公开(公告)号：DE3009633A1

公开(公告)日：1981-09-24

申请号：DE3009633

申请日：1980-03-13

Applicant: BASF AG

Inventor： DOCKNER TONI DIPL CHEM DR ,  KEMPE UWE DIPL CHEM DR ,  KRUG HERBERT ,  MAGNUSSEN PETER DIPL CHEM DR ,  PRAETORIUS WERNER DIPL ING DR

IPC: B01J23/00 ,  C07D233/06 ,  C07D233/08 ,  C07D233/10

Abstract: 2-Imidazolines are prepared by reacting N,N'-diformyl-1,2-diamines in the gas phase at 200 DEG -350 DEG C., in the presence of certain amounts of an inert gas, over zinc oxide of a particular structure or over a mixture of this zinc oxide and aluminum oxide, as the catalyst. The 2-imidazolines obtainable by the process according to the invention are valuable starting materials for the preparation of dyes, crop protection agents and drugs.

公开(公告)号：DE3009605A1

公开(公告)日：1981-10-01

申请号：DE3009605

申请日：1980-03-13

Applicant: BASF AG

Inventor： DOCKNER TONI DIPL CHEM DR ,  GALLLEI EWALD DIPL CHEM DR ,  KEMPE UWE DIPL CHEM DR ,  KRUG HERBERT ,  MAGNUSSEN PETER DIPL CHEM DR ,  PRAETORIUS WERNER DIPL ING DR ,  SCHWARZ HELMUT DIPL CHEM DR

IPC: C07D233/54 ,  C07D233/56 ,  C07D233/58

公开(公告)号：DE2807659A1

公开(公告)日：1979-09-06

申请号：DE2807659

申请日：1978-02-23

Applicant: BASF AG

Inventor： MERGER FRANZ DIPL CHEM DR ,  NESTLER GERHARD DIPL CHEM DR ,  KEMPE UWE DIPL CHEM DR

IPC: C07B61/00 ,  B01J31/00 ,  B01J31/10 ,  C07C67/00 ,  C07C231/00 ,  C07C231/06 ,  C07C231/08 ,  C07C231/14 ,  C07C233/03 ,  C07C233/05 ,  C07C103/34 ,  C07C102/00

公开(公告)号：DE3212749A1

公开(公告)日：1983-10-13

申请号：DE3212749

申请日：1982-04-06

Applicant: BASF AG

Inventor： DOCKNER TONI DIPL CHEM DR ,  FRANK ANTON ,  KEMPE UWE DIPL CHEM DR ,  WETZLER MATTHIAS DIPL CHEM ,  KARN HELMUT

IPC: C07D233/54 ,  C07D233/56 ,  C07D233/60 ,  C07D233/61 ,  C07D233/64 ,  A01N43/50 ,  A01N47/34 ,  A61K7/40 ,  A61K31/415

公开(公告)号：DE2854428A1

公开(公告)日：1980-06-26

申请号：DE2854428

申请日：1978-12-16

Applicant: BASF AG

Inventor： DOCKNER TONI DIPL CHEM DR ,  KEMPE UWE DIPL CHEM DR ,  KRUG HERBERT ,  MAGNUSSEN PETER DIPL CHEM DR ,  PRAETORIUS WERNER DIPL CHEM DR ,  SZYMANSKI HANS JOACHIM

IPC: C07D233/06 ,  C07D233/08 ,  C07D233/10

Abstract: A novel process for the preparation of 2-imidazolines by reacting 1,2-diamines with nitriles or carbonyl compounds in the gas phase at from 200 DEG to 450 DEG C. in the presence of an oxide or phosphate of a metal of group 3 or 4 of the periodic table and/or in the presence of silicon dioxide. The 2-imidazolines obtainable by the process of the invention are valuable starting materials for the preparation of dyes, crop protection agents and drugs.

公开(公告)号：DE3009631A1

公开(公告)日：1981-09-24

申请号：DE3009631

申请日：1980-03-13

Applicant: BASF AG

Inventor： SCHWARZ HELMUT DIPL CHEM DR ,  DOCKNER TONI DIPL CHEM DR ,  KEMPE UWE DIPL CHEM DR ,  KRUG HERBERT DR ,  PRAETORIUS WERNER DIPL ING ,  MAGNUSSEN PETER DIPL CHEM DR ,  GALLEI EWALD DIPL CHEM DR ,  FEHR ERICH K DIPL CHEM DR

IPC: B01J23/00 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07D233/54 ,  C07D233/56 ,  C07D233/58

Abstract: Imidazoles are prepared by reacting 2-imidazolines at from 250 DEG to 500 DEG C. in the presence of molybdenum oxide and nickel oxide and/or cobalt oxide and aluminum oxide, silicon dioxide and/or silicates as catalysts. The imidazoles obtainable by the process according to the invention are valuable starting materials for the preparation of dyes, crop protection agents, textile auxiliaries, catalysts for polyurethanes and epoxy resins, surfactants and drugs, for example the corresponding nitroimidazoles.

公开(公告)号：DE2825547A1

公开(公告)日：1979-12-20

申请号：DE2825547

申请日：1978-06-10

Applicant: BASF AG

Inventor： DOCKNER TONI DIPL CHEM DR ,  FRANK ANTON ,  KEMPE UWE DIPL CHEM DR ,  WETZLER MATTHIAS DIPL CHEM ,  KARN HELMUT

IPC: C07D233/64 ,  A61K31/415 ,  C07D233/54 ,  C07D233/60 ,  C07D521/00 ,  C08G12/26 ,  C08G59/40 ,  C08G59/50 ,  C08K5/34 ,  C10L1/32

公开(公告)号：DE2714799A1

公开(公告)日：1978-10-05

申请号：DE2714799

申请日：1977-04-02

Applicant: BASF AG

Inventor： FISCHER ROLF DIPL CHEM DR ,  KEMPE UWE DIPL CHEM DR ,  POHL HANS HENNING DIPL CHEM DR ,  WEITZ HANS-MARTIN DIPL CHEM DR

IPC: C07C121/30

Abstract: (I), prepn. by reaching butenediol esters, (II), with at least equiv. quantities of HCN at 60-160 degrees C., takes place in aq. solns. of CuBr contg. alkali bromide, under pressures >=2 (pref. 2-20) bar. Mol. ratio CuBr to (II) is (0.3-0.6) : 1. The alkali bromide is esp. NaBr. The aq. solns. pref. also contain NH4Br and up to 10 wt.% HBr. (I) can be hydrogenated to hexamethylene diamine, used in polyamide prodn. On replacing previously used CuCl + alkali halide by CuBr + alkali bromide, yields of (I) can be increased, e.g. from 30% to >80%. Process can be effected economically on a large scale. Aq. solns. are handled more easily than fused salts. (I) is easily separated.

公开(公告)号：DE3209148A1

公开(公告)日：1983-09-22

申请号：DE3209148

申请日：1982-03-13

Applicant: BASF AG

Inventor： GOETZ NORBERT DIPL CHEM DR ,  ROHR WOLFGANG DIPL CHEM DR ,  MANGOLD DIETRICH DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  DOCKNER TONI DIPL CHEM DR ,  KEMPE UWE DIPL CHEM DR

IPC: C07D231/12

公开(公告)号：DE2936323A1

公开(公告)日：1981-04-02

申请号：DE2936323

申请日：1979-09-08

Applicant: BASF AG

Inventor： DOCKNER TONI DIPL CHEM DR ,  KEMPE UWE DIPL CHEM DR ,  KRUG HERBERT ,  MAGNUSSEN PETER DIPL CHEM DR ,  PRAETORIUS WERNER DIPL ING DR ,  ROMBERG HELMUT DIPL ING DR

IPC: C07D233/54 ,  C07D233/58 ,  C07D233/56