Abstract:
본발명은고체산화물셀의작동효율을상승시키기위해환원방지막이구비된샌드위치박막구조의전해질을포함하는고체산화물셀 및그 제조방법에관한것으로서, 전해질층의환원을방지하고, 전해질두께를최소화하여고체산화물셀의내부저항을낮춰높은개회로전압을출력할수 있어이를적용한고체산화물셀은두꺼운전해질에비하여내부의온도구배가작아열충격저항성이상대적으로향상될수 있다. 또한, 제조과정중 고온의소성단계가없으므로단위전지구성요소간의소성온도격차를효과적으로줄임으로써, 고체산화물셀의제작을위한소성공정을크게단축시킬수 있고, 이를통해제조단가를절감할수 있다.
Abstract:
The present invention relates to a sealant for a low temperature operation solid oxide fuel cell and a manufacturing method thereof and, more specifically, to a sealant for plate-shaped solid oxide fuel cell stack which is operated at low operation temperatures of 700°C or less. The composite sealant according to the present invention exhibits excellent compression resistance and long term endurance at 700 °C, prevents a softening point from being increased while maintaining low nucleation rate, maintains stable states and has excellent thermal cycle sealing stability since leakage and deterioration are not generated, thereby being able to be usefully used as a sealant for a low temperature plate-shaped solid oxide fuel cell stack and being able to usefully used in a plate-shaped solid oxide fuel cell stack module, a plate-shaped solid oxide fuel cell system, a plate-shaped solid oxide fuel cell single cell including the composite sealant of the present invention and the like.
Abstract:
PURPOSE: Provided is a borosilicate based ceramic composition having excellent microwave dielectric property, which is fired at a low temperature of about 950 deg.C and is used in a low temperature co-fired ceramic(LTCC) multi-layer substrate. CONSTITUTION: The low temperature co-fired dielectric ceramic composition comprises 40-60 wt% of an amorphous borosilicate glass and 40-60 wt% of a filler. The dielectric ceramic composition is characterized in that the borosilicate glass is based on SiO2 and B2O3 and contains one or more alkali oxides selected from the group consisting of Na2O, MgO, Li2O and Al2O3 as a firing aid; and the filler is one or more materials selected from the group consisting of alumina, quartz and melt silica. Further, a low temperature co-fired dielectric ceramics are produced by pulverizing the ceramic composition to obtain finely ground powder, forming the powder and firing the formed product at 800-950 deg.C for 2 hours.
Abstract translation:目的:提供一种具有优异的微波介电性能的硼硅酸盐陶瓷组合物,其在约950℃的低温下烧制并用于低温共烧陶瓷(LTCC)多层基材中。 构成:低温共烧介电陶瓷组合物包含40-60重量%的无定形硼硅酸盐玻璃和40-60重量%的填料。 介电陶瓷组合物的特征在于,硼硅酸盐玻璃基于SiO 2和B 2 O 3,并且含有一种或多种选自Na2O,MgO,Li2O和Al2O3作为烧成助剂的碱金属氧化物; 并且填料是选自氧化铝,石英和熔融二氧化硅的一种或多种材料。 此外,通过将陶瓷组合物粉碎以获得精细研磨的粉末,形成粉末并在800-950℃下煅烧所形成的产物2小时来制备低温共烧介电陶瓷。
Abstract:
PURPOSE: A ultrafine dielectric ceramic composition for a low temperature plasticity is provided to achieve a low temperature plasticity and an ultrafine BaTiO3 dielectric ceramic composition by adding a proper sintering material to the BaTiO3. CONSTITUTION: A ultrafine dielectric ceramic composition for a low temperature plasticity is made based on the following formula BaTiO3 + xCu3TiO4. Here, x is ranging from 0.00 to 0.05. M2O3 is added to the composition as much as 0 to 5 mole. Here, M is one or more selected from the group consisting of La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er and Yb.