公开(公告)号：CA2543673A1

公开(公告)日：2005-05-12

申请号：CA2543673

申请日：2004-10-28

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  SCHEIDEL JENS ,  LUYKEN HERMANN ,  FLORES MIGUEL ANGEL ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  SIEGEL WOLFGANG

IPC: C07F9/50 ,  B01J31/18 ,  B01J31/24 ,  C07C253/10 ,  C07C253/30 ,  C07C255/07 ,  C07C255/09 ,  C07F9/12 ,  C07F9/48 ,  C07F9/6574

Abstract: The invention relates to phosphinite phosphites I of formula 1, 2, 3, 4, 5 or 6 and mixtures thereof, wherein R1, R2, R4 independently represent an alkyl or alkylene group with 1 to 8 carbon atoms, provided that at least one of the groups R1, R2, R4 is different from H; R5 to R22 independently represent H, an alkyl or alkylene group with 1 to 8 carbon atoms; R3 is H, methyl or ethyl; X is F, Cl or CF3, if n=1 or 2 and X is H, if n=0.

公开(公告)号：DE10314761A1

公开(公告)日：2004-10-14

申请号：DE10314761

申请日：2003-03-31

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  MOLNAR FERENC

IPC: B01J23/755 ,  B01J31/02 ,  B01J31/14 ,  B01J31/18 ,  C07C253/10 ,  C07C255/04 ,  B01J31/12 ,  B01J31/24 ,  C07B43/08

Abstract: A system which is suitable as a catalyst for the hydrocyanation of olefinically unsaturated compounds and comprises a) Ni(0) b) a compound which complexes Ni(0) as a ligand and contains trivalent phosphorus, c) a Lewis acid and d) a compound of the formula M Rn where M: Al or Ti R: identical or different monovalent alkoxy radicals, in which case a plurality of alkoxy radicals may be bonded together, and additionally, in the case that M=Al, R may be identical or different monovalent alkyl radicals, in which case a plurality of alkyl radicals may be bonded together or one or more alkyl radicals may be bonded to one or more of the abovementioned alkoxy radicals, n: valency of M, and processes for hydrocyanating an olefinically unsaturated compound in the presence of such a system.

公开(公告)号：DE10311119A1

公开(公告)日：2004-09-23

申请号：DE10311119

申请日：2003-03-12

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE

IPC: C07C255/07 ,  C07C253/30

Abstract: Isomerization of 2-methyl-3-butenonitrile (I) to linear pentenonitrile (II) in the presence of zero-valent nickel, a tridentate phosphorus ligand and a Lewis acid comprises removing a mixture of (I) and (II) from the reaction mixture during isomerization.

公开(公告)号：CA2506794A1

公开(公告)日：2004-06-10

申请号：CA2506794

申请日：2003-11-27

Applicant: BASF AG

Inventor： SIEGEL WOLFGANG ,  GOEBBEL HANS-GEORG ,  HADERLEIN GERD

IPC: B01D1/22 ,  B01D3/14 ,  B01D3/32 ,  C07C45/60 ,  C07C45/71 ,  C07C45/82 ,  C07D317/26 ,  C07C47/198

Abstract: The invention relates to a method for producing a pure aliphatic dialdehyde monoacetal by reacting the corresponding aliphatic dialdehyde or a precursor of the corresponding aliphatic dialdehyde with one or more aliphatic monohydric or polyhydric alcohols, during which water is isolated by distillation while obtaining a reaction mixture that is separated by distillation. The invention is characterized in that the separation by distillation is continuously carried out in a partition column during which pure aliphatic dialdehyde monoacetal is obtained as a side-stream of the partition column or the separation by distillation is continuously carried o ut in two distillation columns during which crude aliphatic dialdehyde monoacet al is obtained as a side-stream in the first distillation column, the crude aliphatic dialdehyde monoacetal is fed to the second distillation column, an d pure aliphatic dialdehyde monoacetal is obtained as a side-stream from the second distillation column.

公开(公告)号：AU2003246375A1

公开(公告)日：2004-02-02

申请号：AU2003246375

申请日：2003-07-04

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  JUNGKAMP TIM ,  SCHEIDEL JENS

IPC: B01J31/18 ,  B01J27/32 ,  B01J31/40 ,  B01J38/00 ,  C07B61/00 ,  C07C253/10 ,  C07C255/04 ,  C07C255/07

Abstract: A process for the recovery of a Lewis acid from a reaction mixture (I) which has been obtained in the hydrocyanation of an olefinically unsaturated compound to a nitrile which has a miscibility gap with water under certain pressure and temperature conditions, in the presence of a catalyst system comprising a Lewis acid and a complex compound. The method comprises a) removing the complex compound from mixture (I) to give a mixture (II), b) adding water to mixture (II) and placing mixture (II) under pressure and temperature conditions to provide a phase (III) and a phase (IV), c) adding a liquid diluent (V) which c1) does not form an azeotrope with water and whose boiling point under certain pressure conditions is higher than that of water, or c2) forms an azeotrope or heteroazeotrope with water under certain pressure conditions, to phase (III), d) subjecting the mixture of phase (III) and liquid diluent (V) to distillation under the pressure conditions mentioned in step c1) or c2), and e) subjecting mixture (VII) to hydrocyanation of an olefinically unsaturated compound to give the nitrile.

公开(公告)号：CA2464710A1

公开(公告)日：2003-04-24

申请号：CA2464710

申请日：2002-10-04

Applicant: BASF AG

Inventor： MOLNAR FERENC ,  HADERLEIN GERD ,  ALTMAYER MARCO ,  JUNGKAMP TIM ,  SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BARTSCH MICHAEL ,  BAUMANN ROBERT

IPC: B01J31/22 ,  B01J31/18 ,  C07B61/00 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  C07C255/07 ,  C07F9/48

Abstract: The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylen e group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF3 and n is 1 or 2.

公开(公告)号：DE10046025A1

公开(公告)日：2002-03-28

申请号：DE10046025

申请日：2000-09-18

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  BARTSCH MICHAEL ,  KUNSMANN-KEITEL DAGMAR PASCAL ,  HADERLEIN GERD ,  SIEGEL WOLFGANG ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J23/755 ,  B01J31/18 ,  B01J31/24 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  B01J31/12 ,  C07F15/04

Abstract: Production of adiponitrile from butadiene and hydrogen cyanide uses a catalyst comprising a Group VIII metal complex having at least one tricyclic bifunctional phosphorus, arsenic or antimony ligand. Production of adiponitrile by: (a) reacting butadiene with hydrogen cyanide in the presence of a catalyst, (b) optionally catalytically isomerizing the resulting mixture of pentenonitriles to covert branched nitriles to linear nitriles, and (c) reacting the nitrile mixture with hydrogen cyanide in the presence of a catalyst comprises performing steps (a), (b) and/or (c) in the presence of a catalyst comprising a Group VIII metal complex having at least one ligand of formula (I). A , A = O, Si, SiRR, NR or CRR; R = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; Y , Y = groups comprising one or more P, As or Sb atoms, each directly bonded to at least two O, S or NR' heteroatoms; R' = H, alkyl, cycloalkyl or aryl; R -R = R, COOR', COOM, SO2R', SO3M, N(R')2, N(R')3 X , OR', SR', (CHR''CH2O)xR', (CH2NR')xR', (CH2CH2NR')xR', halogen, CF3, NO2, acyl or CN, or R and/or R can form fused ring systems with 1-3 rings; R = H, Me or Et; M = a cation; X = an anion; x = 1-120. An Independent claim is also included for a process for isomerizing branched aliphatic monoalkenonitriles to linear aliphatic monoalkenonitriles using such a catalyst.

公开(公告)号：CA2522520C

公开(公告)日：2011-11-08

申请号：CA2522520

申请日：2004-04-15

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BASSLER PETER

IPC: C01C3/02 ,  C01C3/04 ,  C07C253/00

Abstract: The invention relates to a method for dehydrating hydrocyanic acid by distillation. Said method is characterised in that a crude hydrocyanic acid containing between 50 and 99.9 wt. % HCN, between 0.1 and 40 wt. % water, between 0 and 15 wt. % carbon oxides and optionally between 0.01 and 1 wt. % non-volatile stabiliser is distilled in a distillation column at a pressure of between 1 bar and 2.5 bar, a sump temperature of between 100 ~C and 130 ~C and a head temperature of between 25 ~C and 54 ~C in the absence of a volatile stabiliser. A discharge stream, containing purified anhydrous hydrocyanic acid and carbon oxides is thus obtained from the head and a discharge stream containing water and optionally the non-volatile stabiliser is obtained from the sump.

公开(公告)号：ES2288737T3

公开(公告)日：2008-01-16

申请号：ES05701200

申请日：2005-01-27

Applicant: BASF AG

Inventor： SCHEIDEL JENS ,  MILLER CHRISTIAN ,  BAUMANN ROBERT ,  JUNGKAMP TIM ,  BARTSCH MICHAEL ,  HADERLEIN GERD

IPC: C07C253/30 ,  C07C255/07

Abstract: Procedimiento para la isomerización del pentenonitrilo en una corriente de educto, caracterizado porque la isomerización del cis-2-pentenonitrilo en el trans-3-pentenonitrilo tiene lugar sobre al menos un catalizador disuelto de manera homogénea en la corriente del educto, que es una monoamina o una diamina con 1 hasta 20 átomos de carbono, o un líquido iónico, eligiéndose el líquido iónico entre el grupo constituido por los aductos de ácidos de Brönstedt de substancias nitrogenadas orgánicas.

公开(公告)号：ES2284000T3

公开(公告)日：2007-11-01

申请号：ES04722843

申请日：2004-03-24

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ANGEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN

IPC: B01J27/14 ,  B01J23/755 ,  B01J31/02 ,  B01J31/14 ,  B01J31/18 ,  C07C253/10 ,  C07C255/04

Abstract: Sistema apropiado como catalizador para el hidrocianado de compuestos con insaturación olefínica, que contiene a) Ni(0), b) Ni(0) como ligando compuesto complejante que contiene fósforo trienlazante, c) un ácido de Lewis, y d) un compuesto de la fórmula M Rn, representando M: Al o Ti R: restos alcoxi monovalentes iguales o diferentes, pudiendo estar puenteados entre sí varios restos alcoxi, adicionalmente en el caso de M = Al R restos alquilo monovalentes iguales o diferentes, pudiendo estar puenteados entre sí varios restos alquilo, o pudiendo estar puenteado uno o varios restos alquilo con uno o varios restos alcoxi citados anteriormente, n: valencia de M.