CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    2.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号:WO2016184884A1

    公开(公告)日:2016-11-24

    申请号:PCT/EP2016/061078

    申请日:2016-05-18

    CPC classification number: C08F4/651 C08F110/06 C08F2500/12 C08F2500/15

    Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and a an electron donor of formula (I) where independently, Z is a bridging group, the R 2 groups, equal to or different from each other, are hydrogen or a C 1 -C 20 hydrocarbon radicals, m is a number satisfying the valences of Z and n is an integer ranging from 1 to 10, R 1 and R 4 are selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N,O; and R 3 group, is hydrogen or R 4 groups. The catalyst system based on the solid catalyst component is endowed with high activity and stereospecificity.

    Abstract translation: 一种用于烯烃聚合的固体催化剂组分,其包含Mg,Ti和式(I)的电子给体,其中独立地Z为桥连基,R2基彼此相同或不同,为氢或C1- C20烃基,m是满足Z的化合价的数,n是1至10的整数,R 1和R 4选自C 1 -C 15烃基,任选地含有选自卤素,P,S,N, O; 和R 3基团,是氢或R 4基团。 基于固体催化剂组分的催化剂体系具有高活性和立体定向性。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    3.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号:WO2016156473A1

    公开(公告)日:2016-10-06

    申请号:PCT/EP2016/057031

    申请日:2016-03-31

    Abstract: Catalyst component for the polymerization of olefins comprising Mg. Ti and an electron donor belonging to mercaptoester derivatives of specific formula (I) in which Z is selected from C, Si, O, N, S or P with the proviso that the atoms O, S, P and N are not directly linked to either the carboxylic group or the sulphur atom of formula (I), the R 2 groups, equal to or different from each other, are hydrogen or a C 1 -C 20 hydrocarbon radicals, optionally containing a heteroatom selected from halogen, P, S, N,O and Si, which can be fused together to form one or more cycles, m is a number satisfying the valences of Z and n is an integer ranging from 1 to 10, X is O or S, Y is -OR 3 , -NR 4 R 5 ) or R 6 groups in which R 1 and R 3 are selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N,O, and Si, R 4 -R 5 groups, independently, are hydrogen or R 1 groups and R 6 groups have the same meaning as R 1 groups.

    Abstract translation: 包含Mg的烯烃聚合的催化剂组分。 Ti和属于特定式(I)的巯基酯衍生物的电子给体,其中Z选自C,Si,O,N,S或P,条件是原子O,S,P和N不直接连接到 式(I)的羧基或硫原子,相同或不同的R 2基团是氢或C 1 -C 20烃基,任选地含有选自卤素,P,S,N, O和Si,其可以融合在一起形成一个或多个循环,m是满足Z的化合价的数,n是1至10的整数,X是O或S,Y是-OR 3,-NR 4 R 5) 或R6基团,其中R 1和R 3选自C 1 -C 15烃基,任选地含有选自卤素,P,S,N,O和Si的杂原子,R 4 -R 5基团独立地为氢或R 1基团,R 6 组与R1组具有相同的含义。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    4.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号:WO2013182585A1

    公开(公告)日:2013-12-12

    申请号:PCT/EP2013/061546

    申请日:2013-06-05

    Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups equal to or different from each other, are C 1 -C 15 hydrocarbon groups, the R 1 -R 2 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which can be fused together to form one or more cycles; n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0 and that diisobutyl o-phenylenediacetate is excluded.

    Abstract translation: 包含Mg,Ti和其中R基彼此相同或不同的下式(I)的电子给体化合物的烯烃聚合催化剂组分是C 1 -C 15烃基,R 1 -R 2基, 相同或不同的是氢,卤素或C 1 -C 15烃基,任选地含有选自卤素,P,S,N和Si的杂原子,其可以一起稠合形成一个或多个循环; n和m是0-3的整数,条件是它们中的至少一个不同于0,并且排除邻苯二乙酸二异丁酯。

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