公开(公告)号：DE2624656A1

公开(公告)日：1977-12-15

申请号：DE2624656

申请日：1976-06-02

Applicant: BASF AG

Inventor： GOETSCH MANFRED DIPL CHEM DR ,  GRITTNER FRANZ ING GRAD ,  HAAF FRANZ DIPL CHEM DR ,  HERNER MARTIN DIPL CHEM DR ,  HATZMANN GUENTER DIPL CHEM DR ,  MUELLER GUENTER

IPC: C08L27/06 ,  C08L51/04 ,  C08J5/18

Abstract: A vinyl chloride emulsion polymer (I) esp. for film prepd. according to the Luvitherm process contains 0.5-5 wt. % graft copolymer (II) as processing aid. (II) comprises (a) 30-80 wt.% elastomeric polymer as the backbone with a Tg 0 degrees C and contains >=15 wt.% (w.r.t. the elastomeric backbone) conjugated diene and (b) 70-20 wt.% 1-4C alkyl methacrylate and/or monovinyl aromatic cpd. and opt. other comonomers. The PVC may be processed more rapidly into a film. The films have good gloss and smoothness and may be used as adhesive or magnetic recording tapes.

公开(公告)号：DE3035643A1

公开(公告)日：1982-05-06

申请号：DE3035643

申请日：1980-09-20

Applicant: BASF AG

Inventor： BRANDSTETTER FRANZ DIPL CHEM D ,  ECHTE ADOLF DIPL CHEM DR ,  HOFMANN HERMANN PANKRAZ DIPL C ,  NAARMANN HERBERT DIPL CHEM DR ,  HAAF FRANZ DIPL CHEM DR ,  BRUESSAU RUDOLF DIPL CHEM DR

IPC: C08F279/02 ,  C08L51/04 ,  C08L71/12 ,  C08L71/04 ,  C08L53/02

Abstract: A thermoplastic moulding compsn. comprises an impact resistant styrene polymer (I) contg. a matrix with a wt. ave. mol. wt. (GPC) of greater than 270000 and a mol.wt. distribution of 3 or less and a polyphenylene ether (II). The compsn. comprises 5-90 pref. 20-80 wt.% (I) and 95-10 pref. 80-20 wt.% (II). (I) are prepd. by polymerisation of monovinyl aromatic monomers in the presence of a rubber. The amt. of rubber in (I) is 2-20 pref. 5-15 wt.%. (II) is esp. poly(2,6-dimethyl-1,4-phenylene)ether (IIA). The mouldings have low shrinkage and high impact resistance.

公开(公告)号：DE2457725A1

公开(公告)日：1976-06-16

申请号：DE2457725

申请日：1974-12-06

Applicant: BASF AG

Inventor： GEHM ROBERT DIPL CHEM DR ,  FALKENSTEIN GEORG DIPL CHEM DR ,  STEIN DIETER DIPL CHEM DR ,  HAAF FRANZ DIPL CHEM DR ,  HEINZ GERHARD DIPL CHEM DR ,  SCHOEN ERNST DIPL CHEM DR

IPC: C08G18/40 ,  C08G18/62 ,  C08G18/63

Abstract: Prepn. of (cellular) polyurethanes is claimed from a mixt. of a) >=1 polyisocyanate, B) >=1 polyhydroxy cpd. of mol. wt. 500-7,000 chosen from polyether- and polyesterpolyols and opt. D) other conventional additives, the novelty being that a polymer (C) is included in the mixt.; C) is an alkoxylated polymer prepd. by reacting 0.1-120 mol. ethylene oxide per mol. of gp. capable of being alkoxylated in (C). Polymers contg. covalently bonded polyhydroxy cpds. are easily obtd. cf. prior art in which either (a) polyhydroxy cpd. and polyisocyanates were reacted or (b) in situ free radical graft polymers contg. polyether-polyols grafted over C-C bonds were used. The polyurethanes have better load capacity, tensile, strength, compression set, and tear strength. Foams with low temp. flexibility may be prepd. with proper choice of (C). As flexible or rigid foams, elastomers or coatings. The foams may be used for upholstery, shoe soles, crash pads, etc.

公开(公告)号：DE3102252A1

公开(公告)日：1982-09-02

申请号：DE3102252

申请日：1981-01-24

Applicant: BASF AG

Inventor： BRANDSTETTER FRANZ DIPL CHEM D ,  ECHTE ADOLF DIPL CHEM DR ,  HAAF FRANZ DIPL CHEM DR ,  HAMBRECHT JUERGEN DIPL CHEM DR ,  NAARMANN HERBERT DIPL CHEM DR

IPC: C08L51/00 ,  C08L71/12 ,  C08L71/04 ,  C08L25/06 ,  C08L51/06

Abstract: In mixtures of impact-modified polystyrene with polyphenylene ethers, the aging resistance is improved by the use of polyphenylene ethers having a metal content of less than 100 ppm.

公开(公告)号：DE3102394A1

公开(公告)日：1982-08-26

申请号：DE3102394

申请日：1981-01-24

Applicant: BASF AG

Inventor： BRANDSTETTER FRANZ DIPL CHEM D ,  ECHTE ADOLF DIPL CHEM DR ,  HAAF FRANZ DIPL CHEM DR ,  HAMBRECHT JUERGEN DIPL CHEM DR ,  PRIEBE EDMUND DIPL CHEM DR

IPC: C08L25/08 ,  C08L51/00 ,  C08L71/12 ,  C08L71/04 ,  C08L25/04 ,  C08L51/04

Abstract: The concomitant use of acrylonitrile together with styrene during the grafting of polyacrylate soft components of mixtures of impact-modified polystyrene with polyphenylene ethers improves the impact strength thereof.

公开(公告)号：DE3105947A1

公开(公告)日：1982-08-19

申请号：DE3105947

申请日：1981-02-18

Applicant: BASF AG

Inventor： BRANDSTETTER FRANZ DIPL CHEM D ,  HAAF FRANZ DIPL CHEM DR ,  MUENCH VOLKER DIPL CHEM DR ,  NAARMANN HERBERT DIPL CHEM DR

IPC: C08K5/00 ,  C08L51/04 ,  C08L71/12 ,  C08L71/04 ,  C08K5/49 ,  C08L25/10

公开(公告)号：DE2457726A1

公开(公告)日：1976-06-16

申请号：DE2457726

申请日：1974-12-06

Applicant: BASF AG

Inventor： FALKENSTEIN GEORG DIPL CHEM DR ,  STEIN DIETER DIPL CHEM DR ,  HAAF FRANZ DIPL CHEM DR ,  HEINZ GERHARD DIPL CHEM DR ,  SCHOEN ERNST DIPL CHEM DR

IPC: C08G18/40 ,  C08G18/62 ,  C08G18/63

Abstract: (Cellular)polyurethanes are prepd. from a mixt. of A) >=1 polyisocyanate, B) >=1 polyhydroxy cpd. of mol. wt. 500-7,000 chosen from polyether-and polyester-polyols and opt. D) other conventional additives, the novelty being that a polymer (C) is included in the mixt.; C) is the reaction prodt. of a polymer contg. >=1 gp. capable of (trans)esterification and a polyhydroxy cpd. chosen from polyester- or polyether-polyols of mol. wt. 200-7,000 with formation of at least a partial ester like bond. Polymers contg. covalently bonded polyhydroxy cpds., useful in polyurethane chemistry are easily obtd. cf. prior art where either a) polyhydroxy cpds. and polyisocyanates were reacted or b) in situ free radical graft polymers contg. polyetherpolyols grafted over C-C bonds were used. Physical props. e.g., load capacity and low temp. flexibility are also improved. As flexible or rigid, foams, elastomers or coatings. The foams may be used as shoe soles, or in the automobile industry.

公开(公告)号：DE3113953A1

公开(公告)日：1982-10-21

申请号：DE3113953

申请日：1981-04-07

Applicant: BASF AG

Inventor： BRANDSTETTER FRANZ DIPL CHEM D ,  ECHTE ADOLF DIPL CHEM DR ,  HAAF FRANZ DIPL CHEM DR ,  NAARMANN HERBERT DIPL CHEM DR

IPC: C08L51/04 ,  C08L53/02 ,  C08L71/12 ,  C08L71/04 ,  C08L25/10

公开(公告)号：DE3106746A1

公开(公告)日：1982-09-09

申请号：DE3106746

申请日：1981-02-24

Applicant: BASF AG

Inventor： BRANDSTETTER FRANZ DIPL CHEM D ,  HAAF FRANZ DIPL CHEM DR ,  NAARMANN HERBERT DIPL CHEM DR ,  SCHUSTER HANS H DIPL CHEM DR

IPC: C08L71/12 ,  C08L71/04 ,  C08L25/04 ,  C08L51/04

公开(公告)号：DE3102251A1

公开(公告)日：1982-09-02

申请号：DE3102251

申请日：1981-01-24

Applicant: BASF AG

Inventor： BRANDSTETTER FRANZ DIPL CHEM D ,  ECHTE ADOLF DIPL CHEM DR ,  HAAF FRANZ DIPL CHEM DR ,  HAMBRECHT JUERGEN DIPL CHEM DR ,  NAARMANN HERBERT DIPL CHEM DR

IPC: C08L51/00 ,  C08L33/00 ,  C08L33/02 ,  C08L51/02 ,  C08L51/04 ,  C08L51/06 ,  C08L71/00 ,  C08L71/12 ,  C08L71/04 ,  C08L25/06

Abstract: A thermoplastic molding material based on a styrene polymer which has been made impact-resistant, and on a polyphenylene ether, wherein the impact-resistant styrene polymer comprises a soft component which has a mean particle diameter of greater than 0.3 mu m and contains an acrylic ester polymer as the elastomeric component. The novel molding materials possess improved flow and give moldings having improved aging resistance.