다공성 금속-유기 골격 물질의 기능화 방법, 이를 이용한 고체산 촉매 및 이 고체산 촉매를 이용한 알코올의 탈수 방법
    2.
    发明公开
    다공성 금속-유기 골격 물질의 기능화 방법, 이를 이용한 고체산 촉매 및 이 고체산 촉매를 이용한 알코올의 탈수 방법 无效
    多金属有机骨架材料的功能化方法,使用相同材料的固体催化剂和用相同催化剂脱醇的方法

    公开(公告)号:KR1020120118240A

    公开(公告)日:2012-10-26

    申请号:KR1020110035698

    申请日:2011-04-18

    Abstract: PURPOSE: A functionalizing method of porous metal-organic backbone materials, a solid catalyst using the same and a hydration method using the same are provided to effectively dehydrate alcohol as being operated as solid acid catalyst. CONSTITUTION: A functionalizing method of porous metal-organic backbone materials comprises the following steps: manufacturing suspended solution by mixing a compound which concurrently has thiol group and a location which can be coordinated with the porous metal - organic backbone material; heating the suspended solution from the first step; oxidizing the heated suspended solution with an oxidizer or oxidizing solid material obtained by solid-liquid separating the heated suspended solution by using the oxidizer; separating the solid from the reactant; and drying the separated solid.

    Abstract translation: 目的:提供多孔金属有机骨架材料的功能化方法,使用其的固体催化剂和使用其的水合方法,以有效地将醇作为固体酸催化剂进行脱水。 构成:多孔金属有机骨架材料的功能化方法包括以下步骤:通过混合同时具有硫醇基的化合物和可与多孔金属 - 有机骨架材料配位的位置制备悬浮溶液; 从第一步加热悬浮溶液; 通过使用氧化剂将加热的悬浮溶液进行固液分离而获得的氧化剂或氧化性固体物质氧化加热的悬浮液; 从反应物中分离固体; 并干燥分离的固体。

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