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公开(公告)号:DE19730168A1
公开(公告)日:1999-01-28
申请号:DE19730168
申请日:1997-07-15
Applicant: BASF AG
Inventor: SALING PETER DR , KLAHR ERHARD DR , REICHELT HELMUT DR , GRUETTNER-MERTEN SABINE DR
IPC: C09B29/085 , C09B29/01 , C09B29/08 , C09B43/42 , C07C211/52 , C07C217/84 , C07C245/08 , C07C253/30 , C07C255/58 , D06P1/18
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公开(公告)号:DE4339270A1
公开(公告)日:1995-05-24
申请号:DE4339270
申请日:1993-11-18
Applicant: BASF AG
Inventor: GRUETTNER-MERTEN SABINE DR , GRUND CLEMENS DR , GULDNER ANDREAS DR , HAGEN HELMUT DR , REICHELT HELMUT DR , SENS RUEDIGER DR
IPC: B41M5/388 , C07D275/04 , C07D401/12 , C07D417/12 , C09B29/00 , C09B29/09 , C09B29/36 , C09B29/42 , C09B29/46 , D06P1/18 , D06P5/00 , D06P5/13 , D06P5/24 , D06P5/28 , B41M5/38 , C07D403/12
Abstract: 5-Nitro-1,2-benzoisothiazole-4- and -7-azo dyes of formula (I) are new: one of X1 and X2 = NO2 and the other = N=N-K; K = a gp. of formula (IIA-D); R1, R2 = H; 1-8C alkyl, opt. with 1-3 ether O atoms in the chain and opt. substd. by 1-4C alkanoyloxy; 5-7C cycloalkyl; or 3-6C (halo)alkenyl; R = H;1-8C alkyl opt. with 1-3 ether O atoms in the chain; or 1-8C alkoxy; R4 = 1-8C alkyl; 1-8C alkoxy; 1-8C alkylsulphonylamino; 1-8C alkanoylamino, opt. substd. by 1-4C alkoxy; or benzoylamino; R5 = H; 1-8C alkyl; (substd.) phenyl; or thienyl; R6 = amino or OH; R7 = 1-8C alkyl, opt. with 1-3C ether O atoms in the chain; benzyl; 5-7C cycloalkyl; 3-6C alkenyl; or (substd.) phenyl; R8 = H or 1-8C alkyl; R9 = CN, carbamoyl, COOH, 1-8C alkoxycarbonyl or acetyl; R10, R11, R12 = as R1, R2 or NR11R12 = a 5-6 membered satd. heterocycle opt. contg. other hetero-atoms; if X1 = N=N-K, X2 may also = H, CN, halogen, CNS, 1-4C alkylthio or 1-4C alkylsulphonyl.
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公开(公告)号:DE4132075A1
公开(公告)日:1993-04-01
申请号:DE4132075
申请日:1991-09-26
Applicant: BASF AG
Inventor: DEGEN HELMUT , LANGE ARNO DR , GRUETTNER-MERTEN SABINE DR , REICHELT HELMUT DR
Abstract: Blue dye mixtures, containing 30 to 95% by weight, relative to the total weight of the dyes, of one or more dyes based on 1,4-diaminoanthraquinone-2,3-dicarboximides and 5 to 70% by weight, relative to the total weight of the dyes, of one or more thiophene azo dyes containing a coupling component from the aniline series, and their use for the dyeing or printing of polyester fabrics.
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公开(公告)号:DE4232557A1
公开(公告)日:1994-03-31
申请号:DE4232557
申请日:1992-09-29
Applicant: BASF AG
Inventor: LANGE ARNO DR , BACH VOLKER DR , SENS RUEDIGER DR , ETZBACH KARL-HEINZ DR , REICHELT HELMUT DR , GRUETTNER-MERTEN SABINE DR
IPC: C09B57/00 , B41M5/385 , B41M5/39 , C07D471/04 , C09B23/04 , C09B53/00 , C09B55/00 , C09B67/00 , C09B67/22 , C09B67/38 , D06P1/16 , D06P3/42 , D06P3/48
Abstract: Use of pyridine dyes of the formula or , in which R is optionally substituted C1-C20-alkyl, optionally substituted phenyl or hydroxyl, R is a carbocyclic or heterocyclic radical, R is cyano, carbamoyl, carboxyl or C1-C4-alkoxycarbonyl, R is oxygen or the radical of a CH-acidic compound, R is hydrogen or C1-C4-alkyl, R is optionally substituted C1-C20-alkyl, optionally substituted phenyl, hydroxyl or optionally substituted amino, and X is nitrogen or alternatively may be CH, for dyeing or printing synthetic fibres, cellulose esters or mixtures (blends) thereof, dye mixtures containing pyridine dyes of the above formulae and blue disperse dyes, their use for dyeing or printing synthetic fibres, cellulose esters or mixtures (blends) thereof, and triazolopyridine dyes containing a thienyl radical.
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公开(公告)号:DE4215495A1
公开(公告)日:1993-11-18
申请号:DE4215495
申请日:1992-05-12
Applicant: BASF AG
Inventor: GRUETTNER-MERTEN SABINE DR , REICHELT HELMUT DR , LANGE ARNO DR , DEGEN HELMUT
IPC: C09B29/00 , C09B29/042 , C09B29/09 , C09B43/00 , C09B67/48 , D06P1/18 , C09B29/033 , D06P1/39
Abstract: Azo dyes of formula (I) in which L is hydrogen, C1-C8 alkyl or phenyl, L and L are possibly substituted C1-C8 alkyl or L and L together are a residue of formula (a) or (b) in which n is 0, 1 or 2, Y and Y are hydrogen, hydroxymethyl, 1,2-dihydroxyethyl or a residue of formula COO M , so Y and Y are hydrogen or hydroxymethyl and M is the equivalent of a cation, L is hydrogen, possibly substituted phenyl, halogen, C1-C8 alkoxy, possibly substituted phenoxy, C1-C8 alkylthio, C1-C8 alkylsulphonyl, possibly substituted phenylsulphonyl, C1-C8 alkoxycarbonyl, C3-C6 alkenyloxycarbonyl or phenoxycarbonyl, X is nitrogen or the residue C-L where L is cyano, C1-C8 alkoxycarbonyl, C3-C6 alkenyloxycarbonyl, phenoxycarbonyl, C1-C8 alkanoyl, benzoyl, carbamoyl, C1-C4 mono or dialkylcarbamoyl, phenylcarbamoyl, C1-C8 alkylsulphonyl or possibly substituted phenylsulphonyl, and K is the residue of a coupling component, novel crystal modifications of thienylazobenzol dies and the use of said dyes for dyeing or printing textiles.
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公开(公告)号:DE4132685A1
公开(公告)日:1993-04-08
申请号:DE4132685
申请日:1991-10-01
Applicant: BASF AG
Inventor: WIESENFELDT MATTHIAS DR , GRUETTNER-MERTEN SABINE DR , SENS RUEDIGER DR , ETZBACH KARL-HEINZ DR , KILBURG HEIKE DR
IPC: C08F20/34 , C08F220/34 , C08F246/00 , C09B69/10 , G02F1/35 , G02F1/361
Abstract: Polymers containing azo dyestuffs which, as characteristic monomer units, contain radicals of the formulae I, II, III and IV … … in which …… D denotes the radical of a heterocyclic diazo component, … R and R in each case denote hydrogen, C1-C6-alkyl or optionally substituted C1-C6-alkoxy, or R also denotes C1-C4-alkanoylamino, … R denotes hydrogen, C1-C6-alkyl, C5-C7-cycloalkyl or C3-C4- alkenyl, … R denotes hydrogen, deuterium, methyl, trideuterated methyl or chlorine, … R denotes hydrogen or deuterium, … Y and Y in each case denote optionally substituted C2-C10-alkylene, … W denotes oxygen, imino or C1-C4-alkylimino and … X denotes hydroxyl, optionally substituted C1-C6-alkoxy, phenoxy, amino or C1-C4-mono- or dialkylamino, … where the average molecular weight of the polymer is 1000 to 100,000, their use in non-linear optics and the use of monomeric azo dyestuffs for the preparation of the novel polymers.
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公开(公告)号:DE19831375A1
公开(公告)日:1999-07-08
申请号:DE19831375
申请日:1998-07-13
Applicant: BASF AG
Inventor: SALING PETER DR , KLAHR ERHARD DR , REICHELT HELMUT DR , GRUETTNER-MERTEN SABINE DR
IPC: C09B29/085 , C09B29/01 , C09B29/08 , C09B43/42 , C07C211/52 , C07C215/68 , C07C217/78 , C07C219/34 , D06P1/18
Abstract: Azo dyes of formula (I) are new. In (I), X = O or a radical NR ; R = H or 1-13C alkyl optionally with interruption by 1-4 O atoms in ether function and with or without hydroxyl or 1-4C alkanoyloxy substitution; R = 1-13C alkyl optionally with interruption by 1-4 O atoms in ether function and with or without hydroxy, 1-4C alkanoyloxy or halogen substituted-1-4C alkanoyloxy substitution, or is optionally substituted phenyl; Y = H, halogen or cyano; Z = nitro or additionally cyano when Y = halogen or cyano; R = 1-4C alkyl, methoxymethyl or optionally substituted phenyl; R = H, 1-4C alkoxy or 1-4C alkyl; and R and R = 2-13C alkyl optionally with interruption by 1-4 O atoms in ether function and with or without hydroxyl, 1-4C alkanoyloxy or cyano substitution, methyl with or without hydroxyl, 1-4C alkanoyloxy or cyano substitution, or 2-6C alkenyl. Also claimed are: (1) the use of dinitro amino aromatics of formula (II) as diazo component in the synthesis of azo dyes as above; and (2) dinitro aromatics of formula (IIa) or (IIb); In (II), X, R , Y and Z = as above. In (IIa), X and R = as above; Y = halogen or cyano; and Z = nitro or cyano. In (IIb), X = as above; and R = 3-11C alkyl optionally with interruption by 1-4 O atoms in ether function and with or without hydroxy, 1-4C alkanoyloxy or halogen substituted-1-4C alkanoyloxy substitution.
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公开(公告)号:DE59208569D1
公开(公告)日:1997-07-10
申请号:DE59208569
申请日:1992-09-21
Applicant: BASF AG
Inventor: WIESENFELDT MATTHIAS DR , GRUETTNER-MERTEN SABINE DR , SENS RUEDIGER DR , ETZBACH KARL-HEINZ DR , KILBURG HEIKE DR
IPC: C08F20/34 , C08F220/34 , C08F246/00 , C09B69/10 , G02F1/35 , G02F1/361
Abstract: Polymers containing azo dyestuffs which, as characteristic monomer units, contain radicals of the formulae I, II, III and IV … … in which …… D denotes the radical of a heterocyclic diazo component, … R and R in each case denote hydrogen, C1-C6-alkyl or optionally substituted C1-C6-alkoxy, or R also denotes C1-C4-alkanoylamino, … R denotes hydrogen, C1-C6-alkyl, C5-C7-cycloalkyl or C3-C4- alkenyl, … R denotes hydrogen, deuterium, methyl, trideuterated methyl or chlorine, … R denotes hydrogen or deuterium, … Y and Y in each case denote optionally substituted C2-C10-alkylene, … W denotes oxygen, imino or C1-C4-alkylimino and … X denotes hydroxyl, optionally substituted C1-C6-alkoxy, phenoxy, amino or C1-C4-mono- or dialkylamino, … where the average molecular weight of the polymer is 1000 to 100,000, their use in non-linear optics and the use of monomeric azo dyestuffs for the preparation of the novel polymers.
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公开(公告)号:DE59206937D1
公开(公告)日:1996-09-26
申请号:DE59206937
申请日:1992-05-29
Applicant: BASF AG
IPC: C09B29/042 , C09B29/00 , C09B29/08 , C09B29/09
Abstract: Thiazole azo dyestuffs of the formula … … in which …… R denotes hydrogen, optionally substituted C1-C6-alkyl, halogen, optionally substituted C1-C6-alkoxy, optionally substituted C1-C6-alkylthio, optionally substituted phenylthio, C1-C6-alkylsulphonyl, optionally substituted phenylsulphonyl or C1-C4-alkoxycarbonyl, … R denotes cyano, C1-C4-alkanoyl, benzoyl, C1-C6-alkylsulphonyl, optionally substituted phenylsulphonyl or a radical of the formula -CH = T, in which T represents the radical of a CH-acidic compound, … R denotes hydrogen, optionally substituted C1-C6-alkoxy, C1-C4-alkoxycarbonyl, carbamoyl or C1-C4-mono- or dialkyl carbamoyl, … R denotes C1-C6-alkyl, optionally substituted C1-C6-alkoxy, optionally substituted C1-C4-alkoxycarbonyloxy, optionally substituted phenoxycarbonyloxy, substituted aminocarbonyloxy, optionally substituted C1-C4-alkanoyloxy, optionally substituted C1-C4-alkanoylamino, or optionally substituted phenyl, … R denotes hydrogen, optionally substituted C1-C10-alkyl or optionally substituted C3-C5-alkenyl and … R and R denote hydrogen, halogen, cyano, optionally substituted C1-C10-alkyl, optionally substituted C1-C4-alkoxy, amino or C1-C4-mono- or dialkylamino, … and their use for the dyeing or printing of textile fibres.
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公开(公告)号:DE4207745A1
公开(公告)日:1993-09-16
申请号:DE4207745
申请日:1992-03-11
Applicant: BASF AG
Inventor: LAUTH GUENTER DR , HOELDERICH WOLFGANG DR , WAGENBLAST GERHARD DR , ALBERT BERNHARD DR , LAMM GUNTHER DR , REICHELT HELMUT DR , GRUND CLEMENS DR , GRUETTNER-MERTEN SABINE DR
IPC: C01B25/36 , C01B25/45 , C01B33/26 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/00 , C01B39/02 , C09B63/00 , C09D7/00
Abstract: Crystalline molecular sieves containing one or more chromophores of the mono or polyazo dye class having no acid groups, and their use as colorants.
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