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公开(公告)号：DE2625541A1
公开(公告)日：1977-12-22
申请号：DE2625541
申请日：1976-06-05
Applicant: BASF AG
Inventor： NISSEN AXEL DIPL CHEM DR , HEILEN GERD DIPL CHEM DR , SAPPER EKKEHARD DIPL CHEM DR , FLIEGE WERNER DIPL CHEM DR DR , WITTWER ARNOLD DIPL CHEM DR
IPC: B01J23/80 , B01J23/835 , B01J23/84 , C07B61/00 , C07C45/00 , C07C45/62 , C07C45/65 , C07C45/72 , C07C45/73 , C07C45/74 , C07C49/04 , C07C49/213 , C07C67/00
Abstract: Aldehydes or ketones of not less than 4 or 5 carbon atoms, respectively, are manufactured in a one stage process in the liquid phase by subjecting aldehydes and/or ketones of not less than 2 or 3 carbon atoms, respectively, to an aldol condensation and hydrogenating the resulting olefinically unsaturated aldehyde, the catalyst used for the aldol condensation and hydrogenation containing nickel or cobalt or their mixtures, zinc oxide and at least one of the elements iron, arsenic, antimony, bismuth, gallium, indium, thallium, germanium, tin, lead, cadmium and mercury or compounds of the said elements.
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公开(公告)号：DE3105446A1
公开(公告)日：1982-09-02
申请号：DE3105446
申请日：1981-02-14
Applicant: BASF AG
Inventor： GRAMLICH WALTER DIPL CHEM DR , HEILEN GERD DIPL CHEM DR , MERCKER HANS JOCHEN DIPL CHEM , SIEGEL HARDO DIPL CHEM DR
IPC: C07C47/228 , B01J23/00 , C07B61/00 , C07C45/00 , C07C45/61 , C07C45/73 , C07C47/235 , C07C47/26 , C07C67/00 , C07C209/00 , C07C209/26 , C07C211/27 , C07C211/29 , C07D211/14 , C07D223/04 , C07D265/30 , C07D295/023 , C07C47/277 , C07D223/02 , C07D295/04
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公开(公告)号：DE3104765A1
公开(公告)日：1982-09-02
申请号：DE3104765
申请日：1981-02-11
Applicant: BASF AG
Inventor： REBAFKA WALTER DIPL CHEM DR , HEILEN GERD DIPL CHEM DR , HALBRITTER KLAUS DIPL CHEM DR , FRANZISCHKA WOLFGANG DIPL ING
IPC: C07D211/12 , B01J23/00 , B01J27/00 , C07D207/32 , C07D207/323 , C07D213/08 , C07D213/09 , C07D213/133
Abstract: A pyridine or a pyrrole is obtained in a one-stage process directly from an alpha , omega -dinitrile of appropriate carbon skeleton when the dinitrile is reacted in the gas phase with hydrogen, over a hydrogenation catalyst.
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公开(公告)号：DE2615308A1
公开(公告)日：1977-10-13
申请号：DE2615308
申请日：1976-04-08
Applicant: BASF AG
Inventor： NISSEN AXEL DIPL CHEM DR , WOERZ OTTO DIPL CHEM DR , HEILEN GERD DIPL CHEM DR , FLIEGE WERNER DIPL CHEM DR , WITTWER ARNOLD DIPL CHEM DR
Abstract: A process for the prepn. of higher ketones of formula: R'CH2CH2COR2 comprises the reaction of an aldehyde of formula (I): R1-CHO with ketones of formula (II) CH3COR2 at 80-280 degrees C in the presence of hydrogen and a catalytic system, which contains an oxide or salt of a rare earth metal or mixts. of these and one or more Group VIII metals. In the above, R' is 1-20C alkyl, esp. 1-5C), aryl or cycloalkyl opt. substd. by alkyl, or 7-20C (pref. 7-10 C) aralkyl; the above gps. may also be substd. by OH or alkoxyl gps. inert to the reaction conditions; R2 is the same as R'. Typical cpds. are methyl isoamyl ketone used as a solvent and intermediate and 4-phenyl-butan-2-one used in perfumery. As a result of the catalyst which favours both the condensation and hydrogenation steps, the process is more selective, simpler, cheaper and gives higher yields compared with previous processes. Using acetone and methyl propanol, the catalyst is 10% Ni, 10% Co, 10% rare earth oxides (95% Nd2O3) on an alumina support giving a mixture contg. 40.8% starting materials and 34.3% 5-methylhexane-2-one. The pref. reaction temp. is 140-220 degrees C.
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公开(公告)号：DE3125662A1
公开(公告)日：1983-01-13
申请号：DE3125662
申请日：1981-06-30
Applicant: BASF AG
Inventor： SCHROEDER WOLFGANG DIPL CHEM D , LENGSFELD WOLFGANG DIPL CHEM D , HEILEN GERD DIPL CHEM DR , HERTEL OTTO DIPL CHEM DR , BOETTGER GUENTER DIPL CHEM DR
IPC: B01J23/74 , B01J23/75 , B01J23/755 , C07D265/30 , C07D295/00 , C07D295/023 , C07D295/02 , C07D295/04
Abstract: Morpholine and other cyclic imines are obtained by reacting diethylene glycol and other appropriate diols with ammonia under hydrogenating conditions in the gas phase in the presence of a catalyst which contains copper, a smaller amount of nickel and alumina.
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Patent Agency Ranking
公开(公告)号：DE2941386A1
公开(公告)日：1981-05-21
申请号：DE2941386
申请日：1979-10-12
Applicant: BASF AG
Abstract: A process for the preparation of alpha -methylsubstituted ketones by reacting the corresponding non-methylsubstituted ketones with formaldehyde under hydrogenating conditions. The reaction proceeds easily and with good yields if a catalyst containing metallic palladium deposited on a zirconium, hafnium, titanium or tin phosphate is used. The products are valuable intermediates for the preparation of dyes, crop protection agents or drugs.
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公开(公告)号：DE2931692A1
公开(公告)日：1981-02-26
申请号：DE2931692
申请日：1979-08-04
Applicant: BASF AG
IPC: C07C33/046 , C07C33/04
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公开(公告)号：DE2845254A1
公开(公告)日：1980-05-08
申请号：DE2845254
申请日：1978-10-18
Applicant: BASF AG
Inventor： RENTZEA COSTIN DIPL ING DR , SAUTER HUBERT DIPL CHEM DR , AMMERMANN EBERHARD DIPL CHEM D , HEILEN GERD DIPL CHEM DR , JUNG JOHANN
IPC: A01N43/50 , A01N43/64 , A01N43/653 , A01N47/10 , A01N47/20 , C07D233/60 , C07D249/04 , C07D249/08 , C07D405/06 , C07D409/06 , C07D521/00 , A01N5/00
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公开(公告)号：DE2832699A1
公开(公告)日：1980-02-14
申请号：DE2832699
申请日：1978-07-26
Applicant: BASF AG
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