PROCESS FOR THE PREPARATION OF ALKYLARYL COMPOUNDS

    公开(公告)号:MY136695A

    公开(公告)日:2008-11-28

    申请号:MYPI20045180

    申请日:2004-12-16

    Applicant: BASF AG

    Abstract: The preparation of alkylaryl compounds takes place by a) reaction of a C 4 /C 5 -olefin mixture over a metathesis catalyst to prepare a C 4-8 -olefin mixture comprising 2-pentene, and optional removal of the C 4-8 -olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C 4-8 -olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C 8-16 -olefins, removal of these C 8-16 -olefins and optional removal of a partial stream thereof, d) reaction of the c 8-16 -olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c 8-16 -olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).

    METHOD FOR THE SIMULTANEOUS PRODUCTION OF TETRAHYDROFURANS AND PYRROLIDONES

    公开(公告)号:MY139906A

    公开(公告)日:2009-11-30

    申请号:MYPI20030658

    申请日:2003-02-25

    Applicant: BASF AG

    Abstract: A PROCESS FOR COPRODUCING ALKYL-SUBSTITUTED OR UNSUBSTITUTED THF AND PYRROLIDONES BY CATALYTICALLY HYDROGENATION C4- DICARBOXYLIC ACIDS AND/OR DERIVATIVES THEREOF IN THE GAS PHASE IN THE PRESENCE OF COPPER CATALYSTS AND THE REACTING GBL WITH AMMONIA OR PRIMARY AMINES TO GIVE PYRROLIDONES COMPRISES A) HYDROGENATING C4-DICARBOXYLIC ACIDS AND/OR THE DERIVATIVES THEREOF IN THE GAS PHASE AT 200 TO 300°C, 10 TO 10000 KPA (0.1 TO 100 BAR), CATALYST HOURLY SPACE VELOCITIES OF FROM 0.01 TO 1 KG OF REACTANT/L OF CATALYST* HOUR AND REACTANT/HYDROGEN MATERIAL/HYDROGEN MOLAR RATIOS OF 20 TO 800 IN THE PRESENCE OF CATALYSTS COMPRISING COPPER, ALUMINIUM AND/OR ZINC TO GIVE MIXTURES OF THF AND GBL, B) SEPARATING THE HYDROGENATION EFFLUENT OBTAINED BY DISTILLATION INTO A THF/WATER MIXTURE AS TOP PRODUCT AND A GBL-CONTAINING BOTTOM PRODUCT, C) SEPARATING THE THF/WATER MIXTURE FROM STEP B) IN A DISTILLATION FACILITY CONSISTING OF THREE COLUMNS (1,2,3) BY WITHDRAWING WATER FROM THE BOTTOM OF THE FIRST COLUMN (1), RECYCLING WATER-CONTAINING THF FROM THE SECOND TO THE FIRST COLUMN, PASSING A SIDE STREAM FROM THE FIRST COLUMN (1) INTO THE SECOND COLUMN (2), RECYCLING THE BOTTOM PRODUCT OF THE THIRD COLUMN (3) INTO THE FIRST COLUMN (1) AND WITHDRAWING A DISTILLATE AT THE TOP OF THE FIRST COLUMN (1), WHEREIN A SIDE STREAM OF THE SECOND COLUMN (2) IS PASSED INTO THE THIRD COLUMN (3) AND THE PURE THF IS OBTAINED AS THE TOP PRODUCT OF THE THIRD COLUMN (3), D) RECOVERING GBL FROM THE GBL-CONTAINING BOTTOM PRODUCT FROM STEP B) BY DISTILLATION AND E) REACTING THE GBL OBTAINED WITH AMMONIA OR AMINES TO GIVE THE CORRESPONDING PYRROLIDONES.

    METHODS FOR PRODUCING ALKYLARYL SULFONATES BY USING MODIFIED DIMERIZED OLEFINS

    公开(公告)号:MY135566A

    公开(公告)日:2008-05-30

    申请号:MYPI20034950

    申请日:2003-12-22

    Applicant: BASF AG

    Abstract: THE INVENTION RELATES TO PROCESSES FOR THE PREPARATION OF ALKYLARYLSULFONATES BY A) REACTION OF A C4-OLEFIN MIXTURE OVER A METATHESIS CATALYST TO PREPARE AN OLEFIN MIXTURE COMPRISING 2-PENTENE AND/OR 3-HEXENE AND OPTIONAL REMOVAL OF 2-PENTENE AND/OR 3-HEXENE,B) DIMERIZATION OF THE 2-PENTENE AND/OR 3-HEXENE OBTAINED IN STAGE A) IN THE PRESENCE OF A DIMERIZATION CATALYST TO GIVE A MIXTURE COMPRISING C10-12-OLEFINS AND OPTIONAL REMOVAL OF THE C10-12-OLEFINS, C) REACTION OF THE C10-12 MIXTURES OBTAINED IN STAGE B) WITH AN AROMATIC HYDROCARBON IN THE PRESENCE OF AN ALKYLATION CATALYST TO FORM ALKYL AROMATIC COMPOUNDS, WHERE, PRIOR TO THE REACTION, ADDITIONAL LINEAR OLEFINS MAY BE ADDED,D) SULFONATION OF THE ALKYL AROMATIC COMPOUNDS OBTAINED IN STAGE C) AND NEUTRALIZATION TO GIVE ALKYLARYLSULFONATES, WHERE, PRIOR TO THE SULFONATION, LINEAR ALKYLBENZENES MAY ADDITIONALLY BE ADDED,E) OPTIONAL MIXING OF THE ALKYLARYLSULFONATES OBTAINED IN STAGE D) WITH LINEAR ALKYLARYLSULFONATES.

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