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公开(公告)号：JP2004175802A
公开(公告)日：2004-06-24
申请号：JP2003392990
申请日：2003-11-21
Applicant: Basf Ag , ビーエーエスエフ アクチェンゲゼルシャフト
Inventor： LIANG SHELLUE , FISCHER ROLF-HARTMUTH , HUBER-DIRR SYLVIA , HAUNERT ANDREA
IPC: C07C45/54 , B01J23/04 , C07B61/00 , C07C45/48 , C07C49/597
CPC classification number: B01J23/04 , C07C45/48 , Y02P20/582 , C07C49/597
Abstract: PROBLEM TO BE SOLVED: To provide a method for preparing cyclopentenones from dicarboxylic acids. SOLUTION: The present invention provides a process for preparing 2-cyclopentenones of general formula 1 [in the formula R 1 to R 4 are each H, an alkyl, an alkenyl, a cycloalkyl, a cycloalkenyl, an aralkylene or an aryl group], by converting hexenedioic acids and/or their esters (for example, 3-hexene-1, 6-dioic acid) at temperatures of from 150 to 450°C., over solid oxide catalysts, wherein the catalysts on an oxide carrier material comprise from 0.01 to 5% by weight of at least one alkali metal oxide. COPYRIGHT: (C)2004,JPO
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公开(公告)号：WO2004054948A8
公开(公告)日：2005-06-23
申请号：PCT/EP0313634
申请日：2003-12-03
Applicant: BASF AG , FISCHER ROLF-HARTMUTH , KRUG THOMAS , HAUNERT ANDREA , ROEPER MICHAEL , SIRCH TILMAN , STUEER WOLFRAM
Inventor： FISCHER ROLF-HARTMUTH , KRUG THOMAS , HAUNERT ANDREA , ROEPER MICHAEL , SIRCH TILMAN , STUEER WOLFRAM
IPC: C07C29/17 , C07C29/149 , C07C31/20 , C07C67/347 , C07C69/593
CPC classification number: C07C29/177 , C07C31/20
Abstract: The invention relates to a method for producing 1,6-hexanediol having a purity of > 99.5 wt. % by catalytic dimerisation of acrylic acid esters, catalytic hydrogenation of the thus obtained hexene diacidic diester in order to form 1.6-hexanediol. Said method consists in: a) dimerising C1- C8-acrylic acid esters in the presence of at least one rhodium compound in order to form mixtures predominantly of 2- and 3-hexene diacdic diesters, b) hydrating the obtained dimerisation discharge in the presence of chrome-free catalysts containing mainly copper as a hydrogenation component and c) purifying the thus obtained raw 1.6-hexanediol by fractionating distillation.
Abstract translation: 本发明涉及一种用于制备具有> 99.5重量％的纯度的1,6-己二醇，由丙烯酸酯，以这种方式获得成1,6-己二醇的二酯己烯的催化氢化方法，其包括催化二聚化：一个 ）C1至C8丙烯酸酯在二聚的至少一种铑化合物的存在下，得到主要为2-和3-己烯二酯的混合物，b）中氢化在无铬的存在下将所得二聚化流出物，含有作为氢化主要是铜催化剂，和c）将如此得到的粗1 1,6-己二醇通过分馏进行纯化。
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公开(公告)号：BRPI0613571A2
公开(公告)日：2016-11-16
申请号：BRPI0613571
申请日：2006-06-26
Applicant: BASF AG
Inventor： HAUNERT ANDREA , STRÖFER ECKHARD , TEBBEN GERD-DIETER , SCHELLING HEINER , KARL JÖRN , EIERMANN MATTHIAS , PINKOS ROLF
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公开(公告)号：NO20076505L
公开(公告)日：2008-01-28
申请号：NO20076505
申请日：2007-12-19
Applicant: BASF AG
Inventor： STROFER ECKHARD , KARL JORN , TEBBEN GERD-DIETER , SCHELLING HEINER , PINKOS ROLF , HAUNERT ANDREA , EIERMANN MATTHIAS
Abstract: A biodiesel fuel mixture having a cetane number of >40, comprising a) from 1 to 100% by weight of biodiesel, b) from 0 to 98.9% by weight of diesel oil of fossil origin, c) from 0.1 to 20% by weight of polyoxyalkylene dialkyl ether of the formula RO(CH 2 O) n R in which R is an alkyl group having from 1 to 10 carbon atoms and n=from 2 to 10, and d) from 0 to 5% by weight of further additives.
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公开(公告)号：CA2613877A1
公开(公告)日：2007-01-04
申请号：CA2613877
申请日：2006-06-26
Applicant: BASF AG
Inventor： HAUNERT ANDREA , EIERMANN MATTHIAS , PINKOS ROLF , KARL JOERN , SCHELLING HEINER , TEBBEN GERD-DIETER , STROEFER ECKHARD
Abstract: A biodiesel fuel mixture having a cetane number of >40, comprising a) from 1 to 100% by weight of biodiesel, b) from 0 to 98.9% by weight of diesel oil of fossil origin, c) from 0.1 to 20% by weight of polyoxyalkylene dialkyl ether of the formula RO(CH 2 O) n R in which R is an alkyl group having from 1 to 10 carbon atoms and n=from 2 to 10, and d) from 0 to 5% by weight of further additives.
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Patent Agency Ranking
公开(公告)号：AT334956T
公开(公告)日：2006-08-15
申请号：AT03799469
申请日：2003-12-03
Applicant: BASF AG
Inventor： FISCHER ROLF-HARTMUTH , KRUG THOMAS , HAUNERT ANDREA , ROEPER MICHAEL , SIRCH TILMAN , STUEER WOLFRAM
IPC: C07C29/17 , C07C29/149 , C07C31/20 , C07C67/347 , C07C69/593
Abstract: Production of 1,6-hexanediol of purity at least 99.5 % comprises: (1) catalytically dimerizing a 1-8C acrylic acid ester in presence of rhodium compounds to a mixture mainly of 2- and 3-hexenedioic acid diesters; (2) hydrogenating the ester mixture in chromium-free mainly copper-containing catalysts; and (3) purifying the resulting diol mixture by fractional distillation.
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公开(公告)号：DE102004053839A1
公开(公告)日：2006-05-11
申请号：DE102004053839
申请日：2004-11-04
Applicant: BASF AG
Inventor： SCHELLING HEINER , STROEFER ECKHARD , PINKOS ROLF , HAUNERT ANDREA , TEBBEN GERD-DIETER , HASSE HANS , BLAGOV SERGEJ
Abstract: Preparation of a polyoxymethylene dimethyl ether (I) comprises feeding methylal and trioxane to a reactor and reacting in the presence of an acidic catalyst, where the quantity of water introduced into the reaction mixture by means of the methylal, trioxane and/or the catalyst is less than 1 wt.%, related to the reaction mixture. Preparation of a polyoxymethylene dimethyl ether (I) of formula (H 3CO(CH 2O) nCH 3) (where n is 2-10) comprises feeding methylal and trioxane to a reactor and reacting in the presence of an acidic catalyst, where the quantity of water introduced into the reaction mixture by means of the methylal, trioxane and/or the catalyst are less than 1 wt.%, related to the reaction mixture.
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公开(公告)号：CA2569246A1
公开(公告)日：2006-01-19
申请号：CA2569246
申请日：2005-07-07
Applicant: BASF AG
Inventor： HAUNERT ANDREA , HOUSSIN CHRISTOPHE , JUNICKE HENRIK
IPC: C07C29/149 , B01J23/72 , C07B41/02
Abstract: A process for the hydrogenation of an organic compound containing at least one carbonyl group comprises bringing the organic compound in the presence of hydrogen into contact with a shaped body which can be produced by a process in which (i) an oxidic material comprising copper oxide, aluminum oxide and aluminum oxide is made available (ii) pulverulent metallic copper, copper flakes, pulverulent cement, graphite or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to form a shaped body.
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公开(公告)号：BRPI0408384B1
公开(公告)日：2014-11-11
申请号：BRPI0408384
申请日：2004-03-20
Applicant: BASF AG
Inventor： HUBER-DIRR SYLVIA , HAUNERT ANDREA , HESSE MICHAEL , JUNICKE HENRIK
IPC: C07C29/149 , B01J21/04 , B01J23/72 , B01J23/83
Abstract: A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is hydrogenated in the presence of a shaped article which contains (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide, and (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof, is provided.
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公开(公告)号：DE102004033557A1
公开(公告)日：2006-02-16
申请号：DE102004033557
申请日：2004-07-09
Applicant: BASF AG
Inventor： HAUNERT ANDREA , PINKOS ROLF , KRUG THOMAS , SIRCH TILMAN , KOCH MICHAEL , TEBBEN GERD-DIETER
IPC: C07C29/136 , C07C31/20
Abstract: The present invention provides a process for preparing 1,6-hexanediol by hydrogenating dialkyl adipates, alkyl 6-hydroxycaproates, 1,4-cyclohexanedione and 4-hydroxycyclohexan-1-one as ester mixtures comprising impurities, by a) freeing resulting the esterification mixture of excess alcohol and low boilers in a first distillation stage (alcohol removal), b) carrying out a separation of the bottom product in a second distillation stage into an ester fraction substantially free of 1,4-cyclohexanediols and a fraction comprising at least the majority of the 1,4-cyclohexanediols, c) catalytically hydrogenating the ester fraction substantially free of 1,4-cyclohexanediols (ester hydrogenation) and d) in a purifying distillation stage, obtaining 1,6-hexanediol from the hydrogenation effluent in a manner known per se, which comprises selectively hydrogenating the ester mixture before stage a) and/or before stage b) (purifying hydrogenation).
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