公开(公告)号：JPH1060368A

公开(公告)日：1998-03-03

申请号：JP13815597

申请日：1997-05-28

Applicant: BASF AG

Inventor： BAUMSTARK ROLAND DR ,  DERSCH ROLF DR

IPC: C08F2/30 ,  C08F2/22 ,  C08F2/24 ,  C08F2/32 ,  C08F4/34 ,  C08F220/18 ,  C09D125/08 ,  C09D125/14 ,  C09D133/00 ,  C09D133/06 ,  C09D133/08 ,  C09D133/18 ,  C09D135/02 ,  C09D135/04 ,  C09D157/00

Abstract: PROBLEM TO BE SOLVED: To provide a low-odor binder for a low-release coating compsn. which mainly comprises a water-base polymer dispersion having a film-forming temp. of 10 deg.C or lower and can dispense with a solvent. SOLUTION: A water-base polymer dispersion is obtd. by the free-radical waterbase emulsion polymn. of a monomer mixture contg. 45-70 pts.wt. at least one monomer of which the homopolymer has a glass transition point lower than 20 deg.C. 30-55 pts.wt. at least one monomer of which the homopolymer has a glass transition point higher than 50 deg.C, 0-1 pt.wt. at least one monomer having an acid group, and 0-2 pts.wt. at least one other monomer selected from among a 3-6C α, '-unsatd. carboxamide, its 2-6C hydroxyalkyl ester, and an N- vinyllactam.

公开(公告)号：JP2001106861A

公开(公告)日：2001-04-17

申请号：JP2000247546

申请日：2000-08-17

Applicant: BASF AG

Inventor： BAUMSTARK ROLAND DR ,  KIRSCH STEFAN ,  DERSCH ROLF DR ,  DOBBELAAR JOHANNES ,  MELAN MICHAEL

IPC: C08L33/06 ,  C08F2/24 ,  C08F212/02 ,  C08F212/04 ,  C08F220/12 ,  C08K5/00 ,  C08L25/00 ,  C09D5/02 ,  C09D125/02 ,  C09D133/06 ,  E04C2/04

Abstract: PROBLEM TO BE SOLVED: To obtain a binder formulation based on an aqueous polymer dispersion which assures uniform film formation without addition of a coalescing agent and forms a coating film of low adhesion and high blocking resistance. SOLUTION: The binder formulation has a minimum film-forming temperature of 10 deg.C or less, contains at least one anionic emulsifying agent and at least one nonionic emulsifying agent, and further contains at least one binder polymer in the form of an aqueous dispersion, the binder polymer comprising monomers of A1, A2, A3, B, C, D and E, where the monomer A1 is a vinyl aromatic monomer, A2 is a 1-4C methacrylate, A3 is acrylnitrile or methacrylonitrile, the monomer B is one kind selected from 1-18C alkyl acrylate and 5-18C alkyl methacrylates, C is methacrylic acid, D is one kind selected from 3-6C monoethylenically unsaturated monocarboxylic amides and 1-4C hydroxyalkyl esters and E is ethylene glycole diacrylate, or the like.

公开(公告)号：DE4334178A1

公开(公告)日：1995-04-13

申请号：DE4334178

申请日：1993-10-07

Applicant: BASF AG

Inventor： BAUMSTARK ROLAND DR ,  PORTUGALL MICHAEL DR

IPC: C08L57/00 ,  C08F2/22 ,  C08K5/07 ,  C08L33/06 ,  C09D129/00 ,  C09D129/10 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C09D133/24 ,  C09D137/00 ,  C09D139/00 ,  C09D141/00 ,  C09D157/00 ,  C09D157/12 ,  C09D201/02 ,  C09J157/00 ,  C09J201/00 ,  C09K3/10 ,  C08L39/00 ,  C08L33/14 ,  C08L33/24 ,  C08J3/03 ,  C08F26/00 ,  C08F20/34 ,  C08F20/60 ,  C09J139/00

Abstract: PCT No. PCT/EP94/03224 Sec. 371 Date Mar. 11, 1996 Sec. 102(e) Date Mar. 11, 1996 PCT Filed Sep. 27, 1994 PCT Pub. No. WO95/09896 PCT Pub. Date Apr. 13, 1995Aqueous polymer compositions which contain a polymer having ureido groups and a polyaldehyde compound are suitable for the production of coatings having high adhesion to substrate and having high cohesion.

公开(公告)号：DE4435422A1

公开(公告)日：1996-04-18

申请号：DE4435422

申请日：1994-10-04

Applicant: BASF AG

Inventor： BAUMSTARK ROLAND DR ,  RUPANER ROBERT DR

IPC: C08F2/00 ,  C08F2/16 ,  C08F2/22 ,  C08F4/40 ,  C08F6/00 ,  C08F12/08 ,  C08F14/06 ,  C08F14/08 ,  C08F18/08 ,  C08F18/10 ,  C08F20/04 ,  C08F20/12 ,  C08F20/56 ,  C08F6/14 ,  C08J3/03

Abstract: A process is disclosed for preparing an aqueous polymer dispersion. An aqueous dispersion of a polymer that contains at least one chemically bound, incorporated monomer containing at least one ethylenically unsaturated group, is prepared in a manner known per se, so that the aqueous polymer dispersion contains in total more than 0 but less than or 1 % by weight of free, i.e. non chemically bound monomers having an ethylenically unsaturated double bond, in relation to the polymer content of the aqueous polymer dispersion. This residual monomer content is then reduced with a radical redox initiator system containing at least one oxidising agent and at least one reducing agent. The redox initiator system contains as reducing agent a reducing agent that is present in an aqueous solution in at least two mutually balanced tautomer forms, for example the aminoiminomethanosulfinic acid and/or its salts.

公开(公告)号：DE4315207A1

公开(公告)日：1994-11-10

申请号：DE4315207

申请日：1993-05-07

Applicant: BASF AG

Inventor： BAUER GERHARD DR ,  HAEBERLE KARL DR ,  BAUMSTARK ROLAND DR ,  BOTT KASPAR DR

IPC: C07C251/54 ,  C07C271/12 ,  C07C271/28 ,  C08G18/80 ,  C08K5/33 ,  C07C271/10 ,  C07C251/38 ,  C08J3/24 ,  C09D109/00 ,  C09D125/02 ,  C09D127/02 ,  C09D129/10 ,  C09D131/02 ,  C09D133/00 ,  C09J11/06

公开(公告)号：DE19720345A1

公开(公告)日：1997-12-04

申请号：DE19720345

申请日：1997-05-15

Applicant: BASF AG

Inventor： BAUMSTARK ROLAND DR ,  WILDBURG GERALD DR ,  HAEUSLING LUKAS DR ,  GUENTHER WULFF PROF DR ,  SCHOENFELD RAINER ,  GRUEN MICHAEL

IPC: C09J125/08 ,  C09J125/18 ,  C09J157/10 ,  C09K3/10 ,  D06M15/233 ,  D06M15/263 ,  D06M15/285 ,  D06M15/327 ,  D06M15/347 ,  D06M15/356 ,  D06M17/06 ,  C09J133/26 ,  C09D123/00 ,  C09D125/18 ,  C09D133/26 ,  C09J123/00

Abstract: An adhesive contains a polymer comprising 0.1-100 wt.% monomers of formula (I). In (I): R1-R6 = H or 1-18C alkyl; Z = single bond or one of the groups of formulae (a)-(h); R7-R11 = H or 1-10C alkyl; X = 1-20C alkylene, 1-10C alkylene oxide or -O-(CH2)nm; m = 1-50; and n = 1-10. -C(O)-O-X- (a) -C(O)-NR11-X- (c) -O-C(O)-X- (d) -C(O)-NR11- (f) -O-X- (g) -O-CH2-X- (h) Also claimed are: (i) polymers comprising 0.1-100 wt.% (I), with the exception of compounds in which R3 is H and Z is a single bond; and (ii) the use of the polymers in coating materials, impregnating materials or adhesives.

公开(公告)号：DE19539460A1

公开(公告)日：1997-04-30

申请号：DE19539460

申请日：1995-10-24

Applicant: BASF AG

Inventor： PAKUSCH JOACHIM DR ,  SCHULER BERNHARD DR ,  MAECHTLE WALTER DR ,  BAUMSTARK ROLAND DR

IPC: C08F2/22 ,  C08J3/12 ,  C08L33/06 ,  C08L41/00 ,  C08F20/38 ,  C04B24/26 ,  C08F6/14 ,  C08F6/22 ,  C08F20/58

Abstract: The process for drying aqueous dispersions of a polymer (B), in which the dispersion contains, as auxiliary drying agent, at least one polymer (A) containing (in polymerised form) 80-100 wt.% monomer(s) (a) of formula CH2CR1C(O)XCR2R3-R4-SOH (I) or salts thereof and 0-20 wt.% other radically polymerisable monomer(s) (b), in which R1-3 = H or 1-3 C alkyl; R4 = 1-5 C alkylene; and X = O or NH. Also claimed are: (i) the polymer powder containing (A) and (B); (ii) the mineral binder containing such polymer powder(s); (iii) the synthetic resin-plaster drying preparation containing such powder(s); (iv) the aqueous polymer dispersions of (B) with an emulsifier content of not more than 2 wt.%, containing (A) with a Mw of 5000-35,000 as added dispersant; (v) the process for the radical aqueous emulsion polymerisation of ethylenic monomers, in which (A) with a Mw of 5000-35000 is added before, during or after polymerisation; and (vi) the polymer powder obtained by drying as above.

公开(公告)号：DE4325455A1

公开(公告)日：1995-02-02

申请号：DE4325455

申请日：1993-07-29

Applicant: BASF AG

Inventor： BAUER GERHARD DR ,  BAUMSTARK ROLAND DR ,  BOTT KASPAR DR ,  VOSS HARTWIG DR

IPC: C07C239/20 ,  C08K5/32 ,  C25B3/00 ,  B01D61/42 ,  C09D157/10 ,  C09D201/06 ,  C09J157/10 ,  C09J201/06 ,  C09K3/10

公开(公告)号：ES2166025T3

公开(公告)日：2002-04-01

申请号：ES97108625

申请日：1997-05-28

Applicant: BASF AG

Inventor： BAUMSTARK ROLAND DR ,  DERSCH ROLF DR

IPC: C08F2/30 ,  C08F2/22 ,  C08F2/24 ,  C08F2/32 ,  C08F4/34 ,  C08F220/18 ,  C09D125/08 ,  C09D125/14 ,  C09D133/00 ,  C09D133/06 ,  C09D133/08 ,  C09D133/18 ,  C09D135/02 ,  C09D135/04 ,  C09D157/00

Abstract: Binders comprising at least one aqueous polymer dispersion with a minimum film-forming temperature less than 10 degrees C are prepared by radical aqueous emulsion polymerisation of monomer mixtures that contain the following components :(A) 45-70 parts by weight at least one monomer whose homopolymer has a glass transition temperature (Tg) less than 20 degrees C ; (B) 30-55 parts by weight at least one monomer whose homopolymer has a Tg greater than 50 degrees C ; (C) 0-1 part by weight at least one monomer with acidic groups ; and (D) 0-2 parts by weight at least one extra monomer chosen from amides, alpha , beta -unsaturated 3-6C carboxylic acids (or their hydroxy-(2-6C alkyl)-esters) and/or N-vinyl lactams. Low emission, solvent-free coating materials containing at least one of these binders are also claimed.

公开(公告)号：AT207518T

公开(公告)日：2001-11-15

申请号：AT97108625

申请日：1997-05-28

Applicant: BASF AG

Inventor： BAUMSTARK ROLAND DR ,  DERSCH ROLF DR

IPC: C08F2/30 ,  C08F2/22 ,  C08F2/24 ,  C08F2/32 ,  C08F4/34 ,  C08F220/18 ,  C09D125/08 ,  C09D125/14 ,  C09D133/00 ,  C09D133/06 ,  C09D133/08 ,  C09D133/18 ,  C09D135/02 ,  C09D135/04 ,  C09D157/00

Abstract: Binders comprising at least one aqueous polymer dispersion with a minimum film-forming temperature less than 10 degrees C are prepared by radical aqueous emulsion polymerisation of monomer mixtures that contain the following components :(A) 45-70 parts by weight at least one monomer whose homopolymer has a glass transition temperature (Tg) less than 20 degrees C ; (B) 30-55 parts by weight at least one monomer whose homopolymer has a Tg greater than 50 degrees C ; (C) 0-1 part by weight at least one monomer with acidic groups ; and (D) 0-2 parts by weight at least one extra monomer chosen from amides, alpha , beta -unsaturated 3-6C carboxylic acids (or their hydroxy-(2-6C alkyl)-esters) and/or N-vinyl lactams. Low emission, solvent-free coating materials containing at least one of these binders are also claimed.