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公开(公告)号:KR1019930009792B1
公开(公告)日:1993-10-11
申请号:KR1019880009948
申请日:1988-08-04
Applicant: 한국화학연구원
IPC: C07D307/79
Abstract: Cyclohexane-1,3-dione derivs. of formula (I) are new. In the formula (I), R1, R2 and R3 are each C1-4 alkyl; R4=C1-4 alkyl; R5=C1-4 alkyl, C1-4 haloalkyl, C2-6 alkenyl, C2-6 haloalkenyl, C2-6 haloalkanoyl, substd. benzoyl, C1-6 alkyl or C2-6 alkoxy alkyl. Also claimed is the prepn. of (I) which comprises reacting 5- or 7- (2,3- dihydrobenaofuranyl)cyclohexane-1,3-dione with an organic acid anhydride in the presence of a base, reacting the obtd. cpd. with R5ONH2 HCl in the presence of a base, and reacting the obtd. oxime deriv. with R6X.
Abstract translation: 环己烷-1,3-二酮衍生物。 式(I)的化合物是新的。 在式(I)中,R 1,R 2和R 3各自为C 1-4烷基; R4 = C1-4烷基; R5 = C1-4烷基,C1-4卤代烷基,C2-6烯基,C2-6卤代链烯基,C2-6卤代烷酰基。 苯甲酰基,C 1-6烷基或C 2-6烷氧基烷基。 还声称是prepn。 的(I)化合物,其包括在碱的存在下使5-或7-(2,3-二氢苯并呋喃基)环己烷-1,3-二酮与有机酸酐反应。 CPD。 在碱存在下用R 5 ONH 2 H,并使该反应物反应。 肟衍生物 与R6X。
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公开(公告)号:KR1019950004700B1
公开(公告)日:1995-05-04
申请号:KR1019920010224
申请日:1992-06-12
Applicant: 한국화학연구원
IPC: C07D209/48
Abstract: The carbonyl derivatives at m-position of phenyl of phenyl-1,2,3,6-tetrahydro phthal imide (I) for herbicide is prepared by (1) reacting alpha-carbonyl compounds and N-(2-fluoro-4-chloro- 5-hydroxyphenyl) -1,2,3,6-tetrahydro phthalimide (IV) from 1,2,3,6-tetrahydro phthalate and 2-fluoro- 4-chloro- 5-hydroxy aniline to get N-fluoro-4-chloro- 5-O-[1-(2,4-dichlorophenyl0 ethane-1-on-2-yl - 1,2,3,6-tetrahydro phthalimide (VI) which has carbonyl group, (2) reacting (VI) and hydroxyl amines to get (I). (I) as herbicide is useful for tomato, wheat, soybean, corn and rice.
Abstract translation: 苯基-1,2,3,6-四氢邻苯二甲酰亚胺(I)苯基苯基m-位羰基衍生物用于除草剂是通过(1)使α-羰基化合物与N-(2-氟-4-氯 -5-羟基苯基)-1,2,3,6-四氢邻苯二甲酰亚胺(Ⅳ)和2-氟-4-氯-5-羟基苯胺得到N-氟-4 - 氯代-5-O- [1-(2,4-二氯苯基)乙烷-1-酮-2-基-1,2,3,6-四氢邻苯二甲酰亚胺(Ⅵ),其具有羰基,(2)使 )和羟胺得到(I)。(I)作为除草剂可用于番茄,小麦,大豆,玉米和水稻。
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