure of 2 to 20 atm higher than the saturation pressure of bubble. And the regeneration of main separation membrane is conducted within a shortened time by washing the surface and pore inside of the separation membrane by using supercritical fluids without any restrictions of sort, figure, process concerning with the separation membrane. CONSTITUTION: The method comprises two steps of minimizing contamination of the pre-treatment separation membrane and regeneration performance of the main separation membrane. The minimization method comprises stabilizing the subject material to separate at a state of 2 to 20 atm higher than the saturation pressure of bubble at the pre-treatment filter media consisting of the same separation membrane or similar material from the hydrophilic or hydrophobic point of view followed by forcible adsorption. The regeneration method of performance of the separation membrane comprises washing the surface and pore inside of the separation membrane by using supercritical fluid of supercritical carbon dioxide or reformed supercritical fluid reformed by methanol, ethanol, and isopropanol followed by drying.
Abstract translation: 目的：通过高压预过滤和通过用超临界流体清洗其微结构来提供膜的维护，其中通过清洁预处理过滤介质使主分离膜的污染最小化，通过稳定和强制吸附进行清洁 在高于气泡的饱和压力的2至20个大气压的高压下的亲水或疏水污染物。 并且主分离膜的再生通过使用超临界流体清洗分离膜内部的表面和孔隙而在缩短的时间内进行，而不受分离膜的分类，图形化处理的限制。 构成：该方法包括两个步骤：最大限度地减少预处理分离膜的污染和主分离膜的再生性能。 最小化方法包括将主体材料稳定在高于来自亲水或疏水视点的相同分离膜或类似材料组成的预处理过滤介质下的气泡的饱和压力的2至20个大气压的状态下分离，随后 通过强制吸附。 分离膜的再生方法包括使用超临界二氧化碳的超临界流体或由甲醇，乙醇和异丙醇重整的重整超临界流体洗涤分离膜的表面和孔，然后干燥。
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