公开(公告)号：JPH10130218A

公开(公告)日：1998-05-19

申请号：JP28173797

申请日：1997-10-15

Applicant: BASF AG

Inventor： VOIT GUIDO DR ,  DERNBACH MATTHIAS DR ,  BECK KARL ,  HOLDERBAUM MARTIN DR ,  WEYER HANS-JUERGEN DR

IPC: C07C249/02 ,  C07C251/24

Abstract: PROBLEM TO BE SOLVED: To produce a stable benzophenone imine free from a reverse reaction to form benzophenone during storage by distilling ammonia and also removing water using distillation or using non-distillation means from an effluent of a benzophenone imine reaction. SOLUTION: This method is composed of the processes distilling ammonia and removing water using distillation or using non-distillation means from an effluent of a benzophenone imine reactor generated by catalytic reaction of a benzophenone of the formula [R and R are independently a halogen, hydroxy, a 6-10C aryl, a 1-12C alkyl, etc.; (m) and (n) are each independently an integer of 0-5] and ammonia. The distillation is preferably carried out at 20-200 deg.C under a pressure of 1-1,000 mbar.

公开(公告)号：JPH10147556A

公开(公告)日：1998-06-02

申请号：JP20448197

申请日：1997-07-30

Applicant: BASF AG

Inventor： ELLER KARSTEN DR ,  KUMMER RUDOLF DR ,  DERNBACH MATTHIAS DR

IPC: B01J29/06 ,  C07B61/00 ,  C07C209/02 ,  C07C209/60 ,  C07C211/03 ,  C07C211/16 ,  C07C211/21 ,  C07C211/33 ,  C07C211/43

Abstract: PROBLEM TO BE SOLVED: To obtain an amine in high yield by reacting an olefin with ammonia, or a primary or secondary amine at given temperature and pressure in the presence of zeolite of NES structure as the heterogeneous reaction catalyst. SOLUTION: The method for producing this amine reacts an olefin shown by formula I (R to R are each H, a 1-20C alkyl, 2-20C alkenyl, 4-20C cycloalkyl-alkyl, or the like), e.g. isobutene, with ammonia, or a primary or secondary amine shown by formula II (R and R are each H, a 1-20C alkyl or the like) at 200 to 350 deg.C and 100 to 300 bar in the presence of zeolite of NES structure as the heterogeneous reaction catalyst, to produce the objective compound shown by formula III (e.g. tert-butylamine). This method gives the objective compound in high yield, high yield per treatment space-time, while controlling deactivation of the catalyst.

公开(公告)号：JPH10324668A

公开(公告)日：1998-12-08

申请号：JP4367198

申请日：1998-02-25

Applicant: BASF AG

Inventor： ELLER KARSTEN DR ,  KUMMER RUDOLF DR ,  DERNBACH MATTHIAS DR ,  LUETZEL HANS-JUERGEN

IPC: B01J29/06 ,  C07B61/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C211/17

Abstract: PROBLEM TO BE SOLVED: To produce amine in high yield, i.e., in high selectivity and high spatiotemporal yield by reacting ammonia or primary or secondary amine with olefin at high temperature and high pressure by using a specific heterogeneous catalyst. SOLUTION: This objective amine of formula III is obtained by reacting a primary or secondary amine of formula I (R and R are each H, an alkyl, alkenyl, aryl, etc.), or ammonia with an olefin of formula II (R to R are each the same as R or R ) at 200 to 350 deg.C and 100 to 300 bar in the presence of a heterogeneous catalyst consisting of NU-85 zeolite. This NU-85 zeolite catalyst may be ion-exchanged or doped with alkali metal, alkali earth metal or rare earth metal. Also, the catalyst may be subjected to acid treatment by using such an acid as hydrochloric acid or sulfuric acid. Preferably, there is recycled the material which has not been converted yet when the amine of formula III is isolated.

公开(公告)号：DE19749568A1

公开(公告)日：1998-05-28

申请号：DE19749568

申请日：1997-11-10

Applicant: BASF AG

Inventor： LAQUA GERHARD DR ,  DERNBACH MATTHIAS DR

IPC: C07C273/02 ,  C07C273/18 ,  C07C275/28 ,  C07C275/58 ,  C07C275/14 ,  C07C273/00

Abstract: Process for cleaning (poly)isocyanurates at 80-350 deg C and elevated pressure, optionally in the presence of a catalyst comprises reacting the isocyanurates with primary and/or secondary amines and/or NH3 and/or substances which split. The NH3 under reaction conditions, as NH functional substances with water has a content of

公开(公告)号：MY140112A

公开(公告)日：2009-11-30

申请号：MYPI20041329

申请日：2004-04-12

Applicant: BASF AG

Inventor： WARTINI ALEXANDER DR ,  DERNBACH MATTHIAS DR ,  MAAS STEFFEN DR

IPC: C07C29/141

Abstract: PROCESS FOR THE CATALYTIC HYDROGENATION OF METHYLOLALKANALS OF THE FORMULA WHERE R¹ AND R² ARE EACH, INDEPENDENTLY OF ONE ANOTHER, A FURTHER METHYLOL GROUP OR AN ALKYL GROUP HAVING FROM 1 TO 22 CARBON ATOMS OR AN ARYL OR ARALKYL GROUP HAVING FROM 6 TO 33 CARBON ATOMS, IN THE LIQUID PHASE OVER A HYDROGENATION CATALYST, WHEREIN THE pH OF THE HYDROGENATION FEED IS SET TO FROM 6.3 TO 7.8 BY ADDITION OF AT LEAST ONE TERTIARY AMINE.

公开(公告)号：MY128780A

公开(公告)日：2007-02-28

申请号：MYPI20005705

申请日：2000-12-05

Applicant: BASF AG

Inventor： DERNBACH MATTHIAS DR ,  KRATZ DETLEF DR ,  STAMMER ACHIM DR ,  SCHULZ GERHARD DR

IPC: C07C45/82 ,  C07B61/00 ,  C07C29/14 ,  C07C31/22 ,  C07C45/75 ,  C07C45/83 ,  C07C45/86 ,  C07C47/058 ,  C07C47/19

Abstract: FORMALDEHYDE IS REMOVED BY DISTILLATION FROM REACTION SOLUTIONS CONTAINING A METHYLOLATED ALKANAL WHICH WAS OBTAINED FROM THE REACTION OF FORMALDEHYDE WITH AN ALKANAL WHICH HAS AT LEAST ONE ACIDIC HYDROGEN ATOM α TO THE CARBONYL FUNCTION OR FROM THE REACTION OF A 2-ALKYLACROLEIN OR ACROLEIN WITH WATER AND FORMALDEHYDE, BY A PROCESS IN WHICH THIS REACTION WAS CARRIED OUT IN THE PRESENCE OF CATALYTIC AMOUNTS OF AN ORGANIC AMINE. THE PROCESS PERMITS THE IMPROVED REMOVAL OF FORMALDEHYDE FROM THE REACTION MIXTURE AND FURTHERMORE FACILITATES THE HYDROGENATION OF THE ALKANAS THUS OBTAINED TO GIVE POLYOLS.

公开(公告)号：MY128614A

公开(公告)日：2007-02-28

申请号：MYPI20021234

申请日：2002-04-05

Applicant: BASF AG

Inventor： KOCH MICHAEL DR ,  MASS STEFFEN DR ,  POEPEL WOLFGANG JUERGEN DR ,  DERNBACH MATTHIAS DR

IPC: C07C27/04 ,  B01J21/06 ,  B01J23/00 ,  B01J23/70 ,  B01J23/72 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  C07B61/00 ,  C07C29/14 ,  C07C29/141 ,  C07C31/18 ,  C07C31/22

Abstract: IN A PROCESS FOR THE CATALYTIC HYDROGENATION OF A CARBONYL COMPOUND OR A MIXTURE OF TWO OR MORE CARBONYL COMPOUNDS IN THE PRESENCE OF CATALYST TABLETS WHICH COMPRISE AN INORGANIC, TiO₂-CONTAINING SUPPORT AND, AS ACTIVE COMPONENT, COPPER OR A MIXTURE OF COPPER WITH AT LEAST ONE METAL SELECTED FROM THE GROUP CONSISTING OF ZINC, ALUMINUM, CERIUM, NOBEL METALS AND METALS OF TRANSITION GROUP VIII AND WHOSE COPPER SURFACE AREA IS NOT MORE THAN 10 m²/g, THE DIAMETER d AND/OR THE HEIGHT h OF THE TABLETS IS LESS THAN 3 mm.

公开(公告)号：MY131957A

公开(公告)日：2007-09-28

申请号：MYPI20023650

申请日：2002-09-30

Applicant: BASF AG

Inventor： KOCH MICHAEL DR ,  WARTINI ALEXANDER DR ,  SIRCH TILMAN ,  DERNBACH MATTHIAS DR

IPC: C07C29/88 ,  C07C29/90 ,  C07C31/22

Abstract: A PROCESS FOR REMOVING TRIALKYLAMMONIUM FORMATE FROM METHYLOLALKANES WHICH HAVE BEEN OBTAINED BY CONDENSATION OF FORMALDEHYDE WITH A HIGHER ALDEHYDE COMPRISES DECOMPOSING TRIALKYLAMMONIUM FORMATE AT ELEVATED TEMPERATURE IN THE PRESENCE OF A HYDROGEN-CONTAINING GAS OVER CATALYSTS COMPRISING AT LEAAST ONE METAL OF GROUPS 8 TO 12 OF THE PERIODIC TABLE.THE PROCESS MAKES IT POSSIBLE TO SEPARATE OFF THE TRIALKYLAMMONIUM FORMATE FROM METHYLOLALKANES PREPARED BY THE ORGANIC CANNIZZARO PROCESS OR BY THE HYDROGENATION PROCESS.

公开(公告)号：DE19642541A1

公开(公告)日：1998-04-16

申请号：DE19642541

申请日：1996-10-15

Applicant: BASF AG

Inventor： VOIT GUIDO DR ,  DERNBACH MATTHIAS DR ,  BECK KARL ,  HOLDERBAUM MARTIN DR ,  WEYER HANS-JUERGEN DR

IPC: C07C249/02 ,  C07C251/24 ,  C07C249/14

Abstract: Water and ammonia are removed from crude benzophenone-imines obtained by the catalytic reaction of ammonia with benzophenones of formula (I), in which R , R = (a) halogen, hydroxyl, nitro or amino groups, (b) 1-12C linear, branched or cyclic alkyl or alkoxy, optionally substituted with 6-10C aryl, F, Cl or Br, (c) 6-10C aryl or aryloxy, optionally substituted with 1-12C alkyl or alkoxy, (d) heteroalkyl groups comprising alkyl groups as above with in-chain O, S and/or N atom(s), or (e) heteroaryl groups with 5-10 ring atoms containing 1-3 O, S and/or N atoms; m, n = 0-5. The process comprises removing the ammonia by distillation and removing the water by distillation or with a drying agent.

公开(公告)号：DE19630670A1

公开(公告)日：1998-02-05

申请号：DE19630670

申请日：1996-07-30

Applicant: BASF AG

Inventor： ELLER KARSTEN DR ,  KUMMER RUDOLF DR ,  DERNBACH MATTHIAS DR

IPC: B01J29/06 ,  C07B61/00 ,  C07C209/02 ,  C07C209/60 ,  C07C211/03 ,  C07C211/16 ,  C07C211/21 ,  C07C211/33 ,  C07C211/43 ,  C07C211/00 ,  C07C211/07 ,  C07C211/13 ,  B01J29/70

Abstract: In the preparation of amines of formula R5R6CHCR3R4NR1R2 (I) by reacting olefins of formula R5R6C=CR3R4 (II) with ammonia (NH3) or primary or secondary amines of formula HNR1R2 (III) at 200-350 deg. C and 100-300 bar in the presence of a heterogeneous catalyst, the catalyst comprises zeolite with NES structure (2-dimensional pore system with approximate dimensions of 4.7 x 6.0 Angstrom ); in which R1 - R6= hydrogen, 1-20 C alkyl, 2-20 C alkenyl, 2-20 C alkynyl, 3-20 C cycloalkyl, 4-20 C alkyl-cycloalkyl, 4-20 C cycloalkyl-alkyl, aryl, 7-20 C alkylaryl or 7-20 C aralkyl; or R3 + R2 = an (un)saturated 3-9 C alkylene di-chain; and R3 or R5 = 21-200 C alk(en)yl or R3 + R3 = a 2-12 C alkylene chain.