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公开(公告)号:WO2016142377A1
公开(公告)日:2016-09-15
申请号:PCT/EP2016/054903
申请日:2016-03-08
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: CHEVALIER, Reynald , MIGNOGNA, Alessandro , MORINI, Giampiero
CPC classification number: C08F110/06 , C07F7/28 , C08F2500/12 , C08F2500/15 , C08F4/651
Abstract: A solid catalyst component which exhibits high activity and stereo specificity polymerization of olefins comprising Mg, Ti and an electron donor of formula (I) where R and R 1 are selected from C 1 -C 20 hydrocarbon groups C 6 -C 14 aryl or alkylaryl groups hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N,O; R 2 to R 11 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups which can be optionally fused together to form one or more cycles with the proviso that R 6 and R 11 cannot join together to form a phenyl ring.
Abstract translation: 显示出具有式(I)的Mg,Ti和电子给体的烯烃的高活性和立体特异性聚合的固体催化剂组分,其中R和R 1选自C 1 -C 20烃基C 6 -C 14芳基或烷基芳基烃基,任选地 含有选自卤素,P,S,N,O的杂原子; R 2至R 11基团彼此相同或不同,为氢,卤素或C 1 -C 15烃基,其可以任选地稠合在一起形成一个或多个循环,条件是R 6和R 11不能连接在一起形成苯环 。
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公开(公告)号:WO2016142334A1
公开(公告)日:2016-09-15
申请号:PCT/EP2016/054772
申请日:2016-03-07
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MIGNOGNA, Alessandro , MORINI, Giampiero , CHEVALIER, Reynald
CPC classification number: C08F110/06 , C08F4/6455 , C08F4/6457 , C08F4/649 , C08F4/6495 , C08F4/6498 , C08F2410/01 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6543
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti, halogen and an electron donor of formula (I) or (II). When activated with an aluminum alkyl and optionally an external electron donor is capable to give high activity and stereospecificity in the polymerization of olefins.
Abstract translation: 包含Mg,Ti,卤素和式(I)或(II)的电子给体的烯烃聚合的固体催化剂组分。 当用烷基铝和任选的外部电子给体活化时,能够在烯烃聚合中产生高活性和立体定向性。
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公开(公告)号:WO2014184171A1
公开(公告)日:2014-11-20
申请号:PCT/EP2014/059717
申请日:2014-05-13
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MIGNOGNA, Alessandro , CHEVALIER, Reynald , GUIDOTTI, Simona , LIGUORI, Dario , MORINI, Giampiero , SCHNEIDER, Martin
CPC classification number: C08F110/06 , C07C271/44 , C07C2601/14 , C07C2602/08 , C08F4/6545 , C08F4/6543 , C08F4/651 , C08F2500/12 , C08F2500/15
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from specific diphenol derivatives.
Abstract translation: 一种用于烯烃聚合的固体催化剂组分,包括Mg,Ti,Cl和至少一种电子给体化合物,它是通过与Mg化合物和至少具有Ti-卤素键的电子与电子接触而获得的反应产物 供体选自具体的二酚衍生物。
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公开(公告)号:WO2014184289A1
公开(公告)日:2014-11-20
申请号:PCT/EP2014/059938
申请日:2014-05-15
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MIGNOGNA, Alessandro , CHEVALIER, Reynald , KASHULIN, Igor , NIFANT'EV, Ilya , MORINI, Giampiero , SCHNEIDER, Martin
CPC classification number: C08F110/06 , C07C327/26 , C07C327/28 , C07C329/10 , C07C333/04 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6545
Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I) In which X and Y are selected from, R 1 , and -OR 1 and -NR 2 , B is oxygen or sulphur S is sulphur, R 1 is selected from C 1 -C 15 hydrocarbon groups, optionally contain a heteroatom selected from halogen, P, S, N,0 and Si, which can be fused together to form one or more cycles, R is hydrogen or R 1 and A is a bivalent bridging group with chain length between the two bridging bonds being 1-10 atoms.
Abstract translation: 用于聚合含有Mg,Ti和式(I)的电子给体的烯烃的催化剂组分其中X和Y选自R 1和-OR 1和-NR 2,B是氧或硫,S是硫,选择R 1 C 1 -C 15烃基任选地含有选自卤素,P,S,N,O和Si的杂原子,其可以稠合在一起以形成一个或多个循环,R是氢或R 1,并且A是二价桥连基, 两个桥键之间的链长为1-10个原子。
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公开(公告)号:WO2015032939A1
公开(公告)日:2015-03-12
申请号:PCT/EP2014/069056
申请日:2014-09-08
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MIGNOGNA, Alessandro , CHEVALIER, Reynald , MORINI, Giampiero , SCHNEIDER, Martin
IPC: C08F4/651 , C08F110/06 , C07C271/12 , C08F4/654
CPC classification number: C08F110/06 , C07C271/12 , C08F4/651 , C08F2500/12
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I), where R 1 is selected from C 1 -C 15 hydrocarbon groups, R 2 groups, equal to or different from each other, are hydrogen or R 1 groups which can be fused together to form one or more cycles and A is a bivalent bridging group. The said catalyst components exhibit high activity and stereo specificity in the polymerization of olefins.
Abstract translation: 包含Mg,Ti和式(I)的电子给体的烯烃聚合的固体催化剂组分为氢或R 1基团,其中R 1选自C 1 -C 15烃基,R 2基团彼此相同或不同 其可以融合在一起以形成一个或多个循环,并且A是二价桥连基团。 所述催化剂组分在烯烃聚合中表现出高活性和立体特异性。
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公开(公告)号:EP2997050B1
公开(公告)日:2018-01-17
申请号:EP14727427.8
申请日:2014-05-13
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: MIGNOGNA, Alessandro , CHEVALIER, Reynald , GUIDOTTI, Simona , LIGUORI, Dario , MORINI, Giampiero , SCHNEIDER, Martin
CPC classification number: C08F110/06 , C07C271/44 , C07C2601/14 , C07C2602/08 , C08F4/6545 , C08F4/6543 , C08F4/651 , C08F2500/12 , C08F2500/15
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from specific diphenol derivatives.
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公开(公告)号:EP3268396A1
公开(公告)日:2018-01-17
申请号:EP16709005.9
申请日:2016-03-07
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: MIGNOGNA, Alessandro , MORINI, Giampiero , CHEVALIER, Reynald
CPC classification number: C08F110/06 , C08F4/6455 , C08F4/6457 , C08F4/649 , C08F4/6495 , C08F4/6498 , C08F2410/01 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6543
Abstract: When activated with an aluminum alkyl and optionally an external electron donor, solid catalyst component can give high activity and stereospecificity in the polymerization of olefins.
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公开(公告)号:EP2997049B1
公开(公告)日:2017-08-23
申请号:EP14724437.0
申请日:2014-05-15
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: MIGNOGNA, Alessandro , CHEVALIER, Reynald , KASHULIN, Igor , NIFANT'EV, Ilya , MORINI, Giampiero , SCHNEIDER, Martin
CPC classification number: C08F110/06 , C07C327/26 , C07C327/28 , C07C329/10 , C07C333/04 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6545
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公开(公告)号:EP3044239A1
公开(公告)日:2016-07-20
申请号:EP14759226.5
申请日:2014-09-08
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: MIGNOGNA, Alessandro , CHEVALIER, Reynald , MORINI, Giampiero , SCHNEIDER, Martin
IPC: C08F4/651 , C08F110/06 , C07C271/12 , C08F4/654
CPC classification number: C08F110/06 , C07C271/12 , C08F4/651 , C08F2500/12
Abstract: The present technology relates to a solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of the general formula (I): where R1 is selected from C1-C15 hydrocarbon groups, the R2 groups are equal to or different from each other, are hydrogen, or the R1 groups can be fused together to form one or more cycles and A is a bivalent bridging group. The catalyst components of the present disclosure exhibit high activity and stereospecificity in the polymerization of olefins.
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公开(公告)号:EP3268398A1
公开(公告)日:2018-01-17
申请号:EP16709346.7
申请日:2016-03-08
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: CHEVALIER, Reynald , MIGNOGNA, Alessandro , MORINI, Giampiero
CPC classification number: C08F110/06 , C07F7/28 , C08F2500/12 , C08F2500/15 , C08F4/651
Abstract: where R and R1 are selected from the group consisting of C1-C20 hydrocarbon groups, C6-C14 aryl or alkylaryl groups hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of halogens, P, S, N, and O; R2 to R11 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups which can be optionally fused together to form one or more cycles with the proviso that R6 and R11 cannot join together to form a phenyl ring.
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