Abstract:
본 발명은 높은 표면적과 분자크기 또는 나노크기의 세공을 갖고 있어 흡착제, 기체 저장, 센서, 멤브레인, 기능성 박막, 촉매 및 촉매 담체 등에 사용될 수 있는 다공성 금속-유기 골격 물질을 기능화하는 방법, 이를 이용한 고체산 촉매의 제조방법 및 이 촉매를 이용한 알코올의 탈수 방법에 관한 것이다.
Abstract:
PURPOSE: A functionalizing method of porous metal-organic backbone materials, a solid catalyst using the same and a hydration method using the same are provided to effectively dehydrate alcohol as being operated as solid acid catalyst. CONSTITUTION: A functionalizing method of porous metal-organic backbone materials comprises the following steps: manufacturing suspended solution by mixing a compound which concurrently has thiol group and a location which can be coordinated with the porous metal - organic backbone material; heating the suspended solution from the first step; oxidizing the heated suspended solution with an oxidizer or oxidizing solid material obtained by solid-liquid separating the heated suspended solution by using the oxidizer; separating the solid from the reactant; and drying the separated solid.