Abstract:
An novel epoxy compound is represented by the general formula (I) and has a benzo- or naphtho-cycloalkane skeleton: wherein, X, Y, and Z each independently represent an alkyl group having 1 to 10 carbon atoms and optionally substituted with a halogen atom, an aryl group having 6 to 20 carbon atoms and optionally substituted with a halogen atom, an arylalkyl group having 7 to 20 carbon atoms and optionally substituted with a halogen atom, a heterocyclic group having 2 to 20 carbon atoms and optionally substituted with a halogen atom, or a halogen atom; k represents a number of 0 to 4; p represents a number of 0 to 8; r represents a number of 0 to 4; n represents 0 to 10; x represents a number of 0 to 4; y represents a number of 0 to 4; a sum of x and y is 2 to 4; and an optical isomer that exists when n is not 0 may be of any type.
Abstract:
The invention provides a novel compound useful as a highly-sensitive photopolymerization initiator that has excellent stability, low sublimability, excellent developability, and high transmittance in the visible region and that efficiently absorbs, and is activated by, near-ultraviolet rays such as at 365 nm. Also provided are a photopolymerization initiator and a photosensitive composition using the above-described compound. Specifically, the invention provides an oxime ester compound represented by the following general formula (I), a photopolymerization initiator containing the same, and a photosensitive composition containing the photopolymerization initiator and a polymerizable compound having an ethylenically unsaturated bond: wherein, R 1 and R 2 each represent R 11 , COR 11 , CONR 12 R 13 , CN, etc.; R 11 , R 12 , and R 13 each represent a C 1-20 alkyl group, etc.; R 3 and R 4 each represent R 11 , OR 11 , COR 11 , CONR 12 R 13 , OCOR 11 , CN, a halogen atom, etc.; a and b each represent an integer of 0 to 4; X represents an oxygen atom, a sulfur atom, etc.; and R 5 represents OH, COOH, or a group represented by general formula (II).
Abstract:
An oxime ester compound represented by general formula (I): wherein R 1 , R 2 , and R 3 each independently represent R 11 , OR 11 , COR 11 , SR 11 , CONR 12 R 13 , or CN; R 11 , R 12 , and R 13 each independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an arylalkyl group having 7 to 30 carbon atoms, or a heterocyclic group having 2 to 20 carbon atoms, R 4 and R 5 each independently represent R 11 , OR 11 , SR 11 , COR 11 , CONR 12 R 13 , NR 12 COR 11 , OCOR 11 , COOR 11 , SCOR 11 , OCSR 11 , COSR 11 , CSOR 11 , CN, a halogen atom, or a hydroxyl group; and a and b each independently represent 0 to 3.
Abstract:
A novel compound having satisfactory sensitivity (base generating performance), a photosensitive resin composition containing the compound as a photo-initiator, and a cured product of the composition are provided. Specifically, a compound represented by general formula (1) (compound (1)), a photosensitive resin composition containing (A) a photo-initiator comprising at least one compound (1) and (B) a photosensitive resin are provided. Preferred are the compound (1) in which R 1 is an unsubstituted or substituted C6-C20 aromatic hydrocarbon group, the compound (1) in which at least one of R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , and R 11 is nitro, and the compound (1) in which n is 0. The symbols in general formula (1) are as defined in the description.
Abstract:
PROBLEM TO BE SOLVED: To provide an alkaline developable photosensitive resin composition, having excellent sensitivity and contactness to form a micro-pattern with good accuracy, although a photopolymerization initiator is not used or a small quantity thereof is used. SOLUTION: This alkaline developable photosensitive resin composition contains a hydroxyl group of a reaction product obtained by adding carbazolyl group containing β-diketone compound to the (meta) acryloyl group of a compound having two or more (meta) acryloyl groups and hydroxyl groups, and a photopolymerizable unsaturated compound having a structure obtained by esterification reaction with polybasic acid anhydride. COPYRIGHT: (C)2010,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a β-diketone compound having a substituent, capable of efficiently absorbing light. SOLUTION: The β-diketone compound having a carbazolyl group is represented by formula (I) (wherein R 1 is a 1-20C alkyl group; R 2 is R 11 , OR 11 , COR 11 , SR 11 , CONR 12 R 13 or CN; R 11 , R 12 and R 13 are each independently a hydrogen atom, a 1-20C alkyl group, a 6-30C aryl group, a 7-30C arylalkyl group or a 2-20C heterocyclic group; and R 3 and R 4 are each independently a substituent represented by R 11 , OR 11 , SR 11 , COR 11 , CONR 12 R 13 , NR 12 COR 11 , OCOR 11 , COOR 11 , SCOR 11 , OCSR 11 , COSR 11 , CSOR 11 , CN, a halogen atom, a nitro group or a hydroxyl group). COPYRIGHT: (C)2009,JPO&INPIT