公开(公告)号：JPH04103511A

公开(公告)日：1992-04-06

申请号：JP21824290

申请日：1990-08-21

Applicant: KAO CORP

Inventor： HOSOKAWA HITOSHI ,  SUGAWARA SUSUMU ,  FUKUDA KEIICHI ,  IGARASHI TADASHI ,  KONDO AKIHIRO

IPC: A61K8/00 ,  A61K8/73 ,  A61Q3/00 ,  A61Q3/02

Abstract: PURPOSE:To provide the subject base-coating agent containing a water-based polymer emulsion and effective in preventing the discoloration of nail by applying to the surface of nail prior to the application of a nitrocellulose-based nail enamel. CONSTITUTION:The objective base-coating agent for nitrocellulose-based nail enamel contains 5-60wt.% (in terms of solid) of a water-based polymer emulsion. The water-based polymer emulsion is preferably a cationic emulsion, which can be produced by adding water to an organic solvent solution (preferably methyl ethyl ketone solution) of a copolymer derived from 2-10wt.% of a monomer having a basic nitrogen atom and a double bond (e.g. N,N- dimethylaminoethyl acrylate) and 90-98wt.% of a hydrophobic monomer having a double bond (e.g. methyl acrylate) and distilling off the organic solvent. The base-coating agent has high film-forming property and film strength, and gives a coating film having excellent water-resistance.

公开(公告)号：JPH04103510A

公开(公告)日：1992-04-06

申请号：JP22076090

申请日：1990-08-21

Applicant: KAO CORP

Inventor： HOSOKAWA HITOSHI ,  KONO ATSUSHI ,  IGARASHI TADASHI ,  KONDO AKIHIRO

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/06 ,  A61Q1/00 ,  A61Q1/10 ,  A61Q5/00 ,  A61Q17/04

Abstract: PURPOSE:To provide a cosmetic having excellent luster and film-forming property and containing a water-based composite polymer emulsion containing emulsion-constituting polymer particles composed of at least two layers, wherein the polymer of the outermost layer has lower softening point than the polymer of the inner layer. CONSTITUTION:A water-based composite polymer emulsion composed of polymer particles having an outer layer composed of a water-based vinyl resin (A) and an inner layer composed of a polymer of a monomer (B) having a double bond is produced by polymerizing the monomer (B) in the presence of the vinyl resin (A). The objective cosmetic having excellent water-resistance, e.g. hair cosmetic or skin cosmetic contains 1-60wt.% of the above polymer emulsion in terms of solid component. The resin (A) is produced by adding water to an organic solvent solution of a copolymer of 0.5-15wt.% of a monomer having a salt- forming group and a double bond (e.g. acrylic acid) and 85-99.5wt.% of a monomer having a double bond (e.g. methyl acrylate) and distilling off the organic solvent.

公开(公告)号：JPH03101713A

公开(公告)日：1991-04-26

申请号：JP23961589

申请日：1989-09-14

Applicant: KAO CORP

Inventor： RINDOU KATSUHIKO ,  YOSHIMATSU AKIRA ,  KONDO AKIHIRO

IPC: G02F1/1339

Abstract: PURPOSE:To obtain a liquid crystal display device which has a good contrast, hardly generate the uneveness of colors and has excellent durability by constituting a spacer of polymer fine particles having 1X10 to 1X10 OMEGAcm specific volume resisturity value. CONSTITUTION:The spacer is constituted of the polymer fine particles having 1X10 to 1X10 OMEGAcm specific volume resistance value. The spacer consisting of the polyer fine particles having a hetero-5-memberd ring compd. and/or the oxidation polymer of arom. hydrocarbon at least on the surface is particularly preferable as the spacer for liquid crystal display. Such spacer for liquid crystal display can be manufacture from the polymer fine particles conts. >=0.05milli equiv./g anionic functional group. Thus, the resulted polymer fine particles are colored and since the specific volume resistivity value is adequate, the particles do not disturb the orientation of the liquid crystal as foreign matter and the liquid crystal display panel which has the good contrast and is free from the uneveness of colors is obtd. when the spacer is used as the spacer for liquid crystal display.

公开(公告)号：JPH02255725A

公开(公告)日：1990-10-16

申请号：JP7691689

申请日：1989-03-29

Applicant: KAO CORP

Inventor： ODA TAKU ,  KONDO AKIHIRO ,  YODA YOSHITAKA ,  KONO YUICHIRO

IPC: C08G73/02

Abstract: PURPOSE:To provide the subject polymer useful for nonionic surfactants, antifogging agents, compatibilizing agents, etc., by subjecting an oxazoline compound to a cationic ring-opening polymerization reaction, bringing the prepared polymer into contact with an alkali metal acetate salt, etc., and then reacting the product with water. CONSTITUTION:A (substituted) 2-oxazoline compound (e.g. 2-oxazoline or 2- methyl-2-oxazoline) is subjected to a cationic ring-opening polymerization and the prepared polymer is brought into contact with an alkali metal acetate salt (preferably potassium acetate) and/or an alkali metal sulfite salt (preferably sodium bisulfite), followed by reacting the product with water to provide the objective polymer.

公开(公告)号：JPH02255704A

公开(公告)日：1990-10-16

申请号：JP7691589

申请日：1989-03-29

Applicant: KAO CORP

Inventor： YOSHIMATSU AKIRA ,  KONDO AKIHIRO ,  TSUSHIMA RIKIO ,  SHIBATA YUTAKA ,  FUKUYAMA YUKIHIRO

IPC: C08L101/00 ,  B01J13/04 ,  C08F2/44

Abstract: PURPOSE:To obtain the subject highly absorbing and oil-absorbing fine particles by dispersing a monomer mixture containing a hydrophilic monomer containing polyethylene glycol mono(meth)acrylate and crosslinkable monomer in an aqueous medium in the presence of an oil-soluble substance and polymerizing the monomer mixture. CONSTITUTION:In an aqueous medium, is dispersed 100 pts.wt. monomer mixture containing 30-90 pts.wt. hydrophilic monomer containing polyethylene glycol mono(meth)acrylate and 10-70 pts.wt. crosslinking monomer [preferably polyethylene glycol di(meth)acrylate] in the presence of 10-300 pts.wt. oil-soluble substance (e.g. isopropyl alcohol). Polymerization of the monomer mixture is then carried out to afford the objective fine particles, consisting of shell walls of an organic polymer compound having 1.5-10 swelling degree for a liquid substance and capable of providing a spherical shape in enclosing the above- mentioned liquid substance and flat shape in releasing the aforementioned liquid substance.

公开(公告)号：JPH02221463A

公开(公告)日：1990-09-04

申请号：JP3806189

申请日：1989-02-17

Applicant: KAO CORP

Inventor： ONISHI MOTOKO ,  IDE KAZUTOSHI ,  ISHIKAWA YOSHINOBU ,  KONDO AKIHIRO ,  YAMAMURA MASAAKI

IPC: C08L33/04 ,  D06M15/233 ,  D06M15/263 ,  D06M15/267

Abstract: PURPOSE:To obtain a sizing agent composition having excellent desirability on fiber in high bath ratio, providing cloth with tension of good touch to the skin, comprising an aqueous resin dispersion having particle diameter of aqueous resin, a glass transition temperature thereof and the lowermost film-forming temperature which show

公开(公告)号：JPH02193059A

公开(公告)日：1990-07-30

申请号：JP23818788

申请日：1988-09-22

Applicant: KAO CORP

Inventor： SAKATA MASARU ,  TANIGAKI MASANOBU ,  KONDO AKIHIRO ,  TOTOKI SHINTARO ,  KAWABATA NARIAKI

IPC: G01N27/327 ,  C08F8/32 ,  C08F26/06 ,  C12Q1/00 ,  G01N27/416

Abstract: PURPOSE:To enable measurement of a concn. of a desired material quickly with reproducibility by arranging a container which is filled with a non-water soluble carrier whose surface is covered with a high polymer containing a pyridinium group as given by a specified formula in the molecule, and an electrochemical device to determine a substance which is generated or consumed with the action of microorganisms being separated from each other. CONSTITUTION:This sensor is equipped with a container which is filled with a non-water soluble carrier whose surface is covered with a high polymer containing a pyridinium group as given by a formula (wherein R represents a benzene group, a phenethyl group, a 1-16C alkyl group or a pentafluorophenyl methyl group and X a halogen atom) for adsorption of a microorganism in a molecule and an electrochemical device to determine a substance which is generated or consumed with the anion of the microorganisms being separated from each other. The high polymer containing a pyridinium group in the mole cule includes a benzyl group and phenethyl group or the like. The use of this sensor enables measurement of various substances such as saccharides quickly and easily in addition to BOD in water.

公开(公告)号：JPH02157213A

公开(公告)日：1990-06-18

申请号：JP30959188

申请日：1988-12-07

Applicant: KAO CORP

Inventor： YODA YOSHITAKA ,  WADA MIYUKI ,  KONO YUICHIRO ,  ODA TAKU ,  KONDO AKIHIRO

IPC: A61K8/00 ,  A61K8/84 ,  A61Q5/02 ,  A61Q19/10 ,  C11D1/66

Abstract: PURPOSE:To provide a detergent composition containing a polyethyleneimine copolymer, having excellent frothing power and cleaning power and giving low irritation to the skin and hair. CONSTITUTION:The objective detergent composition contains a copolymer of (A) a recurring unit of formula I (R1 is H, methyl or ethyl) and (B) a recurring unit of formula II (R2 is 4-15C alkyl, aryl or aralkyl) at a weight ratio (A/B) of 9/1-1/9 (preferably 8/2-4/6) as an active component. The molecular weight of the copolymer is preferably 500-20,000, especially 1,000-6,000. The copolymer can be produced by the ring-opening isomerization cationic polymerization of a 2-substituted-2-oxazoline.

公开(公告)号：JPH02155926A

公开(公告)日：1990-06-15

申请号：JP30958688

申请日：1988-12-07

Applicant: KAO CORP

Inventor： ODA TAKU ,  KONDO AKIHIRO ,  YODA YOSHITAKA ,  KONO YUICHIRO

IPC: B01F17/52 ,  C08G73/02 ,  C11D1/52

Abstract: PURPOSE:To obtain the title copolymer useful for a nonionic surface active agent by performing a ring-opening cationic polymn. of a plurality of specified 2-oxazoline monomers. CONSTITUTION:The title copolymer having repeating units of formulas III and IV and an MW of 500-50,000 is obtd. by performing simultaneously ring- opening polymn. of 5-95wt.% 2-oxazoline monomer of formula I (wherein R1 is H or a 1-3C alkyl) and 5-95wt.% 2-oxazoline monomer of formula II (wherein R2 is a 6-22C alkyl, aralkyl or aryl).

公开(公告)号：JPH01218884A

公开(公告)日：1989-09-01

申请号：JP4562388

申请日：1988-02-26

Applicant: KAO CORP

Inventor： SUZUKI ATSUSHI ,  KANO YOSHIHARU ,  ODA TAKU ,  KONDO AKIHIRO

IPC: B41M5/337

Abstract: PURPOSE:To obtain a thermal recording material which is effectively prevented from adhesion of refuse or sticking and causes little abrasion of a thermal head, by incorporating specified fine particles of a porous organic high molecular weight compound into a thermal color forming layer and/or an undercoat layer. CONSTITUTION:Fine particles of a porous organic high molecular weight com pound used in a thermal recording material can improve feeding properties such as adhesion of refuse and sticking, through absorbing an electron-donative dye, a phenolic substance for developing a color by reacting with the dye, a melted product of a known wax used as a sensitizer, or the like. This takes place at the surfaces of the porous fine particles, so that the particles must have a BET specific surface area of at least 30m /g, and a particle diameter sufficient for absorption of the melted product, namely, 0.1-10mum. The amount of the fine particles used in a thermal recording layer or a coat layer is desir ably 1-50wt.%, preferably, 3-20wt.% based on the recording layer.