公开(公告)号：DE1644989A1

公开(公告)日：1971-07-15

申请号：DE1644989

申请日：1967-11-16

Applicant: BASF AG

Inventor： POHLEMANN HEINZ DR ,  SPOOR HERBERT DR ,  MARX MATTHIAS DR ,  KLUG HANS DR

IPC: C03C25/28 ,  C03C25/285 ,  C09D133/06 ,  C09D157/12 ,  D06M15/29

公开(公告)号：DE2961067D1

公开(公告)日：1981-12-24

申请号：DE2961067

申请日：1979-07-13

Applicant: BASF AG

Inventor： HUMMERICH RAINER DR ,  BALZER WOLF-DIETER DR ,  KLUG HANS DR ,  TRIMBORN WERNER DR ,  KRAUSE HANS-JOACHIM DR

IPC: C08G6/02

公开(公告)号：DE2861898D1

公开(公告)日：1982-07-29

申请号：DE2861898

申请日：1978-12-20

Applicant: BASF AG

Inventor： PETERSEN HARRO DR ,  FISCHER KURT ,  KLUG HANS DR ,  TRIMBORN WERNER DR

IPC: C08G12/00 ,  C08G12/02 ,  C08G12/12 ,  C09D161/20 ,  C09D161/24

Abstract: A process for the preparation of soft and hard resins, and their use in surface-coating binders. According to the invention, soft and hard resins are prepared from a urea and a CH-acidic aldehyde by reacting a urea of the general formula (I) (I) where X is oxygen or sulfur and R1 and R2 are hydrogen or identical or different alkyl, aryl or aralkyl, or may be an alkyleneurea radical, with at least 2 moles of a CH-acidic aldehyde of the general formula (II) (II) where R3 is hydrogen and R4 is alkyl, aryl or aralkyl, or R3 and R4 are identical or different alkyl, aryl or aralkyl, in the presence of a strong acid, to give a condensation product, and then treating the latter with a base in an anhydrous medium. These soft and hard resins are used, in combination with other film-forming agents, as surface-coating binders.

公开(公告)号：DE1644990A1

公开(公告)日：1971-07-15

申请号：DE1644990

申请日：1967-11-25

Applicant: BASF AG

Inventor： MARX MATTHIAS DR ,  POHLEMANN HEINZ DR ,  KLUG HANS DR

IPC: C08F220/12 ,  C08F265/06 ,  C09D4/06

公开(公告)号：DE1644985A1

公开(公告)日：1971-06-24

申请号：DE1644985

申请日：1951-01-28

Applicant: BASF AG

Inventor： MARX MATTHIAS DR ,  KLUG HANS DR ,  KIEMSTEDT KARL DR

IPC: C09D133/14 ,  C09J133/04

公开(公告)号：CH494271A

公开(公告)日：1970-07-31

申请号：CH1429669

申请日：1968-06-25

Applicant: BASF AG

Inventor： MARX MATTHIAS DR ,  HERMANN PANKRANZ DR HOFMANN ,  KLUG HANS DR

IPC: C08F220/28 ,  C09D125/06 ,  C09D133/14 ,  C09J133/04 ,  C09J133/06 ,  C09J133/14 ,  C09J3/14 ,  C09D3/48

公开(公告)号：DE3532865A1

公开(公告)日：1987-04-02

申请号：DE3532865

申请日：1985-09-14

Applicant: BASF AG

Inventor： KLUG HANS DR ,  MUELLER HORST

IPC: C08G18/08 ,  C08G18/16 ,  C08G18/18 ,  C08G18/46 ,  C08G63/692 ,  C08G63/68 ,  C08G18/79 ,  C08G18/80 ,  C08G63/20 ,  C08G63/76 ,  C09D3/72

Abstract: The invention relates to hydroxyl-containing saturated polyester resins, to their preparation, to their use for two-component polyurethane paints, (surface coatings, lacquers, enamels, varnishes), and to a process for extending their pot life. These hydroxyl-containing polyester resins contain incorporated acidic phosphoric acid ester groups (phosphate groups), the acid number emanating from the phosphoric acid being from 5 to 60 mg of KOH/g. In order to extend the pot life, volatile tertiary amines or volatile amides of secondary amines can be added to them. The hydroxyl-containing polyester resins according to the invention are suitable, in combination with polyisocyanates, for two-component paints.

公开(公告)号：DE3532864A1

公开(公告)日：1987-04-02

申请号：DE3532864

申请日：1985-09-14

Applicant: BASF AG

Inventor： KLUG HANS DR ,  MUELLER HORST

IPC: C08G18/42 ,  C08G18/79 ,  C08G63/137 ,  C08G63/12 ,  C08G18/80 ,  C08G63/20 ,  C09D3/72

Abstract: The invention relates to a process for the preparation of highly reactive hydroxyl-containing polyesters, and to their use. To this end, dicarboxylic anhydrides are esterified first with polyols containing from 3 to 6 primary hydroxyl groups per molecule and subsequently with diols containing from 3 to 6 carbon atoms, in the presence of an acidic catalyst and an entrainer at from 100 to 150 DEG C with azeotropic removal of water. The hydroxyl-containing polyesters prepared according to the invention are suitable, in combination with polyisocyanates, for two-component paints (surface coatings, enamels, laquers, varnishes).

公开(公告)号：DE2861932D1

公开(公告)日：1982-08-19

申请号：DE2861932

申请日：1978-12-20

Applicant: BASF AG

Inventor： PETERSEN HARRO DR ,  FISCHER KURT ,  KLUG HANS DR ,  TRIMBORN WERNER DR ,  SCHMIDT HORST DR

IPC: C08G12/00 ,  C08G12/02 ,  C08G12/10 ,  C08G12/12 ,  C08G12/14 ,  C08G12/40 ,  C09D161/20 ,  C09D161/24 ,  C09D3/52

Abstract: A process for the preparation of soft and hard resins, and their use in surface-coating binders are disclosed. According to the invention, soft and hard resins are prepared from a urea, formaldehyde and a CH-acidic aldehyde by reacting a urea of the general formula (I) or (II) (I) (II) where R1 and R2 are hydrogen or identical or different alkyl, A is alkylene and X is oxygen or sulfur, with formaldehyde and a CH-acidic aldehyde of the general formula (III) where R3 and R4 are identical or different alkyl, aryl or alkylaryl wherein the urea, formaldehyde and CH-acidic aldehyde are employed in a mole ratio of from 1:2:2 to 1:4:4, at from 60 DEG to 150 DEG C., in the presence of an acid and in the presence or absence of a solvent and/or diluent, and then treating the product with a base in an anhydrousmedium.

公开(公告)号：DE2305023A1

公开(公告)日：1974-08-08

申请号：DE2305023

申请日：1973-02-02

Applicant: BASF AG

Inventor： BRONSTERT KLAUS DR ,  MUELLER DIETRICH-WOLFGANG DR ,  KLUG HANS DR ,  GRAH LIESELORE

IPC: C09D7/00 ,  C09D5/28

Abstract: Flatting agents for coatings obtained by reacting a polyolefin wax (A) with a vinyl aromatic compound (B) and a copolymerizable alpha , beta -olefinically unsaturated dicarboxylic anhydride (C), optionally partially replaced by at least one alpha , beta -olefinically unsaturated monocaraboxylic acid, the molar ratio of (B) to (C) being from 0.7:1 to 1:0.7 and the sum of the weights of (B) and (C) being from 2 to 50 percent by weight of the weight of polyolefin wax (A). The reaction is carried out at temperatures of from 100 DEG to 200 DEG C, in the presence or absence of conventional free-radical polymerization initiators. The agents are particularly suitable for coatings containing organic solvents.