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公开(公告)号:DE2309375A1
公开(公告)日:1974-09-05
申请号:DE2309375
申请日:1973-02-24
Applicant: BASF AG
Abstract: Cpds. of formula (I) (where each R is H (prefd.) or an aliphatic gp.) are useful as inters. for dyes, pesticides and plastics stabilisers, are themselves useful as stabilisers (e.g. for poly-olefins and polyamides), and are specific solvents in the molten state. They can be prepd., e.g., by reducing the corresp. butan-2-one.
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公开(公告)号:DE2809421A1
公开(公告)日:1979-09-06
申请号:DE2809421
申请日:1978-03-04
Applicant: BASF AG
Inventor: DUDECK CHRISTIAN DIPL CHEM DR , LEHMANN GUNTER ING GRAD , MEISSNER BERND DIPL CHEM DR , DIEM HANS DIPL CHEM DR , FLIEGE WERNER DIPL CHEM DR , PETRI NORBERT DIPL CHEM DR , ROSS KARL-HEINZ DIPL CHEM DR
IPC: B01J23/00 , C07B61/00 , C07C67/30 , C07C69/67 , C07C69/716
Abstract: Alkyl pyruvates are prepared by oxidizing alkyl lactates in the presence of a silver catalyst of a defined particle size, at from 450 DEG to 700 DEG C. The products are starting materials for the preparation of drugs, synthetic resins and plastics.
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公开(公告)号:DE2659293A1
公开(公告)日:1978-07-13
申请号:DE2659293
申请日:1976-12-29
Applicant: BASF AG
IPC: C07C45/00 , C07C45/74 , C07C49/20 , C07C49/557 , C07C49/794 , C07C49/796 , C07C49/798 , C07C49/813 , C07D307/46 , C07D333/22 , C07C49/76 , C07C49/61 , C07C79/36 , C07C97/10
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公开(公告)号:DE2615308A1
公开(公告)日:1977-10-13
申请号:DE2615308
申请日:1976-04-08
Applicant: BASF AG
Inventor: NISSEN AXEL DIPL CHEM DR , WOERZ OTTO DIPL CHEM DR , HEILEN GERD DIPL CHEM DR , FLIEGE WERNER DIPL CHEM DR , WITTWER ARNOLD DIPL CHEM DR
Abstract: A process for the prepn. of higher ketones of formula: R'CH2CH2COR2 comprises the reaction of an aldehyde of formula (I): R1-CHO with ketones of formula (II) CH3COR2 at 80-280 degrees C in the presence of hydrogen and a catalytic system, which contains an oxide or salt of a rare earth metal or mixts. of these and one or more Group VIII metals. In the above, R' is 1-20C alkyl, esp. 1-5C), aryl or cycloalkyl opt. substd. by alkyl, or 7-20C (pref. 7-10 C) aralkyl; the above gps. may also be substd. by OH or alkoxyl gps. inert to the reaction conditions; R2 is the same as R'. Typical cpds. are methyl isoamyl ketone used as a solvent and intermediate and 4-phenyl-butan-2-one used in perfumery. As a result of the catalyst which favours both the condensation and hydrogenation steps, the process is more selective, simpler, cheaper and gives higher yields compared with previous processes. Using acetone and methyl propanol, the catalyst is 10% Ni, 10% Co, 10% rare earth oxides (95% Nd2O3) on an alumina support giving a mixture contg. 40.8% starting materials and 34.3% 5-methylhexane-2-one. The pref. reaction temp. is 140-220 degrees C.
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公开(公告)号:DE2545655A1
公开(公告)日:1977-04-21
申请号:DE2545655
申请日:1975-10-11
Applicant: BASF AG
Inventor: HUPFER LEOPOLD DIPL CHEM DR , MUELLER HERBERT DIPL CHEM DR , FLIEGE WERNER DIPL CHEM DR , MERKEL KARL DR , HOFFMANN HERWIG DIPL CHEM DR
IPC: C07C121/34
Abstract: New 3-methyl-pentan-2,5-diol-bis(2-cyanoethyl) ether is of formula NC-(CH2)2-O-(CH2)2-CH(CH3)-(CH2)2-O-(CH2)2-CN (I) (I) is an intermediate in the prodn. of the corresponding diamine which in turn can be used to prepare epoxy resins and polyurethanes. (I) is also useful as a polar solvent and an additive for minerals and propellants. (I) is made by reaction of 2 mols acrylonitrile and 3-methyl-penta-1,5-diol.
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公开(公告)号:DE2831595A1
公开(公告)日:1980-01-31
申请号:DE2831595
申请日:1978-07-19
Applicant: BASF AG
Inventor: SAUER WOLFGANG DIPL CHEM DR , DUDECK CHRISTIAN DIPL CHEM DR , LEHMANN GUNTER ING GRAD , MEISSNER BERND DIPL CHEM DR , PETRI NORBERT DIPL CHEM DR , ROSS KARL-HEINZ DIPL CHEM DR , HALBRITTER KLAUS DIPL CHEM DR , FLIEGE WERNER DIPL CHEM DR
IPC: C07C69/66 , B01J23/00 , C07B61/00 , C07C45/00 , C07C45/29 , C07C45/37 , C07C45/38 , C07C45/39 , C07C45/67 , C07C47/21 , C07C47/225 , C07C47/45 , C07C49/203 , C07C49/403 , C07C67/00 , C07C69/67 , C07D307/20 , C07D307/32 , C07D325/00 , C07C47/20 , C07C45/16 , C07C49/20 , C07C49/30 , C07C49/61
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公开(公告)号:DE2831229A1
公开(公告)日:1980-01-31
申请号:DE2831229
申请日:1978-07-15
Applicant: BASF AG
Inventor: SAUER WOLFGANG DIPL CHEM DR , ROSS KARL-HEINZ DIPL CHEM DR , DUDECK CHRISTIAN DIPL CHEM DR , LEHMANN GUNTER ING GRAD , PETRI NORBERT DIPL CHEM DR , DIEM HANS DIPL CHEM DR , MEISSNER BERND DIPL CHEM DR , FLIEGE WERNER DIPL CHEM DR
IPC: C07C47/02 , B01J23/00 , B01J23/50 , B01J23/72 , C07B61/00 , C07C45/00 , C07C45/38 , C07C45/39 , C07C47/12 , C07C47/20 , C07C49/04 , C07C49/12 , C07C49/20 , C07C67/00 , C07C45/16
Abstract: Diketones are prepared by oxidizing glycols in the presence of a silver catalyst and/or copper catalyst of a specific particle size, under specific temperature conditions and with a specific composition of the catalyst. The end products are starting materials for the preparation of dyes, drugs, plastics, scents, wrinkle-resist finishes and assistants for increasing the tear strength and resilience of fibrous materials, hardeners for use in the photographic industry, textile assistants for preventing shrinkage after washing, and paper assistants.
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公开(公告)号:DE2817496A1
公开(公告)日:1979-10-31
申请号:DE2817496
申请日:1978-04-21
Applicant: BASF AG
Inventor: SAUER WOLFGANG DIPL CHEM DR , FLIEGE WERNER DIPL CHEM DR , DUDECK CHRISTIAN DIPL CHEM DR , PETRI NORBERT DIPL CHEM DR
IPC: B01J23/00 , B01J35/00 , C07C45/00 , C07C45/29 , C07C45/38 , C07C47/20 , C07C47/228 , C07C47/52 , C07C47/54 , C07C67/00 , C07C213/00 , C07C223/00 , C07C47/48 , C07C95/08 , C07C45/16
Abstract: Aromatic and araliphatic aldehydes are prepared by oxidizing corresponding alcohols with oxygen in the presence of a silver catalyst of a defined particle size, and under defined temperature conditions. The products are starting materials for the preparation of dyes, pesticides, plastics and scents.
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公开(公告)号:DE2715209A1
公开(公告)日:1978-10-19
申请号:DE2715209
申请日:1977-04-05
Applicant: BASF AG
Inventor: DUDECK CHRISTIAN DIPL CHEM DR , DIEM HANS DIPL CHEM DR , BRUNNMUELLER FRITZ DIPL CHEM D , MEISSNER BERND DIPL CHEM DR , FLIEGE WERNER DIPL CHEM DR
IPC: B01J23/00 , B01J23/50 , B01J23/72 , C07B61/00 , C07C45/00 , C07C45/38 , C07C45/67 , C07C47/21 , C07C67/00 , C07C47/20
Abstract: 3-Alkyl-buten-1-als are prepared by oxidative dehydrogenation of 3-alkyl-buten-1-ols in the presence of a silver catalyst, of a particular total thickness, comprising 2 or more layers each of a particular weight and containing particles of a particular size. The products are starting materials for the manufacture of dyes, pesticides, drugs, plastics, naturally occurring materials and scents.
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公开(公告)号:DE2931692A1
公开(公告)日:1981-02-26
申请号:DE2931692
申请日:1979-08-04
Applicant: BASF AG
IPC: C07C33/046 , C07C33/04
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