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公开(公告)号:MY140598A
公开(公告)日:2009-12-31
申请号:MYPI20044406
申请日:2004-10-26
Applicant: BASF AG
Inventor: BOTTKE NILS DR , BENFER REGINA DR , BOSCH MARCO DR , NARBESHUBER THOMAS DR , STEINBRENNER ULRICH DR , STEPHAN JUERGEN DR
Abstract: IN A PROCESS FOR PREPARING ALKYLARYL COMPOUNDS BY REACTING A C10-14-MONOOLEFIN MIXTURE WITH AN AROMATIC HYDROCARBON IN THE PRESENCE OF AN ALKYLATION CATALYST TO FORM ALKYL AROMATIC COMPOUNDS AND IF APPROPRIATE SUBSEQUENTLY SULFONATING AND NEUTRALIZING THE RESULTING ALKYLARYL COMPOUNDS, IN THE C10-14-MONOOLEFINS, ON AVERAGE, MORE THAN 0AND UP TO 100OF METHYL BRANCHES ARE PRESENT IN THE LONGEST CARBON CHAIN AND FEWER THAN 50OF THE METHYL BRANCHES ARE IN THE 2-, 3- AND 4-POSITION, CALCULATED STARTING FROM THE CHAIN ENDS OF THE LONGEST CARBON CHAIN.
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公开(公告)号:MY136695A
公开(公告)日:2008-11-28
申请号:MYPI20045180
申请日:2004-12-16
Applicant: BASF AG
Inventor: STEINBRENNER ULRICH DR , HEIDEMANN THOMAS DR , ROEPER MICHAEL PROF DR , STEPHAN JUERGEN DR , NARBESHUBER THOMAS DR , TROPSCH JURGEN DR , BOTTKE NILS DR , BENFER REGINA DR
IPC: C07C2/66 , C07C303/06 , C07C309/31 , C11D1/22 , C11D11/04
Abstract: The preparation of alkylaryl compounds takes place by a) reaction of a C 4 /C 5 -olefin mixture over a metathesis catalyst to prepare a C 4-8 -olefin mixture comprising 2-pentene, and optional removal of the C 4-8 -olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C 4-8 -olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C 8-16 -olefins, removal of these C 8-16 -olefins and optional removal of a partial stream thereof, d) reaction of the c 8-16 -olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c 8-16 -olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).
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公开(公告)号:MY136625A
公开(公告)日:2008-10-31
申请号:MYPI20045400
申请日:2004-12-29
Applicant: BASF AG
Inventor: JOHANN THORSTEN DR , SCHINDLER GOETZ-PETER DR , BRODHAGEN ANDREAS DR , CRONE SVEN DR , BENFER REGINA DR , SIGL MARCUS DR , DUDA MARK DR
IPC: C07C5/333 , C07C5/48 , C07C11/167
Abstract: The disclosure involves a process for the preparation of butadiene and 1-butene. The process includes at least a first catalytic dehydrogenation of n-butane to obtain a gas stream which is followed by at least a second oxidative dehydrogenation to form a second gas stream. The second gas stream is then subjected to distillation and isomeration steps to obtain butadiene and 1-butene.
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公开(公告)号:MY140092A
公开(公告)日:2009-11-30
申请号:MYPI20045270
申请日:2004-12-21
Applicant: BASF AG
Inventor: JOHANN THORSTEN DR , SCHINDLER GOETZ-PETER DR , BRODHAGEN ANDREAS DR , CRONE SVEN DR , BENFER REGINA DR , HILL THOMAS DR , DUDA MARK DR
IPC: C07C5/327 , C07C5/333 , C07C5/48 , C07C11/167
Abstract: The disclosure relates to a process for preparing butadiene. The process involves nonoxidatively catalytically dehydrogenating butane to obtain a product gas stream containing butane, 1-butene, 2-butene, butadiene, hydrogen and secondary constituents. The 1-butene and 2-butene of the product gas stream is then oxidatively dehydrogenated to give a second gas stream containing butane,2-butene, butadiene, hydrogen, steam and secondary constituents. Next, the butane,2-butene and butadiene are separated from the second gas stream and the butane and 2-butene are then separated from the butadiene product. The butane and 2-butene are then recycled into the nonoxidative catalytic dehydrogenating zone.
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公开(公告)号:MY138099A
公开(公告)日:2009-04-30
申请号:MYPI20021542
申请日:2002-04-26
Applicant: BASF AG
Inventor: BENFER REGINA DR , NILLES MICHAEL DR , WEINLE WERNER , ZEHNER PETER DR
IPC: C07D319/06 , B01D3/00 , B01D3/20 , B01J8/04 , B01J8/18 , B01J8/22 , B01J8/34 , B01J10/00 , B01J19/24 , B01J47/00 , C07C68/04 , C07C69/96
Abstract: A REACTOR (1) HAVING A VERTICAL LONGITUDINAL AXIS AND AN INLET (2) FOR A LIQUID OR LIQUID/SOLID FEED STREAM IN THE UPPER REGION OF THE REACTOR AND AN INLET (3) FOR A GASEOUS STREAM IN THE LOWER REGION OF THE REACTOR (1), CHARACTERIZED BY - AT LEAST TWO CHAMBERS (4) ARRANGED ABOVE ONE ANOTHER IN THE LONGITUDINAL DIRECTION,WHERE - THE CHAMBERS (4) ARE SEPARATED FROM ONE ANOTHER BY LIQUID-TIGHT BOTTOM PLATES, - EACH CHAMBER IS CONNECTED VIA A LIQUID OVERFLOW (6) TO THE CHAMBER (4) LOCATEDIMMEDIATELY UNDERNEATH AND A LIQUID PRODUCT STREAM IS TAKEN OFF VIA THE LIQUID OVERFLOW (6) OF THE BOTTOMMOST CHAMBER (4), - THE GAS SPACE (7) ABOVE THE LIQUID SURFACE IN EACH CHAMBER (4) IS CONNECTED TO THECHAMBER (4) LOCATED IMMEDIATELY ABOVE IT BY ONE OR MORE GUIDE TUBES (8) WHICH OPENS (EACH OPEN) INTO A GAS DISTRIBUTOR (9) PROVIDED WITH OPENINGS FOR EXIT OF GASBELOW THE LIQUID SURFACE, - AND EACH CHAMBER IS PROVIDED WITH AT LEAST ONE GUIDE PLATE (12) WHICH IS ARRANGEDVERTICALLY AROUND EACH SIPHON LIKE GAS DISTRIBUTOR (9) AND WHOSE UPPER END IS BELOW THE LIQUID SURFACE AND WHOSE LOWER END IS ABOVE THE LIQUID - TIGHT BOTTOMPLATE (5) OF THE CHAMBER (4) AND WHICH DIVIDES EACH CHAMBER (4) INTO ONE OR MORESPACES INTO WHICH GAS FLOWS (13) AND ONE OR MORE SPACES INTO WHICH GAS DOESNOT FLOW (14), IS USED FOR GAS/LIQUID OR GAS/LIQUID/SOLID REACTIONS. (FIGURE 1)
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