公开(公告)号：KR100464810B1

公开(公告)日：2005-01-05

申请号：KR1020010038740

申请日：2001-06-30

Applicant: 한국화학연구원

Inventor： 김윤수 ,  김창균 ,  정택모 ,  오영우 ,  구상만 ,  박정우

IPC: C07F3/00

Abstract: PURPOSE: Provided is an organic alkali earth metal complex with thermal stability and good vaporization for formation of metal oxide composite films. The resultant complex is adapted to the production of semiconductors, photoelectrics and piezoelectrics. CONSTITUTION: The complex of organic alkali earth metals, L-M-L', is prepared by adding alcohol to organic solution containing alkali earth metal, expressed by the formula MX + xs HOR -->£M(OR)2|n, followed by mixing with chelate ligands L and L', expressed by the formula £M(OR)2|n + L + L' -->L-M-L', where M is Ba, Sr or Ca, L is R(CH3)CH(OH) (CH2)nCH(OH)(CH3)R'(R and R' are C1-C10 alkyl group, and n is an integer of 1-5), L' is N(CH2CH2XCH2CH2YZ)3(X and Y are O or NH, and Z is C1-C10 alkyl group).

Abstract translation: 用途：提供一种有机碱土金属配合物，具有热稳定性和良好的气化性，用于形成金属氧化物复合膜。 最终的复合体适用于半导体，光电和压电的生产。 构成：有机碱土金属络合物LM-L'通过向含有碱土金属的有机溶液中加入醇制备，由式MX + xs HOR→M（OR）2 n表示， 随后与由式M（OR）2 | n + L + L'→LM-L'表示的螯合配体L和L'混合，其中M是Ba，Sr或Ca，L是R （CH 3）CH（OH）（CH 2）NCH（OH）（CH 3）R '（R和R' 为C1-C10烷基，且n是1-5的整数），L”是N（CH2CH2XCH2CH2YZ）3 （X和Y是O或NH，Z是C 1 -C 10烷基）。

公开(公告)号：KR1020030002011A

公开(公告)日：2003-01-08

申请号：KR1020010038740

申请日：2001-06-30

Applicant: 한국화학연구원

Inventor： 김윤수 ,  김창균 ,  정택모 ,  오영우 ,  구상만 ,  박정우

IPC: C07F3/00

CPC classification number: C07F3/00 ,  C23C16/404

Abstract: PURPOSE: Provided is an organic alkali earth metal complex with thermal stability and good vaporization for formation of metal oxide composite films. The resultant complex is adapted to the production of semiconductors, photoelectrics and piezoelectrics. CONSTITUTION: The complex of organic alkali earth metals, L-M-L', is prepared by adding alcohol to organic solution containing alkali earth metal, expressed by the formula MX + xs HOR -->£M(OR)2|n, followed by mixing with chelate ligands L and L', expressed by the formula £M(OR)2|n + L + L' -->L-M-L', where M is Ba, Sr or Ca, L is R(CH3)CH(OH) (CH2)nCH(OH)(CH3)R'(R and R' are C1-C10 alkyl group, and n is an integer of 1-5), L' is N(CH2CH2XCH2CH2YZ)3(X and Y are O or NH, and Z is C1-C10 alkyl group).

Abstract translation: 目的：提供一种有机碱土金属络合物，具有热稳定性和良好的蒸发性，用于形成金属氧化物复合膜。 所得的复合物适用于制造半导体，光电和压电体。 构成：通过向含有碱土金属的有机溶液中加入醇制备有机碱土金属的混合物，由式MX + xs HOR→M（OR）2 | n表示，然后加入 与螯合配体L和L'混合，由式M M（OR）2 | n + L + L'→LM-L'表示，其中M是Ba，Sr或Ca，L是R（CH 3）CH （OH）（CH2）nCH（OH）（CH3）R'（R和R'是C1-C10烷基，n是1-5的整数），L'是N（CH2CH2XCH2CH2YZ）3（X和Y 是O或NH，Z是C 1 -C 10烷基）。