公开(公告)号：DE10127365A1

公开(公告)日：2002-12-12

申请号：DE10127365

申请日：2001-06-06

Applicant: BASF AG

Inventor： OLBERT GERHARD ,  MATTKE TORSTEN ,  KUMMER MATTHIAS ,  RUEHL THOMAS ,  ROSOWSKI FRANK

IPC: F04D7/06 ,  F04D3/00 ,  F04D13/00 ,  F04D29/40 ,  F04D29/52 ,  F04D29/18 ,  F04D29/44 ,  B01J8/06

Abstract: Pump comprises a housing containing a guide pipe and having an opening in its lower part, via which heat transfer medium removed from the lower region of a reactor flows into the housing. Pump comprises a housing (14) containing a guide pipe (13) and having an opening (15) in its lower part, via which heat transfer medium (6) removed from the lower region of a reactor flows into the housing. The medium further flows up between the inner wall of the housing and the outer wall of the guide pipe via a heat exchanger (18), via an opening in the upper region of the pipe into the inner chamber of the pipe, then via an opening in the lower region of the pipe into a further intermediate chamber between the inner wall of the housing and the outer wall of the guide pipe, and finally into the upper region of the intermediate chamber between contact tubes. Preferred Features: The pump is a propeller pump having three or more blades. The housing is rectangular or circular. Baffle plates (19) are arranged in one or more deviating regions of the housing for the heat transfer medium.

公开(公告)号：AU8182301A

公开(公告)日：2001-12-24

申请号：AU8182301

申请日：2001-06-08

Applicant: BASF AG

Inventor： MACHHAMMER OTTO ,  SCHINDLER GOETZ-PETER ,  TENTEN ANDREAS ,  HARTH KLAUS ,  ZEHNER PETER ,  MULLER-ENGEL KLAUS JOACHIM ,  ROSOWSKI FRANK ,  BORGMEIER FRIEDER

IPC: C07C27/14 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  C07C45/33 ,  C07C45/35 ,  C07C47/22 ,  C07C51/215 ,  C07C51/25 ,  C07C57/04 ,  C07C57/05 ,  C07C57/07

Abstract: In a process for the preparation of acrolein or acrylic acid or a mixture thereof from propane, the propane is subjected, in a first reaction stage, to a partial dehydrogenation under heterogeneous catalysis to give propene, of the components contained in the product gas mixture formed in the first reaction stage other than propene and propane at least a portion of the molecular hydrogen present is then separated off from said mixture and the product gas mixture is then used for the preparation of acrolein and/or acrylic acid by gas-phase catalytic propylene oxidation, molecular nitrogen being present for diluting the reaction gas mixture during the propylene oxidation.

公开(公告)号：ID28000A

公开(公告)日：2001-05-03

申请号：ID20002517

申请日：1999-06-02

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  ROSOWSKI FRANK ,  LINDEN GERD ,  SEUFERT MICHAEL ,  HEFELE GERHARD ,  LORZ PETER MICHAEL

IPC: B01J23/22 ,  B01J27/198 ,  B01J37/02 ,  C07C51/265 ,  C07C51/31 ,  C07C63/16

Abstract: The invention relates to a method for producing shell catalysts for the catalytic vapor-phase oxidation of aromatic carboxylic acids and/or carboxylic acid anhydrides comprised of a supporting core and of catalytically active metal oxides which are deposited in a shell-shaped manner on said supporting core. The inventive catalysts are obtained by spraying an aqueous active mass suspension, said suspension containing the active metal oxides, at higher temperatures onto the hot supporting material which has a temperature ranging from 50 to 450° C. The aqueous active mass suspension contains 1 to 10 wt. %, with regard to the solid content of the active mass suspension, a binding agent comprised of A) a polymerizate obtained by radical polymerization, containing 5 to 100 wt. % of monomers (a) in the form of ethylenically unsaturated acid anhydrides or ethylenically unsaturated dicarboxylic acids whose carboxyl groups can form an anhydride and containing 0 to 95 wt. % monoethylenically unsaturated monomers (b) with the provision that the monomers (a) and (b) comprise, on average, a maximum of 6 carbon atoms which are not functionalized with groups containing oxygen, and of B) an alkanolamine having at least 2 OH groups, a maximum of 2 nitrogen atoms and a maximum of 8 C-atoms, whereby the weight ratio A:B ranges from 1:0.05 to 1:1.

公开(公告)号：DE19910507A1

公开(公告)日：2000-09-14

申请号：DE19910507

申请日：1999-03-10

Applicant: BASF AG

Inventor： JACHOW HARALD ,  TENTEN ANDREAS ,  UNVERRICHT SIGNE ,  ARNOLD HEIKO ,  MACHHAMMER OTTO ,  HAUPT SUSANNE ,  ROSOWSKI FRANK

IPC: B01J23/88 ,  B01J8/02 ,  B01J8/04 ,  B01J8/06 ,  B01J23/31 ,  B01J23/882 ,  B01J23/888 ,  B01J35/00 ,  B01J37/04 ,  C07B61/00 ,  C07C27/14 ,  C07C45/33 ,  C07C47/22 ,  C07C51/215 ,  C07C57/05 ,  B01J23/887 ,  C07C45/35

Abstract: The invention relates to a method for carrying out the heterogeneously catalyzed gas phase oxidation of propane into acrolein and/or acrylic acid in which the initial mixture of reaction gas is fed over a fixed-bed catalyst which is comprised of catalyst charges A, B arranged in two reaction zones A, B that are placed in a spatially successive manner, whereby the temperature of reaction zones A, B are kept at different temperatures.

公开(公告)号：DE19815279A1

公开(公告)日：1999-10-07

申请号：DE19815279

申请日：1998-04-06

Applicant: BASF AG

Inventor： HIBST HARTMUT ,  ROSOWSKI FRANK

IPC: B01J23/28 ,  B01J23/887 ,  B01J35/00 ,  C01G1/02 ,  C01G30/02 ,  C07C51/25 ,  C07C57/055 ,  C01G39/00 ,  B01J27/199

Abstract: The invention relates to multi-metal oxide compounds with a 2-component structure, containing molybdenum, hydrogen, one or more of the elements phosphor, arsenic, boron, germanium and silicon, one or more of the elements copper, zinc, cobalt and iron, and the element antimony. The invention also relates to the use of said compounds for producing methacrylic acid by means of a gas phase catalytic oxidation process.

公开(公告)号：BRPI0612702A2

公开(公告)日：2016-11-29

申请号：BRPI0612702

申请日：2006-06-30

Applicant: BASF AG

Inventor： ROSOWSKI FRANK ,  ALLMANN HANS-MARTIN ,  ZÜHLKE JÜRGEN ,  STEEG RAINER ,  NETO SAMUEL ,  STORCK SEBASTIAN ,  LAUTENSACK THOMAS

IPC: B01J23/00 ,  C07C51/21 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89

公开(公告)号：BRPI0410759B1

公开(公告)日：2014-03-04

申请号：BRPI0410759

申请日：2004-05-21

Applicant: BASF AG

Inventor： ZUEHLKE JUERGEN ,  NETO SAMUEL ,  ROSOWSKI FRANK ,  STORCH SEBASTIAN

IPC: C07C51/265 ,  C07C51/31 ,  C07C63/16

Abstract: A description is given of a process for preparing aldehydes, carboxylic acids and/or carboxylic anhydrides, in particular phthalic anhydride, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed at elevated temperature over a bed of a first catalyst and a bed which is made up of a second catalyst having a higher activity than the first catalyst and is located downstream of the first catalyst in the flow direction of the gaseous stream, wherein the catalytically active composition of the first catalyst comprises at least vanadium oxide, titanium dioxide and antimony oxide and the ratio of vanadium, calculated as V 2 O 5 , to antimony, calculated as Sb 2 O 3 , in the first catalyst is from 3.5:1 to 5:1. The source of antimony oxide used for the first catalyst is preferably particulate antimony trioxide having a mean particle size of from 0.5 to 5 mum. The process allows the desired oxidation products to be obtained in high yield over longer periods of time.

公开(公告)号：ZA200510405B

公开(公告)日：2008-06-25

申请号：ZA200510405

申请日：2005-12-22

Applicant: BASF AG

Inventor： ROSOWSKI FRANK ,  STORCK SEBASTIAN ,  ZUHLKE JURGEN ,  NETO SAMUEL

IPC: C07C20090101 ,  C07C51/265 ,  C07C51/31

Abstract: A description is given of a process for preparing aldehydes, carboxylic acids and/or carboxylic anhydrides, in particular phthalic anhydride, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed at elevated temperature over a bed of a first catalyst and a bed which is made up of a second catalyst having a higher activity than the first catalyst and is located downstream of the first catalyst in the flow direction of the gaseous stream, wherein the catalytically active composition of the first catalyst comprises at least vanadium oxide, titanium dioxide and antimony oxide and the ratio of vanadium, calculated as V 2 O 5 , to antimony, calculated as Sb 2 O 3 , in the first catalyst is from 3.5:1 to 5:1. The source of antimony oxide used for the first catalyst is preferably particulate antimony trioxide having a mean particle size of from 0.5 to 5 mum. The process allows the desired oxidation products to be obtained in high yield over longer periods of time.

公开(公告)号：PL1628763T3

公开(公告)日：2008-02-29

申请号：PL04733250

申请日：2004-05-15

Applicant: BASF AG

Inventor： STORCK SEBASTIAN ,  ZÜHLKE JÜRGEN ,  NETO SAMUEL ,  ROSOWSKI FRANK

IPC: B01J35/02 ,  B01J23/00 ,  B01J23/22 ,  B01J27/198 ,  B01J35/00 ,  B01J35/10 ,  C07C51/265 ,  C07C51/31

公开(公告)号：ES2290712T3

公开(公告)日：2008-02-16

申请号：ES04733250

申请日：2004-05-15

Applicant: BASF AG

Inventor： STORCK SEBASTIAN ,  ZUHLKE JURGEN ,  NETO SAMUEL ,  ROSOWSKI FRANK

IPC: B01J35/02 ,  B01J23/00 ,  B01J23/22 ,  B01J27/198 ,  B01J35/00 ,  B01J35/10 ,  C07C51/265 ,  C07C51/31

Abstract: Sistema catalizador para la producción de anhídrido del ácido ftálico, que presenta al menos tres capas de catalizador dispuestas una sobre otra en el tubo de reacción, cuya actividad catalizadora aumenta de capa en capa y cuya masa activa contiene del 70 al 99% en peso de dióxido de titanio en la modificación anatasa, (i) presentando el catalizador menos activo sobre el material de soporte del 7 al 10% en peso, con respecto al catalizador total, de masa activa, que contiene del 6 al 11% en peso de V2O5, del 0 al 3% en peso de Sb2O3, del 0, 1 al 1% en peso de álcali (calculado como metal alcalino) y como resto TiO2 en forma anatasa con una superficie BET de desde 5 hasta 30 m2/g, (ii) presentando el siguiente catalizador más activo sobre el material de soporte del 7 al 12% en peso, con respecto al catalizador total, de masa activa, que contiene del 5 al 13% en peso de V2O5, del 0 al 3% en peso de Sb2O3, del 0 al 0, 4% en peso de P, del 0 al 0, 4% en peso de álcali (calculado como metal alcalino) y como resto TiO2 en forma anatasa con una superficie BET de desde 10 hasta 40 m2/g, (iii) presentando el catalizador más activo sobre el material de soporte del 8 al 12% en peso, con respecto al catalizador total, de masa activa, que contiene del 5 al 30% en peso de V2O5, del 0 al 3% en peso de Sb2O3, del 0, 05 al 0, 4% en peso de P, del 0 al 0, 3% en peso de álcali (calculado como metal alcalino) y como resto TiO2 en forma anatasa con una superficie BET de desde 15 hasta 50 m2/g, con la condición de que la superficie BET del dióxido de titanio en la capa (i) superior sea menor que la superficie BET del dióxido de titanio en la o las capa(s) (ii) intermedia(s) y la superficie BET del dióxido de titanio en la capa (iii) inferior sea mayor que la superficie BET del dióxido de titanio en la o las capa(s) intermedia(s).