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公开(公告)号:WO0185819A2
公开(公告)日:2001-11-15
申请号:PCT/EP0105230
申请日:2001-05-09
Applicant: BASF AG , NOERENBERG RALF , HILDEBRANDT SOEREN , KLUGE MICHAEL , BOECKH DIETER , PANANDIKER RAJAN K , WERTZ WILLIAM C , RANDALL SHERRI L
Inventor: NOERENBERG RALF , HILDEBRANDT SOEREN , KLUGE MICHAEL , BOECKH DIETER , PANANDIKER RAJAN K , WERTZ WILLIAM C , RANDALL SHERRI L
CPC classification number: C11D3/2075 , C08F8/44 , C11D3/33 , C11D3/3454 , C11D3/3723 , C11D3/3757 , C11D3/3776 , C11D3/378 , C11D3/3784
Abstract: The invention relates to polyelectrolyte complexes of cationic and anionic polymers, comprising (a) cationic condensates of (i) at least one amine and (ii) a cross-linking agent from the group of epihalohydrins, or bishalohydrins of diols, bishalohydrins of polyalkylene glycols, bishalohydrins of polytetrahydrofurans, alkylene dihalides, alkylene trihalides, bis-epoxides, tris-epoxides, tetra-epoxides, and/or mixtures of the above and/or quaternary cationic condensates of (i) and (ii) and (b) anionic compounds with at last three anionic groups and a loading ratio of anionic to cationic polymers of 0.01 to 20. The invention further relates to methods for the production of the polyelctrolyte complexes by means of mixing the cationic condensates (a) with anionic compounds (b).
Abstract translation: 阳离子和阴离子聚合物的聚合电解质络合物,(a)的(i)至少一种胺和(ii)交联剂选自表卤代醇的的缩合物的阳离子,聚亚烷基二醇的二醇的Bishalogenhydrine Bishalogenhydrine,聚四氢呋喃的Bishalogenhydrine,Alyklendihalogenide,Alkylentrihalogenide,双环氧化物 ,Trisepoxide,tetraepoxides和/或所述化合物的混合物和/或(i)和(ii)和(b)为具有至少三个阴离子基团和阴离子的电荷比阳离子从0.01到的聚合物的阴离子化合物的季铵化阳离子缩合物 20可具有,和由阳离子缩合物(A)与阴离子化合物混合于聚电解质络合物的制备方法(b)中。
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公开(公告)号:DE10027634A1
公开(公告)日:2001-12-13
申请号:DE10027634
申请日:2000-06-06
Applicant: BASF AG
Inventor: BOECKH DIETER , NOERENBERG RALF , HILDEBRANDT SOEREN , MOHR BERNHARD , SCHOEPKE HOLGER , LEYRER REINHOLD , HUFF JUERGEN
IPC: D06L1/12 , C08J3/205 , C11D3/37 , C11D17/06 , D06M15/267 , D06M15/285 , D06M15/356 , C09D5/02 , C09D7/02 , C09D133/26 , C08G69/48 , B01F17/00 , C09K3/18
Abstract: The use of particulate, hydrophobic polymers with a particle size of 10 nm to 100 micro m, cationically modified by coating with cationic polymers, as additives in washing or care materials for textiles and as additives in detergents. Independent claims are also included for: (i) a treatment for laundry and textile surfaces, containing: (a) 0.05-40 wt.% of the modified polymer (I); (b) 0.01-10 wt.% of a cationic polymer; and (c) 0-80 wt.% of additive(s) such as acids, bases, inorganic builders, organic co-builders, surfactants, polymeric color-transfer inhibitors, polymeric greying inhibitors, soil release polymers, enzymes, complex-formers, corrosion inhibitors, wax, silicone oils, light stabilizers, dyes, solvents, hydrotropic additives, thickeners and/or alkanolamines; (ii) a laundry after-treatment and care material containing: (a) 0.1-30 wt.% of (I) (containing ethylenically unsaturated monomer unit(s)), dispersed in water; (b) 0.05-20 wt.% of acid; (c) 0.1-10 wt.% of a cationic polymer; (d) 0-30 wt.% of water-soluble salt(s) of magnesium, calcium, zinc or aluminum and/or a cationic surfactant; and (e) 0-10 wt.% of additives such as perfume, silicone oil, light stabilizers, dyes, complex-formers, greying inhibitors, soil-release polyesters, color-transfer inhibitors, non-aqueous solvents, hydrotropic additives, thickeners and/or alkanolamines; (iii) a solid detergent formulation containing: (a) 0.05-20 wt.% of (I) (optionally also modified with multivalent metal ions and/or cationic surfactants); (b) 0.1-40 wt.% of non-ionic, cationic and/or anionic surfactant(s); (c) 0-50 wt.% of inorganic builder; (d) 0-10 wt.% of organic co-builder; and (e) 0-60 wt.% of other ingredients such as regulators, enzymes, perfumes, complex-formers, corrosion inhibitors, bleaching agents and/or activators, color-transfer inhibitors, greying inhibitors, soil-release polyesters, dyes, solubilizers and/or break-up agents; (iv) a liquid detergent formulation containing: (a) , (b) , (c) , (d) , (e) (f) (a) 0.05-20 wt.% of (I) (optionally further modified as in Independent Claim (iii)); (b) 0.1-40 wt.% of surfactant(s) as in Independent Claim (iii); (c) 0-20 wt.% of inorganic builder; (d) 0-10 wt.% of organic co-builder; (e) 0-10 wt.% of additives such as soda, enzymes, perfume, complex formers, corrosion inhibitors, bleaching agents, activators and/or catalysts, color-transfer inhibitors, greying inhibitors, soil-release polyesters, dyes, non-aqueous solvents, hydrotropic agents, thickeners and/or alkanolamines; and (f) 0-90 wt.% of water.
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公开(公告)号:DE10027638A1
公开(公告)日:2001-12-13
申请号:DE10027638
申请日:2000-06-06
Applicant: BASF AG
Inventor: BOECKH DIETER , NOERENBERG RALF , HILDEBRANDT SOEREN , MOHR BERNHARD , SCHOEPKE HOLGER , LEYRER REINHOLD , HUFF JUERGEN
IPC: C09K3/00 , C11D1/02 , C11D1/38 , C11D1/66 , C11D1/83 , C11D3/02 , C11D3/30 , C11D3/37 , C11D3/395 , C11D3/40 , C11D3/43 , C11D3/50 , C11D17/08 , C09D5/02 , B01F17/00 , C08G69/48 , C09D7/02 , C09D133/26 , C09K3/18
Abstract: The use of particulate, hydrophobic polymers with a particle size of 10 nm to 100 microns, cationically modified by coating with cationic polymers, as additives in washing, cleaning and impregnating materials for hard surfaces. Independent claims are also included for: (i) a cleaning material for hard surfaces, containing: (a) 0.05-40 wt.% of (I); (b) 0-20 wt.% of water-soluble salt(s) of magnesium, calcium, zinc or aluminum and/or 0.01-30 wt.% of a cationic surfactant and/or 0.01-15 wt.% of cationic polymer; (c) 0-80 wt.% of additive(s) such as acid or base, inorganic builders, organic co-builders, other surfactants, polymeric color-transfer or greying inhibitors, soil-release polymers, enzymes, complex-formers, corrosion inhibitors, waxes, silicone oils, light stabilizers. dyes, solvents, hydrotropic additives, thickeners and/or alkanolamines; and (d) water (to make up to 100 wt.%); (ii) a hard surface cleaner containing: (a) 0.1-30 wt.% of modified polymer as above (I) containing anionic unsaturated monomer units and dispersed in water; (b) 0.05-20 wt.% of acid; (c) 0-30 wt.% of water-soluble salt(s) of magnesium, calcium, zinc or aluminum and/or a cationic surfactant and/or 0.01-15 wt.% of cationic polymer; (d) 0-20 wt.% of additive(s) such as perfume, other surfactants, silicone oil, light stabilizers, dyes, complex-formers, greying inhibitors, soil-release polyesters, color-transfer inhibitors, non-aqueous solvents, hydrotropic additives, thickeners and/or alkanolamines; and (e) water (to make up 100 wt.%); (iii) a liquid cleaning and care formulation containing: (a) 0.05-30 wt.% of (I); (b) 0.1-40 wt.% of non-ionic or anionic surfactant(s); (c) 0-30 wt.% of salts and/or surfactant as above and/or 0.01-15 wt.% of cationic polymer; (d) 0-10 wt.% of complex-former; (e) 0-20 wt.% of additives such as pH regulators, thickeners, solvents, hydrotropic agents, polycarboxylic acids, silicones, brighteners, perfumes and/or dyes; and (f) 0-90 wt.% of water; (iv) a liquid acid cleaner containing: (a) 0.1-30 wt.% of hydrophobic polymer (particle size as above) with anionic monomer units, dispersed in water; (b) 0.05-20 wt.% of acid; (c) 0.1-30 wt.% of water-soluble cationic polymer; (d) 0-10 wt.% of complex former; (e) 0-20 wt.% of additives as in (ii); and (f) 0-90 wt.% of water; (v) a liquid acid cleaner containing: (a) 0.5-25 wt.% of hydrophobic polymer with 5-45 wt.% of unsaturated carboxylic acid monomer units, dispersed in water with anionic emulsifier and/or protective colloid; (b) 0.01-40 wt.% of non-ionic or anionic surfactant; (c) 0.01-20 wt.% of water-soluble or -dispersible cationic polymer; (d) 0.1-30 wt.% of soluble salts as above and/or cationic surfactant; (e) 0.1-20 wt.% of acid; (f) 0-10 wt.% of complex-former; (g) 0-20 wt.% of additives as in (ii); and (h) 0-90 wt.% of water; (vi) a solid cleaning formulation containing: (a) 0.05-30 wt.% of (I); (b) 0.1-40 wt.% of non-ionic and/or anionic surfactant; (c) 0-10 wt.% of cationic polymer; (d) 0-20 wt.% of salts and/or cationic surfactant as above; (e) 0-80 wt.% of inorganic builder, regulator and/or abrasive; (f) 0-20 wt.% of complex former and/or organic co-builder; (g) 0-10 wt.% of additives such as brighteners, wax, oils, perfume, corrosion inhibitors, bleaching agents, activators and/or catalysts and dyes; and (h) water (to make up 100 wt.%); (vii) a liquid after-rinse and impregnating formulation containing: (a) 0.05-30 wt.% of (I); (b) 0.1-30 wt.% of non-ionic or anionic surfactant; (c) 0-10 wt.% of acid, preferably a carboxylic acid; (d) 0-10 wt.% of cationic polymer; (e) 0-20 wt.% of salts and/or cationic surfactant as above; (f) 0-10 wt.% of additives such as thickeners, complex-formers, solvents, oils, waxes, hydrotropic agents, foam suppressants, polycarboxylic acids, silicones, brighteners, perfume and/or dyes; and (g) 0-90 wt.% of water.
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公开(公告)号:DE50109880D1
公开(公告)日:2006-06-29
申请号:DE50109880
申请日:2001-06-02
Applicant: BASF AG
Inventor: BOECKH DIETER , NOERENBERG RALF , HILDEBRANDT SOEREN , MOHR BERNHARD , SCHOEPKE HOLGER , LEYRER J , HUFF JUERGEN
IPC: C11D3/37 , D06L1/12 , C08J3/205 , C11D17/06 , D06M15/267 , D06M15/285 , D06M15/356
Abstract: The invention relates to the use of cationically-modified, particle-shaped, hydrophobic polymers as addition agents in rinsing, care, detergent, and cleaning products. The surface of said polymers is cationically modified by means of a coating of cationic polymers and the particle size of said polymers ranges from 10 nm to 100 mum.
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公开(公告)号:DE59905070D1
公开(公告)日:2003-05-22
申请号:DE59905070
申请日:1999-01-22
Applicant: BASF AG
Inventor: KAPPES ELISABETH , BRODT GREGOR , KROENER RUDI , WAGNER NORBERT , BOGENSTAETTER THOMAS , HILDEBRANDT SOEREN
IPC: C07B45/02 , C07D213/20
Abstract: Described is a process for preparing 1-(2-sulfoethyl)pyridinium betaine wherein pyridine is reacted with a sulfoethylating agent from the group consisting of carbyl sulfate, ethionic acid and its salt and vinylsulfonic acid and vinylsulfonate, the reaction taking place in aqueous solution or in pyridine.
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公开(公告)号:DE10105030A1
公开(公告)日:2002-08-08
申请号:DE10105030
申请日:2001-02-05
Applicant: BASF AG
Inventor: KLUGE MICHAEL , HILDEBRANDT SOEREN , WAGNER NORBERT , WEHLAGE THOMAS
IPC: C07D223/10 , C07D227/087
Abstract: The invention relates to a method for producing N,N'-carbonylbis- epsilon -caprolactam by the single-stage reaction of epsilon -caprolactam with phosgene, optionally in an inert organic solvent, in the presence of an organic nitrogenous base without an acylable nitrogen atom. The invention is characterised in that the organic nitrogenous base has a pKa-value of between 5 and 7. N,N-dimethylaniline is the preferred nitrogenous base.
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公开(公告)号:DE10105029A1
公开(公告)日:2002-08-08
申请号:DE10105029
申请日:2001-02-05
Applicant: BASF AG
Inventor: KLUGE MICHAEL , HILDEBRANDT SOEREN , WAGNER NORBERT , WEHLAGE THOMAS
IPC: C07D201/02 , C07D201/16 , C07D223/10 , C07D227/087 , C08G69/14
Abstract: The invention relates to a method for producing N,N'carbonylbis- epsilon -caprolactam by reacting epsilon -caprolactam with phosgene in the presence of a hydrogen chloride-binding agent in an inert organic solvent and isolating the reaction product from the product solution. The isolation comprises the following steps: a) optionally distilling off a part of the organic solvent from the product solution; b) adding water to the product solution; c) removing the organic solvent by azeotropic distillation, optionally while replacing the water distilled off, thereby deploying the product solution of organic solvent; d) allowing the N,N'-carbonylbis- epsilon -caprolactam to crystallize from the solution that is deployed from organic solvent, thereby obtaining an aqueous suspension of N,N'-carbonylbis- epsilon -caprolactam; and e) removing the crystallized product.
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公开(公告)号:AT327308T
公开(公告)日:2006-06-15
申请号:AT01947335
申请日:2001-06-02
Applicant: BASF AG
Inventor: BOECKH DIETER , NOERENBERG RALF , HILDEBRANDT SOEREN , MOHR BERNHARD , SCHOEPKE HOLGER , LEYRER REINHOLD J , HUFF JUERGEN
IPC: D06L1/12 , C08J3/205 , C11D3/37 , C11D17/06 , D06M15/267 , D06M15/285 , D06M15/356
Abstract: The invention relates to the use of cationically-modified, particle-shaped, hydrophobic polymers as addition agents in rinsing, care, detergent, and cleaning products. The surface of said polymers is cationically modified by means of a coating of cationic polymers and the particle size of said polymers ranges from 10 nm to 100 mum.
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公开(公告)号:DE50101622D1
公开(公告)日:2004-04-08
申请号:DE50101622
申请日:2001-05-09
Applicant: BASF AG
Inventor: NOERENBERG RALF , HILDEBRANDT SOEREN , KLUGE MICHAEL , BOECKH DIETER , PANANDIKER RAJAN K , WERTZ WILLIAM C , SHERRI RANDALL L
IPC: C08L101/02 , C08F8/44 , C11D3/37 , H01B1/06 , H01B13/00
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公开(公告)号:AT260943T
公开(公告)日:2004-03-15
申请号:AT01933942
申请日:2001-05-09
Applicant: BASF AG
Inventor: NOERENBERG RALF , HILDEBRANDT SOEREN , KLUGE MICHAEL , BOECKH DIETER , PANANDIKER RAJAN K , WERTZ WILLIAM C , SHERRI RANDALL L
IPC: C08L101/02 , C08F8/44 , C11D3/37 , H01B1/06 , H01B13/00
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