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公开(公告)号:JPS6134004A
公开(公告)日:1986-02-18
申请号:JP15443684
申请日:1984-07-25
Applicant: Kao Corp
Inventor: AMIYA TSUYOSHI , TSUSHIMA RIKIO
Abstract: PURPOSE: A water-soluble cationized chitin suitable for use in cosmetics, perfumes, toiletries, etc., prepared by replacing the reactive hydrogen atoms of chitin by quat. nitrogen-containing groups and cleaving its intermolecular hydrogen bonds.
CONSTITUTION: A cationized chitin prepared by replacing the reactive hydrogen atoms in a chitin molecule by quat. nitrogen-containing groups represented by formula I (wherein R is methyl or ethyl and X is a halogen) and cleaving the intermolecular hydrogen bonds. Said modified chitin is produced by reacting 100pts.wt. chitin with at least about 30pts.wt. cationizing agent [e.g., a compound of formula II or III (glycidyltrialkylammonium or 3-chloro-2-hydroxypropyl- trialkylammonium salt)] in the presence of an alkali in an aqueous solvent (water and/or an alcohol), neutralizing and washing the product and dissolving it in, e.g., an aqueous chloride solution (≥about 1N) to cleave the intermolecular hydrogen bonds.
COPYRIGHT: (C)1986,JPO&JapioAbstract translation: 目的:适用于化妆品,香水,化妆品等的水溶性阳离子化壳多糖,通过用几何替代几丁质的反应性氢原子制备。 含氮基团并裂解其分子间氢键。 构成:通过用几何替代几丁质分子中的反应性氢原子制备的阳离子化几丁质。 由式I表示的含氮基团(其中R是甲基或乙基,X是卤素)并切断分子间氢键。 所述改性几丁质是通过使100pts.wt。 甲壳素至少约30pts.wt。 阳离子化剂[例如式II或III的化合物(缩水甘油基三烷基铵或3-氯-2-羟丙基 - 三烷基铵盐)]在碱存在下,在水溶剂(水和/或醇)中,中和并洗涤 产物并将其溶解在例如氯化氢水溶液(> =约1N)中以切割分子间氢键。
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公开(公告)号:JPS6015403A
公开(公告)日:1985-01-26
申请号:JP12378183
申请日:1983-07-07
Applicant: KAO CORP
Inventor: TSUSHIMA RIKIO , FUKUYAMA YUKIHIRO
Abstract: PURPOSE:The titled surfactant capable of giving an emulsion which is low- foaming and has high surface tension and excellent polymerization and mechanical stability, obtained by polymerizing a tert. amino group-containing monomer in the presence of a specified chain transfer agent and oxidizing the tert. amino groups. CONSTITUTION:A surfactant for emulsion polymerization comprising an amine oxide group-containing high-molecular compound of an average MW of 1,000- 10,000 is obtained by (co)polymerizing 30-100mol% tert. amino-group-containing monomer [e.g., (meth)allyldimethylamine] with 70-0mol% monomer copolymerizable therewith (e.g., styrene) at 40-100 deg.C in the presence of a 6-22C alkylmercaptan (e.g., octylmercaptan) as a chain transfer agent and a polymerization initiator (e.g., azobisiosbutyronitrile) in a lower alcohol solvent and oxidizing the tert. amino groups into amine oxide groups with an oxidizing agent (e.g., H2O2).
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公开(公告)号:JPS5787498A
公开(公告)日:1982-05-31
申请号:JP16425780
申请日:1980-11-21
Applicant: KAO CORP
Inventor: NAITOU YUKIO , OKUMURA TAKEO , MATSUNAGA KINJIROU , TSUSHIMA RIKIO
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公开(公告)号:JPS5785309A
公开(公告)日:1982-05-28
申请号:JP16002980
申请日:1980-11-13
Applicant: KAO CORP
Inventor: MATSUNAGA KINJIROU , OKUMURA TAKEO , NAITOU YUKIO , TSUSHIMA RIKIO
Abstract: PURPOSE:To prepare the titled composition giving the hair with excellent touch and having high wave-retainability, by adding hydrolyzed keratin and a cationic surfaceactive agent to a first cold-wave lotion containing a reducing substance as a subst-rate. CONSTITUTION:The titled composition is prepared by mixing a first cold-wave lotion containing a reducing substance as a substrate, with (A) hydrolyzed keratin (1-20wt%, pref. 2-5wt%) and (B) a cationic surface-active agent (0.5- 5wt%). The component (A) is pref. the one having a molecular weight of 200- 5,000 (esp. about 1,000) and obtained by hydrolyzing a keratinous material with an acid, an alkali or an enzyme; and above all, the enzymatic hydrolyzate is suitable for the application to cosmetics. The representative examples of the component (B) are the complunds of formula (one or two of R1-R4 are 8-20C alkyl, etc. and the others are 1-3C alkyl, etc.), etc.
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公开(公告)号:JPS5723631A
公开(公告)日:1982-02-06
申请号:JP9825680
申请日:1980-07-18
Applicant: Kao Corp
Inventor: MIYAMOTO TAKEAKI , AMIYA TSUYOSHI , TSUSHIMA RIKIO
IPC: C08H1/00
Abstract: PURPOSE: To obtain the titled keratin readily soluble in water and aqueous solvents, by readucing a Keratinous substance to cleave sulfhydryl groups, and reacting a cationic agent having a quaternary nitrogen atom and an epoxy group with the reduction product.
CONSTITUTION: A keratinous substance, e.g. wool, feather, hair or nail, is reduced with a reducing agent, e.g. 2-mercaptoethanol, in water or its mixture with an organic solvent, e.g. methanol, acetone or dioxane, to convert disulfide bonds into sulfhydryl bonds. The resultant product is then reacted with a cationic agent, e.g. glycidyltrimethylammonium chloride, having a group of formula I, II or III and a quaternary nitrogen atom in one molecule to give the aimed modified keratinous protein. Perferably, the reducing reaction is carried out at pH 6W11 and if necessary under heating for 2W3hr.
COPYRIGHT: (C)1982,JPO&JapioAbstract translation: 目的:获得容易溶于水和水性溶剂的标题角蛋白,通过读取角质物质以切割巯基,并使具有季氮原子和环氧基的阳离子剂与还原产物反应。 构成:角质物质,例如 羊毛,羽毛,头发或指甲,用还原剂还原。 2-巯基乙醇,在水中或其与有机溶剂的混合物,例如 甲醇,丙酮或二恶烷,将二硫键转化为巯基。 然后将所得产物与阳离子试剂反应,例如 缩水甘油基三甲基氯化铵,具有式I,II或III的基团和一个分子中的季氮原子,得到目标修饰的角质蛋白。 优选地,还原反应在pH6-11下进行,如果需要,加热2-3小时。
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公开(公告)号:JPS5662801A
公开(公告)日:1981-05-29
申请号:JP13969879
申请日:1979-10-29
Applicant: KAO CORP
Inventor: TSUSHIMA RIKIO , KOUNO YOSHINAO
IPC: C08B11/14
Abstract: PURPOSE:A cellulose ether is made to react with a glycidyl trialkyl ammonium halide in an aqueous medium in the presence of a catalyst such as barium hydroxide to increase the effective reaction rate, thus producing the titled compound used as flocculating agent. CONSTITUTION:(A) a cellulose ether such as hydroxyethylcellulose is made to react with (B) a glycidyl trialkylammonium halide such as glydicyl trimethylammonium chloride in a mixed solvent composed of water and a water-soluble organic solvent in the presence of (C) a catalyst of barium hydroxide alone or a combination thereof with another base such as lithium hydroxide to produce the objective cationic compound. USE:Beside flocculating agent, the titled compound is used as pigment holder, paper power strengthener, antistatic agent for fiber or ingredient for cosmetics and shampoo.
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公开(公告)号:JPH02255704A
公开(公告)日:1990-10-16
申请号:JP7691589
申请日:1989-03-29
Applicant: KAO CORP
Inventor: YOSHIMATSU AKIRA , KONDO AKIHIRO , TSUSHIMA RIKIO , SHIBATA YUTAKA , FUKUYAMA YUKIHIRO
IPC: C08L101/00 , B01J13/04 , C08F2/44
Abstract: PURPOSE:To obtain the subject highly absorbing and oil-absorbing fine particles by dispersing a monomer mixture containing a hydrophilic monomer containing polyethylene glycol mono(meth)acrylate and crosslinkable monomer in an aqueous medium in the presence of an oil-soluble substance and polymerizing the monomer mixture. CONSTITUTION:In an aqueous medium, is dispersed 100 pts.wt. monomer mixture containing 30-90 pts.wt. hydrophilic monomer containing polyethylene glycol mono(meth)acrylate and 10-70 pts.wt. crosslinking monomer [preferably polyethylene glycol di(meth)acrylate] in the presence of 10-300 pts.wt. oil-soluble substance (e.g. isopropyl alcohol). Polymerization of the monomer mixture is then carried out to afford the objective fine particles, consisting of shell walls of an organic polymer compound having 1.5-10 swelling degree for a liquid substance and capable of providing a spherical shape in enclosing the above- mentioned liquid substance and flat shape in releasing the aforementioned liquid substance.
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公开(公告)号:JPH0160005B2
公开(公告)日:1989-12-20
申请号:JP15314381
申请日:1981-09-28
Applicant: KAO CORP
Inventor: MATSUNAGA KINJIRO , OKUMURA TAKEO , TSUSHIMA RIKIO
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公开(公告)号:JPH0131761B2
公开(公告)日:1989-06-28
申请号:JP15443684
申请日:1984-07-25
Applicant: KAO CORP
Inventor: AMYA TSUYOSHI , TSUSHIMA RIKIO
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公开(公告)号:JPH01100562A
公开(公告)日:1989-04-18
申请号:JP25767487
申请日:1987-10-13
Applicant: KAO CORP
Inventor: TAKEMURA KAZUNARI , OTANI SHOJI , TSUSHIMA RIKIO
Abstract: PURPOSE:To obtain a toner which is sharp is grain size distribution and is unshaped while maintaining the dispersion stability at the time of suspension polymn. and to prevent defective cleaning by executing a specific method in a production consisting in dispersing a coloring agent and charge control agent into a polymerizable monomer, then executing the suspension polymn. CONSTITUTION:This production process contains the stage for excuting the polymn. by incorporating a polymn.-inert solvent into the polymerizable monomer or absorbing the polymn.-inert solvent in the polymerizable monomer after the polymn. of said monomer, then removing the polymn.-inert solvent. The toner obtd. in such a manner is the so-called unshaped toner having the undulations as if the surfaces are depressed and, therefore, the toner has the excellent cleanability. Since the toner has no sharply pointed parts as with the toner obtd. by a grinding method, the generation of the fine powder by friction with a carrier, etc., is obviated and the excellent printing resistance is obtd.
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