公开(公告)号：BG103970A

公开(公告)日：2000-11-30

申请号：BG10397099

申请日：1999-12-08

Applicant: BASF AG

Inventor： SUTORIS HEINZ F ,  MITULLA KONRAD ,  DUPUIS JACQUES ,  KALIBA CLAUS

IPC: C07B63/04 ,  C07C7/20 ,  C07C15/46 ,  C09K15/20 ,  C09K15/30 ,  C09K15/32

Abstract: The invention relates to a mixture of substances including one or more compounds with vinyl groups as component (A), and as component (B) - stabilizer containing one or more easily volatile nitroxyl compounds as component (b1), one or more not easily volatile nitroxyl compounds as component (b2), optionally one or more aromatic nitrocompounds as component (b3), optionally one or more iron compounds as component (b4). The invention also relates to stabilizers (B) containing the components (b1) & (b2), (b1), (b2) and (b3), (b1) (B2), (b4) and (b1),(b2), (b3) and (b4), and to a method for the inhibition of the premature polymerization of compounds containing vinyl groups during their refining or distillation by the addition of either stabilizer (B) or components from it as individual substances or at least as two groups of components. 10 claims

公开(公告)号：PL337673A1

公开(公告)日：2000-08-28

申请号：PL33767398

申请日：1998-06-04

Applicant: BASF AG

Inventor： SUTORIS HEINZ FRIEDRICH ,  MITULLA KONRAD ,  DUPUIS JACQUES ,  KALIBA CLAUS

IPC: C07B63/04 ,  C07C7/20 ,  C07C15/46 ,  C09K15/20 ,  C09K15/30 ,  C09K15/32

Abstract: A mixture contains one or more vinyl-containing compounds as component (A) and, as a further component, a stabilizer (B) which contains one or more readily volatile nitroxyl compounds as component (b1), one or more sparingly volatile nitroxyl compounds as component (b2), if required one or more aromatic nitro compounds as component (b3) and, if required, one or more iron compounds as component (b4).Stabilizers (B) contain the components (b1) and (b2), (b1) and (b2) and (b3), (b1) and (b2) and (b4), and (b1), (b2), (b3) and (b4), and the premature polymerization of vinyl-containing compounds during their purification or distillation is inhibited by a process in which a stabilizer (B) is added or the components of stabilizer (B) are added as individual substances or in at least two groups of the components.

公开(公告)号：CA2191621A1

公开(公告)日：1995-12-07

申请号：CA2191621

申请日：1995-05-17

Applicant: BASF AG

Inventor： SCHMID RAIMUND ,  MRONGA NORBERT ,  KALIBA CLAUS ,  OSTERTAG WERNER ,  SCHMIDT HELMUT

IPC: B41M3/14 ,  B44F1/12 ,  C09C1/00 ,  C09C1/28 ,  C09D7/12 ,  C09D11/00 ,  D21H21/40 ,  G07D7/00 ,  C09C1/36 ,  C09C3/00

Abstract: Interference pigments based on silicate laminae that are coated with titanium dioxide and heated in a reduced atmosphere are used to produce forgery-proof security documents and packaging.

公开(公告)号：CA2293577A1

公开(公告)日：1998-12-23

申请号：CA2293577

申请日：1998-06-04

Applicant: BASF AG

Inventor： DUPUIS JACQUES ,  MITULLA KONRAD ,  KALIBA CLAUS ,  SUTORIS HEINZ FRIEDRICH

IPC: C07B63/04 ,  C07C7/20 ,  C07C15/46 ,  C09K15/20 ,  C09K15/30 ,  C09K15/32

Abstract: The invention relates to a mixture of substances containing one or several compounds with vinyl groups as constituent (A) and a stabilizer (B) as another constituent containing one or several easily volatile nitroxyl compounds as constituent (b1), one or several non-easily volatile nitroxyl compounds as constituent (b2), optionally one or several aromatic nitro compounds as constituent (b3) and optionally one or several iron compounds as constituent (b4). The invention also relates to stabilizers (B) containing constituents (b1) and (b2), (b1) and (b2) and (b3), (b1) and (b2) and (b4), in addition to (b1), (b2), (b3) and (b4). The invention further relates to a method for inhibiting premature polymerization of compounds with vinyl groups during the cleaning thereof or distillation by adding a stabilizer (B), or by adding the constituents of stabilizer (B) as individual substances or in at least two groups of constituents.

公开(公告)号：ES2108582T3

公开(公告)日：1997-12-16

申请号：ES95920053

申请日：1995-05-17

Applicant: BASF AG

Inventor： SCHMID RAIMUND ,  MRONGA NORBERT ,  KALIBA CLAUS ,  OSTERTAG WERNER ,  SCHMIDT HELMUT

IPC: B41M3/14 ,  B44F1/12 ,  C09C1/00 ,  C09C1/28 ,  C09D7/12 ,  C09D11/00 ,  D21H21/40 ,  G07D7/00

Abstract: PCT No. PCT/EP95/01871 Sec. 371 Date Dec. 2, 1996 Sec. 102(e) Date Dec. 2, 1996 PCT Filed May 17, 1995 PCT Pub. No. WO95/33009 PCT Pub. Date Dec. 7, 1995Interference pigments based on titanium dioxide-coated silicatic platelets which have been heated in a reducing atmosphere are useful for producing forgeryproof documents and packaging.

公开(公告)号：AT159974T

公开(公告)日：1997-11-15

申请号：AT95920053

申请日：1995-05-17

Applicant: BASF AG

Inventor： SCHMID RAIMUND ,  MRONGA NORBERT ,  KALIBA CLAUS ,  OSTERTAG WERNER ,  SCHMIDT HELMUT

IPC: B41M3/14 ,  B44F1/12 ,  C09C1/00 ,  C09C1/28 ,  C09D7/12 ,  C09D11/00 ,  D21H21/40 ,  G07D7/00

Abstract: PCT No. PCT/EP95/01871 Sec. 371 Date Dec. 2, 1996 Sec. 102(e) Date Dec. 2, 1996 PCT Filed May 17, 1995 PCT Pub. No. WO95/33009 PCT Pub. Date Dec. 7, 1995Interference pigments based on titanium dioxide-coated silicatic platelets which have been heated in a reducing atmosphere are useful for producing forgeryproof documents and packaging.

公开(公告)号：CZ9904615A3

公开(公告)日：2000-06-14

申请号：CZ461599

申请日：1998-06-04

Applicant: BASF AG

Inventor： SUTORIS HEINZ FRIEDRICH ,  MITULLA KONRAD ,  DUPUIS JACQUES ,  KALIBA CLAUS

IPC: C07B63/04 ,  C07C7/20 ,  C09K15/30

公开(公告)号：CZ461599A3

公开(公告)日：2000-06-14

申请号：CZ461599

申请日：1998-06-04

Applicant: BASF AG

Inventor： SUTORIS HEINZ FRIEDRICH ,  MITULLA KONRAD ,  DUPUIS JACQUES ,  KALIBA CLAUS

IPC: C07B63/04 ,  C07C7/20 ,  C09K15/30

公开(公告)号：DE19917967A1

公开(公告)日：1999-11-18

申请号：DE19917967

申请日：1999-04-21

Applicant: BASF AG

Inventor： SUTORIS HEINZ FRIEDRICH ,  HAREMZA SYLKE ,  MERGER ROLAND ,  KALIBA CLAUS ,  BERTLEIN GERHARD

IPC: C07B63/04 ,  C07C7/20 ,  C09K15/20 ,  C09K15/04 ,  C07C291/04 ,  C07D211/94 ,  C07D227/02 ,  C07D493/10

Abstract: The stabilizer system in a mixture containing vinyl compounds (A) consists of (B) a mixture to inhibit premature polymerisation, containing (i) at least one N-oxyl compound of a secondary amine with no hydrogens on the alpha-carbon atoms and at least one compound of a transition metal other than iron, optionally with (C) nitro compounds and (D) co-stabilizers. An Independent claim is also included for a method for inhibiting the premature polymerisation of vinyl compounds (A) by adding mixture (B), optionally with (C) and/or (D), before or during purification or distillation.

公开(公告)号：FI964780A0

公开(公告)日：1996-11-29

申请号：FI964780

申请日：1996-11-29

Applicant: BASF AG

Inventor： SCHMID RAIMUND ,  MRONGA NORBERT ,  KALIBA CLAUS ,  OSTERTAG WERNER ,  SCHMIDT HELMUT

IPC: B41M3/14 ,  B44F1/12 ,  C09C1/00 ,  C09C1/28 ,  C09D7/12 ,  C09D11/00 ,  D21H21/40 ,  G07D7/00 ,  D21H ,  C09D

Abstract: PCT No. PCT/EP95/01871 Sec. 371 Date Dec. 2, 1996 Sec. 102(e) Date Dec. 2, 1996 PCT Filed May 17, 1995 PCT Pub. No. WO95/33009 PCT Pub. Date Dec. 7, 1995Interference pigments based on titanium dioxide-coated silicatic platelets which have been heated in a reducing atmosphere are useful for producing forgeryproof documents and packaging.