公开(公告)号：NO914439A

公开(公告)日：1992-05-15

申请号：NO914439

申请日：1991-11-13

Applicant: HOECHST AG

Inventor： BREKNER MICHAEL-JOACHIM ,  OSAN FRANK ,  ROHRMANN JUERGEN ,  ANTBERG MARTIN

IPC: C08F4/642 ,  C08F4/60 ,  C08F4/6592 ,  C08F6/26 ,  C08F10/14 ,  C08F32/00 ,  C08F32/08 ,  C08F210/00 ,  C08F232/08 ,  C08F4/626 ,  C08F232/04

CPC classification number: C08F32/08

公开(公告)号：AU622337B2

公开(公告)日：1992-04-02

申请号：AU5872290

申请日：1990-07-06

Applicant: HOECHST AG

Inventor： BREKNER MICHAEL-JOACHIM ,  ROHRMANN JURGEN ,  SPALECK WALTER ,  ANTBERG MARTIN

IPC: C08F4/642 ,  C07F17/00 ,  C08F4/60 ,  C08F4/602 ,  C08F4/6192 ,  C08F4/622 ,  C08F4/626 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/6592 ,  C08F10/00 ,  C08F32/00 ,  C08F32/04 ,  C08F32/08 ,  C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/14 ,  C08F210/16 ,  C08F232/00 ,  C08F232/04 ,  C08F232/08 ,  C08G61/08 ,  C08F4/656 ,  C08F4/657

Abstract: The prodn. of cycloolefin polymers (COC) comprises the polymerisation of (a) 0.1-100 wt.% monomer(s) of formula (I), (II), (III) or (IV), (b) 0-99.9 wt.% cycloolefin of formula (V) and (c) acyclic 1-olefin(s) of formula (VI), at -78 to +150 degrees C and 0.5-64 bar in soln., suspension, monomer melt or gas phase, in the presence of a catalyst consisting of a metallocene component of formula (IX) and linear and/or cyclic aluminoxane(s) of formula (VII) and/or (VIII). R -R = H or 1-8 C alkyl; n = 2-10; R = 1-6 C alkyl, Ph or benzyl; m = 2-50; M = Ti, Zr, Hf, V, Nb or Ta; R , R = H, halo, 1-10 C alkyl or alkoxy, 2-10 C alkenyl, 6-10 C aryl or aryloxy, 7-40 C aralkyl or alkaryl, or 8-40 C aralkenyl; R , R = mono- or poly-nuclear hydrocarbon residue which can form a sandwich structure with M ; R = -X-, -X-M R R -, -X-C(R )2-, -CR R -, -O-X-, -CR R -CR R - or -BR -; X = -M R R -; M = Si, Ge or Sn; R -R = H, halo, 1-10 C alkyl, fluoroalkyl or alkoxy, 6-10 C aryl or fluoroalkyl, 2-10 C alkenyl, 7-40 C aralkyl or alkaryl, or 8-40 C aralkenyl; or R +R or R +R or R +R may form a ring with their linking atom. Also claimed are COC polymers obtd. by this process, esp. with a content of more than 40 mole% norbornene units. Also claimed are extruded parts, injection moulded prods. and polymer alloys contg. the above COC polymer(s).

公开(公告)号：PT95021A

公开(公告)日：1991-04-18

申请号：PT9502190

申请日：1990-08-17

Applicant: HOECHST AG

Inventor： BREKNER MICHAEL-JOACHIM ,  HERRMANN-SCHONHERR OTTO

IPC: B29C45/00 ,  B29C47/00 ,  C08L65/00 ,  C08L67/00 ,  C08L67/03 ,  C08L71/00 ,  C08L71/08 ,  C08L71/10 ,  C08L79/08 ,  D01F6/94 ,  C08F299/02

公开(公告)号：CA2020640A1

公开(公告)日：1991-01-09

申请号：CA2020640

申请日：1990-07-06

Applicant: HOECHST AG

Inventor： BREKNER MICHAEL-JOACHIM ,  ROHRMANN JUERGEN ,  SPALECK WALTER ,  ANTBERG MARTIN

IPC: C08F4/642 ,  C07F17/00 ,  C08F4/60 ,  C08F4/602 ,  C08F4/6192 ,  C08F4/622 ,  C08F4/626 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/6592 ,  C08F10/00 ,  C08F32/00 ,  C08F32/04 ,  C08F32/08 ,  C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/14 ,  C08F210/16 ,  C08F232/00 ,  C08F232/04 ,  C08F232/08 ,  C08G61/08

Abstract: - 1 - HOE 89/F 220 of the disclosure: Process for the preparation of cycloolefin polymers Polymers of polycyclic olefins of the formulae I to IV having a viscosity number greater than 20 cm3/g and a glass transition temperature above 100.degree.C are obtained without ring opening at a high polymerization rate and at polymerization temperatures advantageous from the technical point of view by means of a catalyst which is composed of a stereo-rigid, chiral metallocene compound of groups IVb to VIb of the Periodic Table of the Elements and an aluminoxane. (I) (II) (III) (IV)

公开(公告)号：CA2107724C

公开(公告)日：2004-12-07

申请号：CA2107724

申请日：1993-10-05

Applicant: HOECHST AG

Inventor： BREKNER MICHAEL-JOACHIM ,  WELLER THOMAS

IPC: C08F32/08 ,  C08F32/00 ,  C08F210/02 ,  C08F232/08 ,  G11B7/2538 ,  G11B7/24 ,  C08F232/04

Abstract: As starting materials for substrates for optical storage disks, cycloolefin copolymers (COC) are produced by a polymerization process in which the polymerization is terminated at a point in time at which the molar-mass distribution M w/M n is 15,000 g/mol and M w/M n less than/equal to 4 and greater than/equal to 2. The substrate is produced by thermal deformation either of a single COC having a molar-mass distribution M w/M n of

公开(公告)号：CA2115196C

公开(公告)日：2004-11-30

申请号：CA2115196

申请日：1994-02-08

Applicant: HOECHST AG

Inventor： BENNETT CYNTHIA ,  BREKNER MICHAEL-JOACHIM ,  COUTANDIN JOCHEN ,  HERRMANN-SCHOENHERR OTTO ,  OSAN FRANK

IPC: B29C55/02 ,  B32B27/32 ,  C08F6/02 ,  C08F32/00 ,  C08F232/00 ,  C08J5/18 ,  C08L45/00 ,  G02F1/1333 ,  C08F232/02 ,  G02F1/1335 ,  H01G4/18 ,  B65D65/40 ,  H01B3/44

Abstract: A film including semi-crystalline cycloolefin copolymers which have a content of catalyst residues of

公开(公告)号：CA2115195C

公开(公告)日：2004-11-23

申请号：CA2115195

申请日：1994-02-08

Applicant: HOECHST AG

Inventor： BENNETT CYNTHIA ,  BREKNER MICHAEL-JOACHIM ,  HERRMANN-SCHOENHERR OTTO ,  OSAN FRANK

IPC: B29C55/02 ,  B29K23/00 ,  B32B27/32 ,  C08F32/00 ,  C08F232/08 ,  C08J5/18 ,  C08L45/00 ,  C08F232/02 ,  G02F1/1335 ,  H01G4/18 ,  B65D65/40 ,  H01B3/44

Abstract: A flexible single- or multilayer non-oriented or mono- or biaxially oriented film in which at least one layer comprises a cycloolefin copolymer, wherein the cycloolefin copolymer has a mechanical loss factor (tan .delta.) of .gtoreq.0.015 at 50.degree.C below the glass transition temperature.

公开(公告)号：AU718870B2

公开(公告)日：2000-04-20

申请号：AU5080796

申请日：1996-04-22

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  BREKNER MICHAEL-JOACHIM ,  KUBER FRANK ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/64 ,  C08F4/642 ,  C08F4/68 ,  C08F4/69 ,  C08F10/00 ,  C08F4/76 ,  C08F4/78 ,  C08F4/643

Abstract: Metallocene cpds. of formula (I) with at least two different metallocene fragments L-MX2-L are new: (I) B = bridging unit; m = 2-100,000; M = Gp. IVb, Vb or VIb metal; X = H, 1-40C hydrocarbon-contg. gp., OH, halogen or pseudohalogen L = a pi-ligand or other electron donor. Also claimed is (i) a catalyst component contg. cpd(s). (I) and cocatalyst(s); (ii) a process for the prodn. of olefin polymers by polymerisation of olefin(s) in presence of a catalyst as in (i); (iii) polyolefins obtd. by this process.

公开(公告)号：ZA977737B

公开(公告)日：1998-03-02

申请号：ZA977737

申请日：1997-08-28

Applicant: HOECHST AG

Inventor： WINTER ANDREAS ,  VOLLMAR ANNETTE ,  FRAAIJE VOLKER ,  BREKNER MICHAEL-JOACHIM ,  SIEMON MANFRED

IPC: C08K3/34 ,  A61L15/24 ,  C08K5/05 ,  C08K5/098 ,  C08L23/02 ,  C08L23/10 ,  C08L45/00 ,  D01F6/46 ,  D04H1/42 ,  D04H1/4291 ,  D04H1/54 ,  D04H3/007 ,  D04H3/16 ,  C08L ,  D01F ,  D04H

公开(公告)号：DE59303811D1

公开(公告)日：1996-10-24

申请号：DE59303811

申请日：1993-04-15

Applicant: HOECHST AG

Inventor： EPPLE ULRICH ,  BREKNER MICHAEL-JOACHIM

IPC: C08F232/00 ,  C08F297/08 ,  C08G81/02 ,  C08L45/00 ,  C08L23/00 ,  C08L53/00 ,  C08L65/00

Abstract: A polymer alloy contains at least one cycloolefin polymer and/or at least one polyolefin and a block copolymer as phase promoter, which has different contents of monomers (norbornene derivatives and cycloolefins and/or acyclic olefins) in the individual blocks. To prepare the alloy, the individual polymers are combined and processed at elevated temperature under the action of shear forces.