公开(公告)号：US11608399B2

公开(公告)日：2023-03-21

申请号：US17248381

申请日：2021-01-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ross E. Behling ,  Jason D. Clapper ,  Albert I. Everaerts ,  Chun-Yi Ting ,  Mark F. Ellis ,  Karl E. Benson ,  Jianhui Xia

IPC: C09J7/38 ,  C08F220/18 ,  C08F265/04 ,  C09J7/40 ,  C08J3/24

Abstract: Curable adhesive compositions are provided that can be cured using ultraviolet or visible light radiation. These curable adhesive compositions, which contain a curable (meth)acrylate copolymer, have a creep compliance that is less than 5(10−4) inverse Pascals at 25° C., a creep compliance that is greater than 1(10−3) inverse Pascals at 70° C., and a shear storage modulus greater than 40 kiloPascals when measured at 25° C. at a frequency of 1 radian/second.

公开(公告)号：US20200317956A1

公开(公告)日：2020-10-08

申请号：US16770984

申请日：2018-12-10

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Christopher J. Campbell ,  John W. Campbell ,  Mark F. Ellis ,  Kathleen S. Shafer ,  Wayne S. Mahoney

IPC: C09J4/00 ,  C08F2/50 ,  C09D4/00 ,  C08K5/55 ,  B32B27/30

Abstract: The present invention is an optically clear adhesive composition including a free-radically polymerizable acrylate or meth(acrylate) functional group oligomer, a trialkyl borane complex initiator, a photoacid generator, and a photosensitizer. A viscosity of the composition immediately after mixing and a viscosity of the composition about 24 hours after mixing changes by less than about 10%.

公开(公告)号：US20180265748A1

公开(公告)日：2018-09-20

申请号：US15761997

申请日：2016-09-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ross E. Behling ,  Jason D. Clapper ,  Albert I. Everaerts ,  Chun-Yi Ting ,  Mark F. Ellis ,  Karl E. Benson ,  Jianhui Xia

IPC: C09J7/38 ,  C08F220/18 ,  C08J3/24 ,  C09J7/40

CPC classification number: C09J7/385 ,  C08F220/18 ,  C08F265/04 ,  C08F2220/1825 ,  C08F2220/1841 ,  C08F2220/1858 ,  C08F2220/1891 ,  C08F2810/20 ,  C08J3/24 ,  C08J2333/10 ,  C09J7/405 ,  C09J2203/326 ,  C09J2205/114 ,  C09J2433/00 ,  C08F216/36 ,  C08F220/56 ,  C08F220/20 ,  C08F2220/301 ,  C08F220/34

Abstract: Curable adhesive compositions are provided that can be cured using ultraviolet or visible light radiation. These curable adhesive compositions, which contain a curable (meth)acrylate copolymer, have a creep compliance that is less than 5(10−4) inverse Pascals at 25° C., a creep compliance that is greater than 1(10−3) inverse Pascals at 70° C., and a shear storage modulus greater than 40 kiloPascals when measured at 25° C. at a frequency of 1 radian/second.

公开(公告)号：US20170081567A1

公开(公告)日：2017-03-23

申请号：US15311224

申请日：2015-05-26

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Sung-Won Ha ,  Babu N. Gaddam ,  Mark F. Ellis ,  Hae-Seung Lee ,  John R. Jacobsen

IPC: C09J133/08 ,  C08F220/18 ,  C09J7/02

CPC classification number: C09J133/08 ,  C08F2/38 ,  C08F2/50 ,  C08F220/06 ,  C08F220/18 ,  C08F265/06 ,  C08L2312/00 ,  C09J4/00 ,  C09J4/06 ,  C09J7/385 ,  C09J151/003 ,  C09J2433/00 ,  C08F2220/1858 ,  C08F2220/1841

Abstract: A method for preparing an acrylate adhesive is provided by the steps of partially polymerizing a monomer mixture to provide a syrup polymer composition having a high molecular weight solute copolymer. This first syrup composition is again polymerized to provide a second syrup polymer composition having a low molecular weight copolymer. The second syrup polymer composition is provided with a crosslinking agent and further polymerized to provide the adhesive composition.

公开(公告)号：US20160326290A1

公开(公告)日：2016-11-10

申请号：US15108324

申请日：2014-12-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ramesh C. Kumar ,  Mark F. Ellis ,  John R. Jacobsen ,  Michael A. Lockett ,  Rajdeep S. Kalgutkar

IPC: C08F220/68 ,  B05D1/04 ,  B05D1/02 ,  B05D1/18 ,  C09J7/02 ,  B05D1/30

CPC classification number: C08F220/68 ,  B05D1/02 ,  B05D1/04 ,  B05D1/18 ,  B05D1/305 ,  C08F2/38 ,  C08F220/14 ,  C08F220/18 ,  C08F228/00 ,  C08L2312/08 ,  C09J7/20 ,  C09J7/255 ,  C09J133/08 ,  C09J143/04 ,  C09J2433/00 ,  C09J2467/006 ,  C08F2220/1891 ,  C08F2230/085 ,  C08F220/44

Abstract: A composition suitable for use as a low adhesion backsize or a primer for low surface energy adhesives, including the reaction product of at least one moisture-curable, semi-crystalline (meth)acrylic oligomer represented by the formula: wherein R1 is independently a C16 to C40 alkyl group; R2 is independently a C1 to C40 alkyl group; each R3 is independently a methyl, ethyl, or isopropyl group; X is a chain transfer agent as defined further below; Y is independently selected to be a methyl, ethyl, or isopropyl group; a, b and c are each independently selected to be an integer of at least 10, and a+b+c 1; and p is 0, 1, 2, or 3. Articles and methods of using the composition as a low adhesion backsize or a primer for a low surface energy adhesive are also described.

公开(公告)号：US20230365841A1

公开(公告)日：2023-11-16

申请号：US18247988

申请日：2021-10-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Peter M. Simone ,  Jason D. Clapper ,  Mark F. Ellis ,  Hollis Z. Beagi ,  Matthew H. Wessel

IPC: C09J7/38 ,  C09J7/35

CPC classification number: C09J7/385 ,  C09J7/35 ,  C09J2203/326 ,  C09J2301/302 ,  C09J2301/304 ,  C09J2301/416 ,  C09J2301/414 ,  C09J2451/00

Abstract: A crosslinkable composition, a crosslinked composition formed upon exposure of the crosslinkable composition to ultraviolet radiation or ionizing radiation, articles containing these crosslinkable or crosslinked compositions, and methods of making the articles are described. The crosslinkable compositions contain two different (meth)acrylate polymers and can be applied to a substrate using an extrusion process. While being extruded, the crosslinkable compositions advantageously are resistant to crosslinking and/or significantly increasing in molecular weight. The crosslinked compositions can function as either a pressure-sensitive adhesive composition or a heat bondable adhesive composition and are particularly well suited for use in electronic devices.

公开(公告)号：US11655403B2

公开(公告)日：2023-05-23

申请号：US16621276

申请日：2018-06-27

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Kelly A. Volp ,  Kathleen S. Shafer ,  Ross E. Behling ,  Ann M. Gilman ,  Mark F. Ellis ,  Matthew R. D. Smith ,  Aaron T. Hedegaard ,  Xiaoming Jiang ,  Cyrus A. Anderson

IPC: C09J133/14 ,  C08L33/14 ,  C09J7/38

CPC classification number: C09J133/14 ,  C08L33/14 ,  C09J7/38 ,  C09J7/385 ,  B32B2405/00 ,  C09J2433/00

Abstract: A curable mixture, a partially cured composition, a cured composition, an article containing either the partially cured composition or the cured composition, and a method of bonding two substrates are provided. The partially cured composition functions as a pressure-sensitive adhesive while the cured composition functions as a structural or semi-structural adhesive. The curable mixture can be applied to a first substrate by printing or dispensing, if desired.

公开(公告)号：US11578162B2

公开(公告)日：2023-02-14

申请号：US17250643

申请日：2019-08-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jayshree Seth ,  Mark F. Ellis ,  Eric W. Nelson ,  Janet A. Venne ,  Christopher C. Pope ,  Matthew H. Wessel

IPC: C08F2/46 ,  C08F2/50 ,  C08G61/04 ,  C08F265/06 ,  C09J7/38 ,  C08F220/18 ,  C08F220/20 ,  C08F220/36 ,  C08K5/105 ,  C08K5/5397

Abstract: Curable compositions, cured compositions, articles containing the curable or cured compositions, and methods of making the articles are provided. More particularly, the curable compositions contain a (meth)acrylate-based polymer having pendant (meth)acryloyl groups, at least one monomer having a single ethylenically unsaturated group, a photoinitiator that includes an acyl phosphine oxide, and a thixotropic agent. The curable compositions can be printed or dispensed, if desired, and the cured compositions are pressure-sensitive adhesives.

公开(公告)号：US12116508B2

公开(公告)日：2024-10-15

申请号：US17310443

申请日：2020-02-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Enzhong Zhang ,  Xiaoming Jiang ,  Lin Yang ,  Mark F. Ellis

IPC: C09J4/00 ,  C08F220/18 ,  C09J133/06

CPC classification number: C09J4/00 ,  C08F220/1808 ,  C09J133/066 ,  C09J133/068 ,  C08F2800/20

Abstract: The present invention provides a UV curable adhesive, wherein based on a total weight of the UV curable adhesive, the UV curable adhesive comprises: from 30 to 70 wt % of an acrylate oligomer; from 20 to 65 wt % of an acrylate monomer; from 1 to 10 wt % of acryloyl morpholine; from 1 to 15 wt % of a photo initiator; and from 0 to 10 wt % of a thickening agent, wherein the acrylate oligomer has a weight average molecular weight in a range of from 10,000 to 100,000 grams/mole and a glass transition temperature in a range of from −50 to 0° C. According to the technical solution of the present invention, the adhesive layer obtained from curing the UV curable adhesive is relatively thick (for example, 0.8 mm), and the adhesive layer has good adhesion property, cohesive force, and tackiness.

公开(公告)号：US20220073792A1

公开(公告)日：2022-03-10

申请号：US17417695

申请日：2019-12-27

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Audrey A. Sherman ,  Mark F. Ellis ,  Barbara L. Kellen ,  David A. Cadalbert

IPC: C09J7/38 ,  C08F220/06 ,  C08F220/18 ,  C08F220/20 ,  C08G77/20

Abstract: Adhesive articles with multi-layer adhesive constructions include a substrate and a multi-layered adhesive. The multi-layered adhesive includes a layer of a first adhesive in contact with the surface of the substrate, and a layer of siloxane-based pressure sensitive adhesive in contact with the first adhesive. The siloxane-based pressure sensitive adhesive includes a siloxane-(meth)acrylate co-polymer. The thickness of the siloxane-based pressure sensitive adhesive layer is less than the thickness of the first adhesive layer.