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公开(公告)号:ES2255745T3
公开(公告)日:2006-07-01
申请号:ES99114453
申请日:1999-07-23
Applicant: BASF AG
Inventor: FRANK GABRIELE , BIASTOCH RALF DR
Abstract: Microcápsulas de resina de melamina-formaldehído útiles para sistemas de grabación sensibles a la presión. Las microcápsulas se preparan añadiendo urea a una dispersión de melamina-formaldehído antes de endurecer. Las microcápsulas (I) se producen por condensación de resinas de melamina-formaldehído y/o sus métilesteres en agua, donde se dispersa el material formador d cápsula insoluble en agua, en presencia de un coloide protector aniónico con un pH de entre 3 y 6.5 y entre 20 y 50ºC seguido dl endurecimiento de las pared de la cápsula entre 50 y 100ºC. Antes del endurecimiento se añade entre 10 y 200 % en peso de urea (w-r-t resina de melanina-formaldehído) opcionalmente enlazada con puentes de etileno o puentes de propileno. Se incluye una reivindicación independiente para un sistema de grabación sensible a la presión que contiene las microcápsulas.
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公开(公告)号:ES2093297T3
公开(公告)日:1996-12-16
申请号:ES93103716
申请日:1993-03-09
Applicant: BASF AG
Inventor: SCHULER BERNHARD DR , DYLLICK-BRENZINGER RAINER DR , BIASTOCH RALF DR
IPC: C07C51/00 , C07C59/08 , C08F2/10 , C08F220/18 , C08F2/16 , C08F20/38 , C08F26/10 , C08F220/10 , C08F220/38 , C08F220/58 , C08F226/10 , C08F228/02 , C09K23/00
Abstract: The invention relates to copolymers containing a) from 20 to 90% of 2-acrylamido-2-methylpropanesulphonic acid, sulphoethyl or sulphopropyl (meth)acrylate or vinylsulphonic acid, b) from 0 to 50% of a vinylically unsaturated acid, c) from 0 to 70% of methyl or ethyl acrylate or methacrylate, C2- to C4-hydroxyalkyl acrylate or N-vinylpyrrolidone, and d) from 0.1 to 10% of styrene or C4- to C18-alkyl acrylate or C4- to C18-alkyl methacrylate. The copolymers according to the invention are particularly suitable as protective colloids in microencapsulation.
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公开(公告)号:DE59304236D1
公开(公告)日:1996-11-28
申请号:DE59304236
申请日:1993-03-09
Applicant: BASF AG
Inventor: SCHULER BERNHARD DR , DYLLICK-BRENZINGER RAINER DR , BIASTOCH RALF DR
IPC: C08F220/18 , C07C51/00 , C07C59/08 , C08F2/10 , C08F2/16 , C08F20/38 , C08F26/10 , C08F220/10 , C08F220/38 , C08F220/58 , C08F226/10 , C08F228/02 , C09K23/00
Abstract: The invention relates to copolymers containing a) from 20 to 90% of 2-acrylamido-2-methylpropanesulphonic acid, sulphoethyl or sulphopropyl (meth)acrylate or vinylsulphonic acid, b) from 0 to 50% of a vinylically unsaturated acid, c) from 0 to 70% of methyl or ethyl acrylate or methacrylate, C2- to C4-hydroxyalkyl acrylate or N-vinylpyrrolidone, and d) from 0.1 to 10% of styrene or C4- to C18-alkyl acrylate or C4- to C18-alkyl methacrylate. The copolymers according to the invention are particularly suitable as protective colloids in microencapsulation.
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公开(公告)号:DE19645024A1
公开(公告)日:1998-05-07
申请号:DE19645024
申请日:1996-10-31
Applicant: BASF AG
Inventor: BOECKH DIETER DR , POTTHOFF-KARL BIRGIT DR , BERTLEFF WERNER DR , NEUMANN PETER DR , JAHNS EKKEHARD DR , BIASTOCH RALF DR , WEHLAGE THOMAS DR
Abstract: Microcapsules containing a bleaching assistant obtained by polymerisation of a monomer mixture comprising (total monomer mixture = 100 wt. %) (a) 5-100 wt. % of at least one ethylenically unsaturated carboxylic acid anhydride, (b) 0-95 wt. % of at least one monoethylenically unsaturated monomer different to monomer group (a), (c) 0-80 wt. % crosslinking monomers having at least two non-conjugated monoethylenically unsaturated groups in the molecule and (d) 0-20 wt. % water soluble monoethylenically unsaturated monomers, in the oil phase of a stable oil-in-water emulsion in the presence of radical forming polymerisation initiators, and optionally continuously or periodically increasing the temperature of the polymerisation reaction mixture during the polymerisation are new. The oil phase of the emulsion contains or consists of the bleaching assistant. Also claimed are washing and cleaning agents containing the encapsulated bleaching agent assistants for the cleaning of textile s.
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公开(公告)号:DE19501053A1
公开(公告)日:1996-07-18
申请号:DE19501053
申请日:1995-01-16
Applicant: BASF AG
Inventor: TRAUTH HUBERT , KROCKENBERGER JUERGEN , JAHNS EKKEHARD DR , BIASTOCH RALF DR
IPC: B01J13/14 , A01N25/28 , A61K8/11 , A61K8/49 , A61K47/08 , A61Q17/00 , A61Q17/04 , C07B63/04 , C07D311/72 , C07F9/09 , C07F9/48 , C08K5/00 , C08K5/15 , C08K5/1545 , C08K5/17 , C08K5/524 , C08K5/5393 , C08K9/10 , C08L101/00 , C09D7/12 , C09K15/06 , C09K15/08 , C09K15/32 , G03C1/34 , A61K7/00
Abstract: The invention concerns a stabiliser mixture containing: (a) one or more chromane derivatives of general formula (I), in which R is a group of formula (i) as shown in which Z represents C7-C30 alkyl, -CH2CH2-S-(C1-C30-alkyl) or a group of formula (ii) as shown; and (b) an inert organic solvent for the formula (I) chromane derivatives chosen from the group containing aliphatic, cycloaliphatic or aromatic hydrocarbons or halogenated hydrocarbons, silicone oils and plant and animal fatty oils. The weight ratio of components (a) and (b) is 99:1-1:99.
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公开(公告)号:DE19718661A1
公开(公告)日:1998-11-05
申请号:DE19718661
申请日:1997-05-02
Applicant: BASF AG
Inventor: OPPENLAENDER KNUT DR , OETTER GUENTER DR , BECKMANN EBERHARD DR , LORENCAK PRIMOZ DR , DYLLICK-BRENZINGER RAINER DR , BIASTOCH RALF DR
IPC: D21C5/02
Abstract: In deinking printed waste paper by beating in aqueous medium in the presence of deinking agent and purification by washing of flotation, the deinking agent (I) comprises hydrogenated 24-50C dimeric acids with an iodine number \} 20 and/or their alkali(ne earth) metal and/or ammonium salts and/or alkoxylation products. Also claimed is the use of these acids and derivatives as (I) for deinking printed waste paper. Preferably (I) consists of 30-40C acids and/or alkoxylation products, especially a 36C acid with an iodine number \} 7.5. The waste paper is beaten in the presence of aqueous sodium hydroxide solution, water glass, hydrogen peroxide (H2O2) and optionally a ligand. Alternatively, beating and flotation are carried out at pH 6.5-8.8 in the absence of these additives and surfactants.
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公开(公告)号:DE4209632A1
公开(公告)日:1993-09-30
申请号:DE4209632
申请日:1992-03-25
Applicant: BASF AG
Inventor: SCHULER BERNHARD DR , DYLLICK-BRENZINGER RAINER DR , BIASTOCH RALF DR
IPC: C08F220/18 , C07C51/00 , C07C59/08 , C08F2/10 , C08F2/16 , C08F20/38 , C08F26/10 , C08F220/10 , C08F220/38 , C08F220/58 , C08F226/10 , C08F228/02 , C09K23/00 , B01J13/14
Abstract: The invention relates to copolymers containing a) from 20 to 90% of 2-acrylamido-2-methylpropanesulphonic acid, sulphoethyl or sulphopropyl (meth)acrylate or vinylsulphonic acid, b) from 0 to 50% of a vinylically unsaturated acid, c) from 0 to 70% of methyl or ethyl acrylate or methacrylate, C2- to C4-hydroxyalkyl acrylate or N-vinylpyrrolidone, and d) from 0.1 to 10% of styrene or C4- to C18-alkyl acrylate or C4- to C18-alkyl methacrylate. The copolymers according to the invention are particularly suitable as protective colloids in microencapsulation.
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公开(公告)号:DE4137619A1
公开(公告)日:1993-05-19
申请号:DE4137619
申请日:1991-11-15
Applicant: BASF AG
Inventor: JAHNS EKKEHARD DR , DYLLICK-BRENZINGER RAINER DR , RAULFS FRIEDRICH-WILHELM DR , BIASTOCH RALF DR
IPC: B01J13/14 , B01J13/18 , B41M5/165 , C08K9/10 , C09D7/00 , C09D11/037 , D06P1/00 , D06P5/00 , G03G9/08 , G03G9/087 , G03G9/093
Abstract: Microcapsules with a core of solid material, obtainable by suspension polymerisation of A) from 30 to 100 % by weight of one or more vinyl monomers (monomers I), B) from 0 to 70 % by weight of one or more bifunctional or polyfunctional monomers (monomers II) and C) from 0 to 40 % by weight of other monomers (monomers III), where the solid particles, the monomers and one or more oil-soluble free-radical initiators are dispersed in water, and the polymerisation is initiated and controlled in the conventional manner through the thermal decomposition of the free-radical initiator, and the preparation and use of these microcapsules.
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