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公开(公告)号:DE10206845A1
公开(公告)日:2003-08-28
申请号:DE10206845
申请日:2002-02-19
Applicant: BASF AG
Inventor: ROEPER MICHAEL , STEPHAN JUERGEN , SCHINDLER GOETZ-PETER , TROPSCH JUERGEN , HEIDEMANN THOMAS , PRINZ MARTINA
IPC: C07B61/00 , C07C2/00 , C07C2/06 , C07C2/10 , C07C6/04 , C07C11/02 , C07C11/107 , C07C29/141 , C07C29/16 , C07C31/125 , C07C41/03 , C07C45/50 , C07C47/21 , C07C29/00 , C11D1/12 , C07H15/04 , C08B37/00 , C07C303/24 , C07F9/09
Abstract: Production of surfactant alcohols or their ethers by derivatization of 10-20C olefins or mixtures, comprises: (i) metathesizing a 4C olefin mixture; (ii) removing the 5-8C olefins; (iii) dimerizing the separated olefins to a 10-16C olefin mixture; (iv) derivatizing the mixture to a mixture of surfactant alcohols; and optionally (v) alkoxylating the alcohols. Production of surfactant alcohols or their ethers by derivatization of 10-20C olefins or mixtures, comprises: (i) metathesizing a 4C olefin mixture of 1-butene/2-butene ratio at least 1.2; (ii) removing the 5-8C olefins; (iii) dimerizing the separated olefins (optionally in admixture) to a 10-16C olefin mixture; (iv) derivatizing the mixture to a mixture of surfactant alcohols (optionally after fractionation); and optionally (v) alkoxylating the alcohols. Independent claims are also included for: (1) the novel olefin mixtures obtained by steps (i) - (iii) above; and (2) the novel surfactant alcohols and their alkoxylates obtained by steps (i) - (iv) and optionally also step (v) above.
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公开(公告)号:BR0111704A
公开(公告)日:2003-07-08
申请号:BR0111704
申请日:2001-06-13
Applicant: BASF AG
Inventor: TROPSCH JUERGEN , MAAS HEIKO
IPC: C07C29/16 , C07C45/50 , C07C303/24 , C07C305/10 , C07F9/09 , C11D1/14 , C11D1/29 , C11D1/34 , C11D1/72 , C11D1/722
Abstract: The invention describes detergents and cleaners comprising an effective proportion of one or more surfactants of the formula I in which a is one of the numbers 11, 12, or 13, R 1 and R 2 are different and are each hydrogen or alkyl radicals R 3 is hydrogen, or a sulfato or phosphate radical, x and y are each a number from 0 to 200, and further known auxiliaries and additives customary in detergents and cleaners and optionally in addition further surfactants.
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公开(公告)号:DE59705081D1
公开(公告)日:2001-11-29
申请号:DE59705081
申请日:1997-02-27
Applicant: BASF AG
Inventor: HAEHNLE HANS-JOACHIM , WALTER MANFRED , TROPSCH JUERGEN , KREMESKOETTER JENS , SCHORNICK GUNNAR , ANSTOCK THOMAS
IPC: A61F13/00 , A61F13/53 , A61L15/00 , A61L15/16 , A61L15/42 , A61L15/60 , C05G3/80 , C08F2/44 , C08F2/48 , C08F220/06 , C08J9/30 , C08L33/02
Abstract: Water-absorbing foamlike crosslinked polymers which are obtainable by(I) foaming a polymerizable aqueous mixture which consists of(a) monoethylenically unsaturated monomers containing acid groups, which are at least 50 mol % neutralized,(b) with or without other monoethylenically unsaturated monomers,(c) crosslinker,(d) initiators,(e) from 0.1 to 20% by weight of at least one surfactant,(f) with or without one or more solubilizers and(g) with or without thickeners, foam stabilizers, polymerization regulators, fillers and/or cell nucleating agents,the foaming being performed by dispersing fine bubbles of a gas inert to free radicals, and(II) polymerizing the foamed mixture with formation of a foamed hydrogel, with or without adjusting the water content of the foamed polymer to from 1 to 60% by weight, processes for their preparation and their use in sanitary articles which are used for absorbing body fluids and in dressing materials for covering wounds are described.
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公开(公告)号:BR9812042A
公开(公告)日:2000-09-26
申请号:BR9812042
申请日:1998-09-05
Applicant: BASF AG
Inventor: TROPSCH JUERGEN , ZELLER DIETER
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公开(公告)号:AU1924397A
公开(公告)日:1997-09-16
申请号:AU1924397
申请日:1997-02-27
Applicant: BASF AG
Inventor: HAEHNLE HANS-JOACHIM , WALTER MANFRED , TROPSCH JUERGEN , KREMESKOETTER JENS , SCHORNICK GUNNAR , ANSTOCK THOMAS
IPC: A61F13/00 , A61F13/53 , A61L15/00 , A61L15/16 , A61L15/42 , A61L15/60 , C05G3/80 , C08F2/44 , C08F2/48 , C08F220/06 , C08J9/30 , C08L33/02
Abstract: Water-absorbing foamlike crosslinked polymers which are obtainable by(I) foaming a polymerizable aqueous mixture which consists of(a) monoethylenically unsaturated monomers containing acid groups, which are at least 50 mol % neutralized,(b) with or without other monoethylenically unsaturated monomers,(c) crosslinker,(d) initiators,(e) from 0.1 to 20% by weight of at least one surfactant,(f) with or without one or more solubilizers and(g) with or without thickeners, foam stabilizers, polymerization regulators, fillers and/or cell nucleating agents,the foaming being performed by dispersing fine bubbles of a gas inert to free radicals, and(II) polymerizing the foamed mixture with formation of a foamed hydrogel, with or without adjusting the water content of the foamed polymer to from 1 to 60% by weight, processes for their preparation and their use in sanitary articles which are used for absorbing body fluids and in dressing materials for covering wounds are described.
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公开(公告)号:ES2102068T3
公开(公告)日:1997-07-16
申请号:ES93923472
申请日:1993-10-15
Applicant: BASF AG
Inventor: DETERING JUERGEN , SCHADE CHRISTIAN , TRIESELT WOLFGANG , TROPSCH JUERGEN
IPC: C08F2/10 , C08F26/00 , C08F26/10 , C08F226/06 , C08F226/10 , C08F289/00 , C11D3/00 , C11D3/37
Abstract: PCT No. PCT/EP93/02851 Sec. 371 Date Apr. 21, 1995 Sec. 102(e) Date Apr. 21, 1995 PCT Filed Oct. 15, 1993 PCT Pub. No. WO94/10281 PCT Pub. Date May 11, 1994There are described the use of copolymers obtainable by free-radically initiated copolymerization of monomer mixtures comprising (a) 60-99% by weight of 1-vinylpyrrolidone, 1-vinylimidazole or mixtures thereof, (b) 1-40% by weight of nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of salts or in quaternized form, and optionally (c) up to 20% by weight of other monoethylenically unsaturated monomers, as detergent additives for inhibiting dye transfer during the wash, detergents which contain such polymers, and polymers which are obtainable by free-radically initiated polymerization of (a) 1-vinylpyrrolidone, 1-vinylimidazole, 1-vinylimidazolium compounds, or mixtures thereof, and optionally (b) other nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of the salts or in quaternized form, and/or (c) other monoethylenically unsaturated monomers, in an aqueous medium in the presence of water-soluble proteins and a process for the preparation of the polymers by polymerising the monomers (a) and optionally (b) and/or (c) in an aqueous medium in the presence of water-soluble proteins using from 0.5 to 400 parts by weight of protein per 100 parts by weight of monomer used in the polymerization.
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公开(公告)号:AT154385T
公开(公告)日:1997-06-15
申请号:AT93923472
申请日:1993-10-15
Applicant: BASF AG
Inventor: DETERING JUERGEN , SCHADE CHRISTIAN , TRIESELT WOLFGANG , TROPSCH JUERGEN
IPC: C08F2/10 , C08F26/00 , C08F26/10 , C08F226/06 , C08F226/10 , C08F289/00 , C11D3/00 , C11D3/37
Abstract: PCT No. PCT/EP93/02851 Sec. 371 Date Apr. 21, 1995 Sec. 102(e) Date Apr. 21, 1995 PCT Filed Oct. 15, 1993 PCT Pub. No. WO94/10281 PCT Pub. Date May 11, 1994There are described the use of copolymers obtainable by free-radically initiated copolymerization of monomer mixtures comprising (a) 60-99% by weight of 1-vinylpyrrolidone, 1-vinylimidazole or mixtures thereof, (b) 1-40% by weight of nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of salts or in quaternized form, and optionally (c) up to 20% by weight of other monoethylenically unsaturated monomers, as detergent additives for inhibiting dye transfer during the wash, detergents which contain such polymers, and polymers which are obtainable by free-radically initiated polymerization of (a) 1-vinylpyrrolidone, 1-vinylimidazole, 1-vinylimidazolium compounds, or mixtures thereof, and optionally (b) other nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of the salts or in quaternized form, and/or (c) other monoethylenically unsaturated monomers, in an aqueous medium in the presence of water-soluble proteins and a process for the preparation of the polymers by polymerising the monomers (a) and optionally (b) and/or (c) in an aqueous medium in the presence of water-soluble proteins using from 0.5 to 400 parts by weight of protein per 100 parts by weight of monomer used in the polymerization.
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公开(公告)号:CA2555788C
公开(公告)日:2013-04-16
申请号:CA2555788
申请日:2005-02-10
Applicant: BASF AG
Inventor: TROPSCH JUERGEN , ZELINSKI THOMAS
Abstract: The invention relates to alkyl ether sulfates of general formula (I), in which R represents a linear or branched C8-C18 alkyl group or mixtures of different linear or branched C8-C18 alkyl groups; R1 represents an aliphatic group selected from the group consisting of methyl and ethyl; M+ represents a cation selected from the group consisting of alkali metals, NH4+ and HNR23+, wherein R2 is selected from the group consisting of linear or branched alkyl groups, CH2CH2OH and CH2CH(OH)CH3; x represents an average value of 0 - 3; y represents an average value of 1 - 10; z represents an average value of 0 -30; and the quotient (II) is > 1. The invention also relates to the use of said alkyl ether sulfates as anionic surfactant components in detergents and cleaning agents, in technical chemical applications or in cosmetic formulations.
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公开(公告)号:DE502004006068D1
公开(公告)日:2008-03-13
申请号:DE502004006068
申请日:2004-10-14
Applicant: BASF AG
Inventor: KLUMPE MARKUS , TROPSCH JUERGEN , KAHL ROLF-DIETER , BOEHN ROLAND , STUTZ SUSANNE , NOERENBERG RALF
Abstract: The alkoxylate mixtures comprise alkoxylates of the formula (I) C5H11CH(C3H7)CH2O(B)p(A)n(B)m(A)qH(I) where A is ethyleneoxy, B, in each case independently, are C3-10-alkyleneoxy or mixtures thereof, groups A and B being present in the form of blocks in the stated sequence, p is a number from 0 to 10, n is a number greater than 0 to 20, m is a number greater than 0 to 20, q is a number greater than 0 to 10, p+n+m+q is at least 1, from 70 to 99% by weight of alkoxylates A1, in which C5H11 is n-C5H11, and from 1 to 30% by weight of alkoxylates A2, in which C5H11 is C2H5CH(CH3)CH2 and/or CH3CH(CH3)CH2CH2, being present in the mixture.
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公开(公告)号:DE102005041347A1
公开(公告)日:2007-03-01
申请号:DE102005041347
申请日:2005-08-31
Applicant: BASF AG
Inventor: SEEBECK TANJA , TROPSCH JUERGEN , KISSAU LARS
IPC: C11D3/37
Abstract: Cleaning formulation free of phosphate for dishwasher comprises: copolymer (1-20 wt.%); chelating agent (1-50 wt.%); weakly foaming non-ionic surfactant (1-15 wt.%); bleaching agent and optionally bleach activator (0-30 wt.%); further builder (0-60 wt.%); enzyme (0-8 wt.%); and one or more further additives. The copolymer comprises acrylic acid, methacrylic acid and/or alkyl-terminated polyalkylene glycol (meth)acrylate. Cleaning formulation free of phosphate for dishwasher comprises: copolymer (1-20 wt.%) from acrylic acid and/or a water-soluble salt of the acrylic acid (50-93 mol.%), methacrylic acid and/or a water soluble salt of methacrylic acid (5-30 mol.%) or at least one non-ionic monomer (I) of formula (H 2C=C(R 1>)-COO-R 2>-[R 3>-O] n-R 4>) (2-20 mol.%); chelating agent (1-50 wt.%) such as glycine-N,N-diacetic acid derivative, glutamic acid-N,N-diacetic acid and/or its salt; weakly foaming non-ionic surfactant (1-15 wt.%); bleaching agent and optionally bleach activator (0-30 wt.%); further builder (0-60 wt.%); enzyme (0-8 wt.%); and one or more further additives such as anionic or zwitterionic surfactant, bleaching catalyst, alkali carrier, corrosion inhibitor, antifoaming agent, dye, aroma material, filler, organic solvent and water (0-50 wt.%). R 1>H or methyl; R 2>a bond or 1-6C alkylene; R 3>2-4C alkylene; R 4>1-6C alkyl; and n : 3-50. Independent claims are included for: (1) a powder- or granulate mixture useful in cleaning formulation for dishwasher, comprising copolymer (10-95 wt.%), chelating agent (5-80 wt.%) and polyethylene glycol and/or non-ionic surfactant; and (2) use of a combination of copolymer and chelating agent, as a coating inhibitor in addition with cleaning formulation for the dish cleaning machine.
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