Abstract:
PURPOSE: A method for synthesizing bifunctional cinchona alkaloid catalyst is provided to ensure low toxicity, and chemical stability, and synthesize chiral hemiester having various structures in a short time. CONSTITUTION: A bifunctional cinchona alkaloid catalyst is denoted by chemical formula 1 or 2. A chiral hemiester is produced by reacting a prochiral or meso-cyclic acid anhydride with nucleophile in organic solvent under the presence of the bifunctional cinchona alkaloid catalyst. The nucleophile is alcohol or thiol. The organic solvent is dimethoxyethane, ethylvinyl ether, methyl t-butyl ether, diethyl ether, diisopropyl ether, tetra hydro furan or dioxane.
Abstract:
본 발명은 신규 플러렌 유도체 및 그의 제조 방법에 관한 것이다. 본 발명의 플러렌 유도체는 양이온성의 플러렌과 상대음이온으로 구성되어 있는 구조로 온화한 반응 조건에서 빠르고 간단하게 합성될 수 있으며, 용해도가 높고 안정할 뿐만 아니라 넓은 용매 범위를 갖는다. 또한, 대기 중의 산소나 습기와 반응하지 않아 안정할 뿐만 아니라 기계적 및 전기적 특성에 결정적 영향을 주는 구조적 변형이 거의 없다. 나아가, 본 발명의 플러렌 유도체의 음이온은 간단한 방법에 의해 다른 음이온으로 교환이 가능하며, 플러렌의 용해가 요구되는 용매의 종류에 따라 자유로운 용해성질 변환이 가능하다.
Abstract:
PURPOSE: A novel fullerene derivative and a method of preparing thereof are provided to simply synthesized the fullerene derivative in a mild reaction condition, and to prevent a constructive deformation without reacting with oxygen and a moisture among the atmosphere. CONSTITUTION: A novel fullerene derivative is marked as Q-C]^+[MXx]^-. In the formula, Q refers to fullerene. C refers to {(CH_2)lO}mH or CHhWvXn. W refers to a alkyl group or a aryl group. M refers to 13~15 group elements. X is a halogen element. L is an integer of 2~6. M is a fixed number of 1~50. H, V, and N is a fixed number of 0~3, respectively. The sum of H, V, and N is 3. A small letter x refers to a fixed number of 4 or 6. Q is selected from a group consisting of grapheme, a carbon nano tube, fullerite, torus, a nanobud, a nanoflower or buckyballs.
Abstract:
PURPOSE: A black photosensitive resin composition for a touch panel is provided to reduce the rate of change in resistance according to the change of temperatures by including graphite oxide and carbon black as a coloring agent. CONSTITUTION: A black photosensitive resin composition for a touch panel includes a coloring agent, an alkali soluble resin, a photo-polymerization compound, a photo-polymerization initiator, and a solvent. The coloring agent includes graphite oxide and carbon black. Rate of change in the sheet resistance of the composition from before to after thermal treatment at 300°C or more is 10Ω/cm^2 or less. 10-80 parts by weight of the graphite oxide is included based on 100 parts by weight of the composition(content of solid parts). 6-76 parts by weight of the carbon black is included based on 100 parts by weight of the composition(content of solid parts). The weight ratio of the graphite oxide and the carbon black is 1:3-3:1. Light shielding rate of the composition is 4.0 or more.
Abstract:
PURPOSE: A black photo-sensitive resin composition, a color filter, and a liquid display device including the same are provided to improve the electric insulation characteristic and the light shielding rate of the composition and to lower the dielectric constant of the composition. CONSTITUTION: A black photo-sensitive resin composition includes a coloring agent, an alkali soluble resin, a photopolymerizable compound, a photopolymerization initiator, and a solvent. The coloring agent includes graphite oxide and carbon black. 1-50 parts by weight of the graphite oxide are included in the composition based on 100 parts by weight of solid parts in the composition. The color filter includes a black matrix or a black column spacer which is formed by the exposure or the development of the composition on a substrate.
Abstract:
PURPOSE: A method for manufacturing chiral hemiester using bifunctional organic catalys is provided to synthesize chiral compound which stereochemically or pharmaceutically useful. CONSTITUTION: A bifunctional organic catalyst is denoted by chemical formula 1 or 2. In chemical formula 1 or 2, Ar is 4-11 reduction aryl; R2-R8 are independently hydrogen, alkyl of 1-12 carbon atoms, alkenyl of 2-12 carbon atoms, alkenyl of 2-12 carbon atoms, alkoxy of 1-12 carbon atoms, or aryl of 4-11 reduction; and P is non-reactive polymer. The non-reactive polymer is polystyrene, polyethylene, or polypropylene. A chiral hemiester is prepared by reacting prochiral compound or meso-cyclic acid anhydride with nucleophile under the presence of a compound of chemical formula 1 or 2. The nucleophile is alcohol, thiol, or amine.