PROCESS FOR THE PREPARATION OF ALKYLARYL COMPOUNDS

    公开(公告)号:MY136695A

    公开(公告)日:2008-11-28

    申请号:MYPI20045180

    申请日:2004-12-16

    Applicant: BASF AG

    Abstract: The preparation of alkylaryl compounds takes place by a) reaction of a C 4 /C 5 -olefin mixture over a metathesis catalyst to prepare a C 4-8 -olefin mixture comprising 2-pentene, and optional removal of the C 4-8 -olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C 4-8 -olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C 8-16 -olefins, removal of these C 8-16 -olefins and optional removal of a partial stream thereof, d) reaction of the c 8-16 -olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c 8-16 -olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).

    5.
    发明专利
    未知

    公开(公告)号:ES2144092T3

    公开(公告)日:2000-06-01

    申请号:ES95119001

    申请日:1995-12-02

    Applicant: BASF AG

    Abstract: Polymers (I), used in hair styling agents, are prepd. by radical-initiated copolymerisation of: (A) 5-50 wt.% (quat.) 1-vinyl imidazole; (B) 20-80 wt.% N-vinyl caprolactam; (C) 10-60 wt.% N-vinyl pyrrolidone; and (D) 0-30 wt.% additional radical copolymerisable monomer which forms a homopolymer with a Tg > 20 degrees C, with the proviso that the polymer is quaternised if (A) is 1-vinyl imidazole. Cosmetic hair and skin formulations contg. (I) as active ingredients are also claimed. Pref. (A) is 3-methyl-1-vinyl imidazolinium chloride or -methyl sulphate, or 3-ethyl-1-vinyl imidazolinium methyl sulphate. (D) is tert.-butyl acrylate. (I) is prepd. by copolymerisation of a mixt. comprising 10-30 wt.% 1-vinyl imidazole quaternised with di(m)ethyl sulphate as component (A), 40-60 wt.% (B), and 30-50 wt.% (C).

    6.
    发明专利
    未知

    公开(公告)号:ES2122726T3

    公开(公告)日:1998-12-16

    申请号:ES96100873

    申请日:1996-01-23

    Applicant: BASF AG

    Abstract: Prodn. of high mol. polymers involves: (a) polymerising water-soluble, mono-ethylenically unsatd. monomers and opt. crosslinkers contg. non-conjugated ethylenically unsatd. double bonds. in the molecule and opt. water-insol. monoethylenically unsatd. monomers in aq. soln. in the presence of polymerisation initiators in a tubular reactor; and (b) forcing the gelatinous reaction mixt. from the reactor with an inert gas. The reactor has: (i) a conical taper at one end, so the ratio of the dia. (D1) of the reactor to the dia. (D2) at the end of the cone is (2-25); and (ii) the angle between D1 at the beginning of the cone and the inner wall of the cone of more than 45 and less than 90 degrees .

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